Preface |
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xix | |
1 Sorbent-Based Microextraction Techniques for the Analysis of Phthalic Acid Esters in Water Samples |
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1 | (62) |
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Miguel Angel Gonzalez-Curbelo |
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2 | (4) |
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1.2 Solid-Phase Microextraction |
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6 | (19) |
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1.3 Stir Bar Sorptive Extraction |
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25 | (1) |
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1.4 Solid-Phase Extraction |
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26 | (22) |
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1.5 Others Minor Sorbent-Based Microextraction Techniques |
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48 | (4) |
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52 | (1) |
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53 | (1) |
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53 | (10) |
2 Occurrence, Human Health Risks, and Removal of Pharmaceuticals in Aqueous Systems: Current Knowledge and Future Perspectives |
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63 | (40) |
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64 | (1) |
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2.2 Occurrence and Behavior of Pharmaceutics in Aquatic Systems |
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65 | (8) |
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65 | (2) |
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2.2.2 Dissemination and Occurrence in Aquatic Systems |
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67 | (4) |
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2.2.3 Behaviour in Aquatic Systems |
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71 | (2) |
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2.3 Human Health Risks and Their Mitigation |
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73 | (15) |
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2.3.1 Human Exposure Pathways |
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73 | (1) |
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2.3.2 Potential Human Health Risks |
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74 | (7) |
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2.3.3 Human Health Risks: A Developing World Perspective |
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81 | (1) |
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2.3.4 Removal of Pharmaceuticals |
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82 | (6) |
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2.3.4.1 Conventional Removal Methods |
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83 | (2) |
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2.3.4.2 Advanced Removal Methods |
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85 | (3) |
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2.3.4.3 Hybrid Removal Processes |
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88 | (1) |
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2.4 Knowledge Gaps and Future Research Directions |
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88 | (2) |
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2.4.1 Increasing Africa's Research Footprint |
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88 | (1) |
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2.4.2 Hotspot Sources and Reservoirs |
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89 | (1) |
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2.4.3 Behavior and Fate in Aquatic Systems |
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89 | (1) |
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2.4.4 Ecotoxicology of Pharmaceuticals and Metabolites |
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89 | (1) |
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2.4.5 Human Exposure Pathways |
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89 | (1) |
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2.4.6 Human Toxicology and Epidemiology |
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90 | (1) |
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2.4.7 Removal Capacity of Low-Cost Water Treatment Processes |
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90 | (1) |
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2.5 Summary, Conclusions, and Outlook |
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90 | (1) |
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91 | (1) |
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91 | (12) |
3 Oil-Water Separations |
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103 | (22) |
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103 | (3) |
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3.2 Sources and Composition |
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106 | (1) |
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3.3 Common Oil-Water Separation Techniques |
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106 | (1) |
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3.4 Oil-Water Separation Technologies |
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107 | (6) |
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3.4.1 Advancement in the Technology of Membrane |
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111 | (2) |
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3.4.1.1 Polymer-Based Membranes |
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111 | (1) |
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3.4.1.2 Ceramic-Based Membranes |
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111 | (2) |
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3.5 Separation of Oil/Water Utilizing Meshes |
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113 | (3) |
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113 | (1) |
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3.5.2 Meshes Functionalization |
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114 | (2) |
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3.5.2.1 Inorganic Materials |
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115 | (1) |
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3.5.2.2 Organic Materials |
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115 | (1) |
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3.6 Separation of Oil-Water Mixture Using Bioinspired Surfaces |
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116 | (2) |
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116 | (1) |
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3.6.2 Superhydrophilic/Phobic and Superoleophilic/Phobic Porous Surfaces |
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117 | (1) |
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118 | (1) |
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118 | (1) |
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119 | (6) |
