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El. knyga: Analytical Chemistry in Archaeology

(University of Oxford), (Tufts University, Massachusetts), (University of Bradford), (University of Bradford)
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An introductory manual that explains the basic concepts of chemistry behind scientific analytical techniques and that reviews their application to archaeology. It explains key terminology, outlines the procedures to be followed in order to produce good data, and describes the function of the basic instrumentation required to carry out those procedures. The manual contains chapters on the basic chemistry and physics necessary to understand the techniques used in analytical chemistry, with more detailed chapters on Atomic Absorption, Inductively Coupled Plasma Emission Spectroscopy, Neutron Activation Analysis, X-ray Flourescence, Electron Microscopy, Infra-red and Raman Spectroscopy, and Mass Spectrometry. Each chapter describes the operation of the instruments, some hints on the practicalities, and a review of the application of the technique to archaeology, including some case studies. With guides to further reading on the topic, it is an essential tool for practitioners, researchers and advanced students alike.

Introduces the basic concepts of chemistry behind scientific analytical techniques and reviews their application to archaeology.

Recenzijos

' aimed at the non-specialist provides enough information to allow readers to find their own depth within the subject a valuable resource ' Journal of Medieval Archaeology

Daugiau informacijos

This book introduces the basic concepts of chemistry behind scientific analytical techniques and reviews their application to archaeology.
List of figures
ix
List of tables
xii
Preface xiii
PART I THE ROLE OF ANALYTICAL CHEMISTRY IN ARCHAEOLOGY
1(44)
Archaeology and Analytical Chemistry
3(28)
The history of analytical chemistry in archaeology
5(5)
Basic archaeological questions
10(15)
Questions of process
25(6)
An Introduction to Analytical Chemistry
31(14)
What is chemistry?
31(7)
Analytical chemistry
38(4)
Special considerations in the analysis of arehaeological material
42(3)
PART II THE APPLICATION OF ANALYTICAL CHEMISTRY TO ARCHAEOLOGY
45(170)
Elemental Analysis by Absorption and Emission Spectroscopies in the Visible and Ultraviolet
47(23)
Optical emission spectroscopy (OES)
47(1)
Atomic absorption spectroscopy (AAS)
48(9)
Inductively coupled plasma atomic emission spectroscopy (ICP--AES)
57(3)
Comparison of analysis by absorption/emission spectrometries
60(2)
Greek pots and European bronzes -- archaeological applications of emission/absorption spectrometries
62(8)
Molecular Analysis by Absorption and Raman Spectroscopy
70(23)
Optical and UV spectrophotometry
70(7)
Infrared absorption spectroscopy
77(6)
Raman spectroscopy
83(2)
Soils, bone, and the ``Baltic shoulder'' -- archaeological applications of vibrational spectroscopy
85(8)
X-Ray Techniques and Electron Beam Microanalysis
93(30)
Introduction to X-rays
93(8)
X-ray fluorescence (XRF) spectrometry
101(8)
Electron microscopy as an analytical tool
109(4)
X-ray diffraction
113(3)
Other X-ray related techniques
116(2)
A cornucopia of delights -- archaeological applications of X-ray analysis
118(5)
Neutron Activation Analysis
123(14)
Introduction to nuclear structure and the principles of neutron activation analysis
123(5)
Neutron activation analysis in practice
128(2)
Practical alchemy -- archaeological applications of NAA
130(7)
Chromatography
137(23)
Principles of chromatography
137(2)
Classical liquid column chromatography
139(1)
Thin layer chromatography (TLC)
139(3)
Gas chromatography (GC)
142(4)
High performance liquid chromatography (HPLC)
146(1)
Sticky messengers from the past -- archaeological applications of chromatography
147(13)
Mass Spectrometry
160(35)
Separation of ions by electric and magnetic fields
160(9)
Light stable isotopes (δD, δ13C, δ15N, δ18O, and δ34S)
169(4)
Heavy isotopes (Pb, Sr) -- thermal ionization mass spectrometry (TIMS)
173(1)
Combined techniques -- GC-MS
174(2)
Isotope archaeology -- applications of MS in archaeology
176(19)
Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)
195(20)
Types of ICP analysis
195(5)
Comparison with other techniques
200(2)
Instrument performance
202(6)
Splitting hairs -- archaeological applications of ICP-MS
208(7)
PART III SOME BASIC CHEMISTRY FOR ARCHAEOLOGISTS
215(107)
Atoms, Isotopes, Electron Orbitals, and the Periodic Table
217(32)
The discovery of subatomic particles
217(10)
The Bohr-Rutherford model of the atom
227(3)
Stable and radioactive isotopes
230(8)
The quantum atom
238(5)
The periodic table
243(6)
Valency, Bonding, and Molecules
249(26)
Atoms and molecules
249(4)
Bonds between atoms
253(5)
Intermolecular bonds
258(2)
Lewis structures and the shapes of molecules
260(3)
Introduction to organic compounds
263(6)
Isomers
269(6)
The Electromagnetic Spectrum
275(19)
Electromagnetic waves
275(4)
Particle wave duality
279(2)
Emission lines and the Rydberg equation
281(5)
Absorption of EM radiation by matter Beer's law
286(2)
The EM spectrum and spectrochemical analysis
288(2)
Synchrotron radiation
290(4)
Practical Issues in Analytical Chemistry
294(28)
Some basic procedures in analytical chemistry
294(8)
Sample preparation for trace element and residue analysis
302(4)
Standards for calibration
306(3)
Calibration procedures and estimation of errors
309(10)
Quality assurance procedures
319(3)
Epilogue
322(4)
Appendices
326(24)
Scientific notation
326(1)
Significant figures
327(1)
Seven basic SI units
328(1)
Physical constants
329(1)
Greek notation
330(1)
Chemical symbols and isotopes of the elements
331(4)
Electronic configuration of the elements (to radon. Z 86)
335(2)
Some common inorganic and organic sample preparation methods used in archaeology
337(3)
General safe practice in the laboratory
340(2)
COSHH assessments
342(8)
References 350(41)
Index 391


Mark Pollard is Edward Hall Professor of Archaeological Science, Research Laboratory for Archaeology, University of Oxford. Cathy Batt is Senior Lecturer in Archaeological Sciences, University of Bradford. Ben Stern is Lecturer in Archaeological Sciences, University of Bradford. Suzanne M. M. Young is NASA Researcher and Lecturer in Chemistry at Tufts University.