4 Microplastics Pollution |
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125 | (14) |
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4.1 Introduction and General Considerations |
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125 | (1) |
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4.2 Key Scientific Issues Concerning Water and Microplastics Pollution |
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126 | (5) |
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4.3 Marine Microplastics: From the Anthropogenic Litter to the Plastisphere |
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131 | (2) |
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4.4 Social and Human Perspectives: From Sustainable Development to Civil Science |
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133 | (1) |
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4.5 Conclusions and Future Projections |
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134 | (1) |
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134 | (5) |
5 Chloramines Formation, Toxicity, and Monitoring Methods in Aqueous Environments |
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139 | (24) |
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140 | (1) |
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5.2 Inorganic Chloramines Formation and Toxicity |
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140 | (3) |
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5.3 Analytical Methods for Inorganic Chloramines |
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143 | (8) |
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5.3.1 Colorimetric and Batch Methods |
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144 | (4) |
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5.3.2 Chromatographic Methods |
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148 | (2) |
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5.3.3 Membrane Inlet Mass Spectrometry |
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150 | (1) |
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5.4 Organic Chloramines Formation and Toxicity |
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151 | (3) |
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5.5 Analytical Methods for Organic Chloramines |
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154 | (2) |
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156 | (1) |
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156 | (7) |
6 Clay-Based Adsorbents for the Analysis of Dye Pollutants |
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163 | (36) |
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164 | (16) |
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165 | (1) |
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165 | (1) |
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165 | (1) |
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6.1.4 Clay-Based Adsorbents |
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166 | (15) |
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166 | (2) |
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168 | (1) |
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169 | (1) |
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170 | (1) |
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170 | (1) |
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171 | (1) |
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171 | (1) |
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172 | (8) |
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180 | (1) |
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181 | (5) |
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6.3.1 Fenton and Photo-Fenton Process |
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182 | (1) |
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6.3.2 Mechanism Using Acid and Base Catalyst |
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182 | (4) |
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6.4 Photo-Catalytic Oxidation |
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186 | (2) |
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188 | (1) |
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188 | (1) |
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188 | (11) |
7 Biochar-Supported Materials for Wastewater Treatment |
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199 | (28) |
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Mohamed El Mehdi Mekhzoum |
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200 | (1) |
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7.2 Generalities of Biochar: Structure, Production, and Properties |
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201 | (11) |
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201 | (2) |
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203 | (2) |
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204 | (1) |
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204 | (1) |
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7.2.2.3 Hydrothermal Carbonization |
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205 | (1) |
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205 | (7) |
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205 | (2) |
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207 | (1) |
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7.2.3.3 Surface Functional Groups |
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207 | (3) |
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7.2.3.4 Cation Exchange Capacity |
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210 | (1) |
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210 | (2) |
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7.3 Biochar-Supported Materials |
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212 | (8) |
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7.3.1 Magnetic Biochar Composites |
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212 | (2) |
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7.3.2 Nano-Metal Oxide/Hydroxide-Biochar Composites |
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214 | (2) |
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7.3.3 Functional Nanoparticles-Coated Biochar Composites |
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216 | (4) |
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220 | (2) |
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222 | (5) |
8 Biological Swine Wastewater Treatment |
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227 | (28) |
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Aline Meireles dos Santos |
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Alberto Meireles dos Santos |
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227 | (1) |
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8.2 Swine Wastewater Characteristics |
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228 | (3) |
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8.3 Microorganisms of Biological Swine Wastewater Treatment |
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231 | (4) |
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8.4 Classification of Biological Swine Wastewater Treatment |
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235 | (1) |
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8.5 Biological Processes For Swine Wastewater Treatment |
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236 | (5) |
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8.5.1 Suspended Growth Processes |
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237 | (2) |
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8.5.1.1 Activated Sludge Process |
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237 | (1) |
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8.5.1.2 Sequential Batch Reactor |
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237 | (1) |
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8.5.1.3 Sequencing Batch Membrane Bioreactor |
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238 | (1) |
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8.5.1.4 Anaerobic Contact Process |
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238 | (1) |
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8.5.1.5 Anaerobic Digestion |
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238 | (1) |
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8.5.2 Attached Growth Processes |
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239 | (17) |
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8.5.2.1 Rotating Biological Contactor |
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239 | (1) |
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8.5.2.2 Upflow Anaerobic Sludge Blanket |
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240 | (1) |
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240 | (1) |
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8.5.2.4 Hybrid Anaerobic Reactor |
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241 | (1) |
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8.6 Challenges and Future Prospects in Swine Wastewater Treatment |
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241 | (1) |
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242 | (13) |
9 Determination of Heavy Metal Ions From Water |
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255 | (18) |
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255 | (1) |
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9.2 Detection of Heavy Metal Ions |
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256 | (11) |
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9.2.1 Atomic Absorption Spectroscopy |
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257 | (1) |
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257 | (1) |
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9.2.3 High-Resolution Surface Plasmon Resonance Spectroscopy with Anodic Stripping Voltammetry |
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258 | (1) |
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259 | (3) |
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9.2.4.1 Enzyme-Based Biosensors |
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260 | (1) |
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9.2.4.2 Electrochemical Sensors |
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261 | (1) |
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9.2.4.3 Polymer-Based Biosensors |
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261 | (1) |
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9.2.4.4 Bacterial-Based Sensors |
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262 | (1) |
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9.2.4.5 Protein-Based Sensors |
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262 | (1) |
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9.2.5 Attenuated Total Reflectance |
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262 | (1) |
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9.2.6 High-Resolution Differential Surface Plasmon Resonance Sensor |
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262 | (1) |
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263 | (1) |
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264 | (1) |
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265 | (1) |
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266 | (1) |
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266 | (1) |
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9.2.11 Macrocylic Compounds |
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266 | (1) |
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9.2.12 Inductively Coupled Plasma Mass Spectrometry |
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267 | (1) |
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267 | (1) |
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268 | (5) |
10 The Production and Role of Hydrogen-Rich Water in Medical Applications |
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273 | (26) |
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273 | (2) |
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275 | (1) |
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275 | (2) |
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10.4 Production of Hydrogen-Rich Water |
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277 | (2) |
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10.5 Mechanism Hydrogen Molecules During Reactive Oxygen Species Scavenging |
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279 | (1) |
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10.6 Hydrogen-Rich Water Effects on the Human Body |
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280 | (5) |
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10.6.1 Anti-Inflammatory Effects |
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280 | (1) |
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10.6.2 Anti-Radiation Effects |
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281 | (1) |
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10.6.3 Wound Healing Effects |
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282 | (2) |
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10.6.4 Anti-Diabetic Effects |
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284 | (1) |
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10.6.5 Anti-Neurodegenerative Effects |
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285 | (1) |
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10.6.6 Anti-Cancer Effects |
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285 | (1) |
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10.6.7 Anti-Arteriosclerosis Effects |
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285 | (1) |
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10.7 Other Effects of Hydrogenated Water |
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285 | (1) |
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10.7.1 Effect of Hydrogen-Rich Water in Hemodialysis |
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285 | (1) |
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10.7.2 Effect on Anti-Cancer Drug Side Effects |
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286 | (1) |
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10.8 Applications of Hydrogen-Rich Water |
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286 | (4) |
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286 | (2) |
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288 | (1) |
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10.8.3 In Therapeutic Applications and Delayed Progression of Diseases |
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289 | (1) |
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10.9 Safety of Using Hydrogen-Rich Water |
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290 | (1) |
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291 | (1) |
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292 | (7) |
11 Hydrosulphide Treatment |
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299 | (32) |
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300 | (25) |
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302 | (5) |
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307 | (8) |
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315 | (10) |
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325 | (1) |
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326 | (5) |
12 Radionuclides: Availability, Effect, and Removal Techniques |
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331 | (30) |
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332 | (8) |
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12.1.1 Available Radionuclides in the Environment |
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333 | (4) |
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333 | (1) |
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12.1.1.2 Thorium (Z = 90) |
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334 | (1) |
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335 | (1) |
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336 | (1) |
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12.1.1.5 Polonium and Lead |
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336 | (1) |
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12.1.2 Presence of Radionuclide in Drinking Water |
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337 | (3) |
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12.1.2.1 Health Impacts of Radionuclides |
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338 | (1) |
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12.1.2.2 Health Issues Caused Due to Uranium |
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338 | (1) |
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12.1.2.3 Health Issues Caused Due to Radium |
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339 | (1) |
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12.1.2.4 Health Issues Caused Due to Radon |
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339 | (1) |
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12.1.2.5 Health Issues Caused Due to Lead and Polonium |
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339 | (1) |
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12.2 Existing Techniques and Materials Involved in Removal of Radionuclide |
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340 | (8) |
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340 | (1) |
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340 | (1) |
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341 | (1) |
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12.2.4 Granulated Activated Carbon |
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341 | (1) |
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342 | (1) |
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12.2.6 Lime Softening, Coagulation, and Co-Precipitation |
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342 | (1) |
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343 | (1) |
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343 | (1) |
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12.2.9 Greensand Filteration |
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344 | (1) |
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344 | (3) |
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12.2.10.1 Radionuclides Sequestration by MOFs |
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344 | (1) |
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12.2.10.2 Radionuclides Removal by COFs |
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345 | (1) |
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12.2.10.3 Elimination of Radionuclides by GOs |
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346 | (1) |
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12.2.10.4 Radionuclide Sequestration by CNTs |
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346 | (1) |
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347 | (1) |
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12.3 Summary of Various Nanomaterial and Efficiency of Water Treating Technology |
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348 | (1) |
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12.4 Management of Radioactive Waste |
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348 | (2) |
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350 | (1) |
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350 | (11) |
13 Applications of Membrane Contactors for Water Treatment |
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361 | (22) |
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362 | (1) |
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13.2 Characteristics of Membrane Contactors |
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362 | (3) |
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13.3 Membrane Module Configurations |
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365 | (1) |
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13.4 Mathematical Aspects of Membrane Contactors |
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366 | (1) |
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13.5 Advantages and Limitations of Membrane Contactors |
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367 | (3) |
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367 | (2) |
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13.5.1.1 High Interfacial Contact |
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368 | (1) |
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13.5.1.2 Absence of Flooding and Loading |
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368 | (1) |
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13.5.1.3 Minimization of Back Mixing and Emulsification |
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368 | (1) |
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13.5.1.4 Freedom for Solvent Selection |
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368 | (1) |
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13.5.1.5 Reduction in Solvent Inventory |
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368 | (1) |
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369 | (1) |
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369 | (1) |
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13.6 Membrane Contactors as Alternatives to Conventional Unit Operations |
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370 | (4) |
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13.6.1 Liquid-Liquid Extraction |
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370 | (1) |
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13.6.2 Membrane Distillation |
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370 | (2) |
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13.6.3 Osmotic Distillation |
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372 | (1) |
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13.6.4 Membrane Crystallization |
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372 | (1) |
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13.6.5 Membrane Emulsification |
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372 | (1) |
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13.6.6 Supported Liquid Membranes |
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373 | (1) |
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13.6.7 Membrane Bioreactors |
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373 | (1) |
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374 | (3) |
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13.7.1 Wastewater Treatment |
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374 | (1) |
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13.7.2 Metal Recovery From Aqueous Streams |
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375 | (1) |
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375 | (1) |
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13.7.4 Concentration of Products in Food and Biotechnological Industries |
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375 | (1) |
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13.7.5 Gaseous Stream Treatment |
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376 | (1) |
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376 | (1) |
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13.8 Conclusions and Future Prospects |
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377 | (1) |
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378 | (5) |
14 Removal of Sulfates From Wastewater |
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383 | (18) |
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383 | (1) |
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14.2 Effect of Sulfate Contamination on Human Health |
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384 | (1) |
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14.3 Groundwater Distribution of Sulfate |
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384 | (1) |
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14.4 Traditional Methods for Sulfate Removal |
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385 | (2) |
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14.4.1 Treatment With Lime |
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385 | (1) |
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14.4.2 Treatment With Limestone |
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386 | (1) |
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387 | (1) |
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14.5 Modern Day's Technique for Sulfate Removal |
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387 | (7) |
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387 | (1) |
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14.5.2 Electrocoagulation |
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388 | (1) |
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14.5.3 Precipitation Methods |
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389 | (2) |
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391 | (1) |
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392 | (1) |
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14.5.6 Biological Treatment |
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393 | (1) |
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14.5.7 Removal of Sulfate by Crystallization |
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394 | (1) |
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14.6 Conclusions and Future Perspective |
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394 | (1) |
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395 | (1) |
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395 | (6) |
15 Risk Assessment on Human Health With Effect of Heavy Metals |
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401 | (20) |
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402 | (1) |
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15.2 Toxic Effects Heavy Metals on Human Health |
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403 | (3) |
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15.3 Biomarkers and Bio-Indicators for Evaluation of Heavy Metal Contamination |
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406 | (11) |
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407 | (1) |
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407 | (1) |
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15.3.3 Daily Intake of Metal |
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408 | (1) |
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15.3.4 The Bioaccumulation Factor |
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409 | (1) |
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15.3.5 Translocation Factor |
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410 | (1) |
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410 | (2) |
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15.3.7 Metal Pollution Index |
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412 | (1) |
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412 | (1) |
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15.3.9 Pollution Load Index |
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412 | (1) |
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15.3.10 Index of Geo-Accumulation |
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413 | (1) |
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15.3.11 Potential Risk Index |
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413 | (1) |
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15.3.12 Exposure Assessment |
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414 | (1) |
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15.3.13 Carcinogenic Risk |
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415 | (2) |
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417 | (4) |
16 Water Quality Monitoring and Management: Importance, Applications, and Analysis |
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421 | (20) |
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16.1 Qualitative Analysis: An Introduction to Basic Concept |
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422 | (1) |
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16.2 Significant Applications of Qualitative Analysis |
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422 | (5) |
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424 | (2) |
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16.2.2 Water Quality Index |
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426 | (1) |
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16.3 Qualitative Analysis of Water |
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427 | (7) |
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16.3.1 Sampling Procedure |
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428 | (1) |
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16.3.2 Sample Transportation and Preservation |
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429 | (2) |
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16.3.3 Some Important Physico-Chemical Parameters of Water Quality |
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431 | (3) |
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16.4 Existing Water Quality Standards |
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434 | (1) |
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16.5 Quality Assurance and Quality Control |
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435 | (2) |
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437 | (1) |
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437 | (4) |
17 Water Quality Standards |
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441 | (28) |
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442 | (1) |
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17.2 Chemical Standards for Water Quality |
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443 | (8) |
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17.2.1 Physical Standards |
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443 | (2) |
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17.2.2 Chemical Standards for Salt Water Quality |
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445 | (1) |
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17.2.3 Biological Standards |
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446 | (1) |
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17.2.4 Radiation Standards |
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447 | (1) |
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17.2.5 Wastewater and Water Quality |
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447 | (4) |
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17.3 Inorganic Substances and Their Effect on Palatability and Household Uses |
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451 | (6) |
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451 | (1) |
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451 | (1) |
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452 | (1) |
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452 | (5) |
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17.4 The Philosophy of Setting Standards for Drinking Water (Proportions and Concentrations of Water Components) |
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457 | (1) |
|
17.5 Detection of Polychlorinated Biphenyls |
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|
458 | (1) |
|
17.6 The Future Development of Water Analysis |
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|
459 | (1) |
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|
460 | (1) |
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|
460 | (9) |
18 Qualitative and Quantitative Analysis of Water |
|
469 | (34) |
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|
|
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|
469 | (1) |
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|
470 | (2) |
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|
472 | (4) |
|
18.3.1 Physical Parameters |
|
|
472 | (1) |
|
18.3.2 Chemical Parameters |
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|
472 | (2) |
|
18.3.3 Biological Parameters |
|
|
474 | (1) |
|
18.3.4 Water Quality Index |
|
|
474 | (2) |
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18.4 Factors Affecting the Quality of Surface Water |
|
|
476 | (1) |
|
18.5 Quantitative Analysis of the Organic Content of the Wastewater |
|
|
477 | (6) |
|
18.5.1 Biochemical Oxygen Demand |
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|
477 | (3) |
|
18.5.1.1 DO Profile Curve in BOD Test |
|
|
478 | (1) |
|
18.5.1.2 Significance of BOD Test |
|
|
479 | (1) |
|
18.5.1.3 Nitrification in BOD Test |
|
|
480 | (1) |
|
18.5.2 Chemical Oxygen Demand |
|
|
480 | (2) |
|
18.5.3 Theoretical Oxygen Demand (ThOD) |
|
|
482 | (1) |
|
18.6 Treatment of Wastewater |
|
|
483 | (9) |
|
18.6.1 Primary Treatment Method |
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|
484 | (1) |
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|
484 | (1) |
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|
484 | (1) |
|
18.6.2 Secondary Treatment |
|
|
485 | (3) |
|
18.6.2.1 Aerobic Biological Process |
|
|
485 | (1) |
|
18.6.2.2 Anaerobic Biological Treatment |
|
|
485 | (2) |
|
18.6.2.3 Activated Sludge Process |
|
|
487 | (1) |
|
18.6.3 Tertiary Treatment |
|
|
488 | (4) |
|
18.6.3.1 Nutrients Removal |
|
|
488 | (2) |
|
18.6.3.2 Phosphorus Removal |
|
|
490 | (1) |
|
18.6.3.3 Ion-Exchange Process |
|
|
490 | (1) |
|
18.6.3.4 Membrane Process |
|
|
491 | (1) |
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|
491 | (1) |
|
|
491 | (1) |
|
18.7 Instrumental Analysis of Wastewater Parameters |
|
|
492 | (5) |
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|
492 | (1) |
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|
492 | (1) |
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|
493 | (1) |
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|
493 | (1) |
|
18.7.5 Total Dissolved Solids |
|
|
494 | (1) |
|
18.7.6 Total Organic Carbon |
|
|
494 | (1) |
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|
495 | (1) |
|
18.7.8 Atomic Absorption Spectroscopy |
|
|
495 | (1) |
|
18.7.9 Inductive Coupled Plasma-Mass Spectroscopy |
|
|
496 | (1) |
|
18.7.10 Gas Chromatography With Mass Spectroscopy |
|
|
497 | (1) |
|
18.8 Methods for Qualitative Determination of Water |
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|
497 | (3) |
|
18.8.1 Weight Loss Method |
|
|
497 | (1) |
|
18.8.2 Karl Fischer Method |
|
|
498 | (1) |
|
18.8.3 Fourier Transform Infrared Spectroscopy Method |
|
|
499 | (1) |
|
18.8.4 Nuclear Magnetic Resonance Spectroscopy Method |
|
|
499 | (1) |
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|
500 | (1) |
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|
500 | (3) |
19 Nanofluids for Water Treatment |
|
503 | (22) |
|
Charles Oluwaseun Adetunji |
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|
504 | (1) |
|
19.2 Types of Nanofluids Used in the Treatment of Water |
|
|
505 | (11) |
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19.2.1 Zero-Valent Metal Nanoparticles |
|
|
505 | (2) |
|
19.2.1.1 Silver Nanoparticles (AgNPs) |
|
|
505 | (1) |
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19.2.1.2 Iron Nanoparticles |
|
|
506 | (1) |
|
19.2.1.3 Zinc Nanoparticles |
|
|
507 | (1) |
|
19.2.2 Metal Oxides Nanoparticles |
|
|
507 | (2) |
|
19.2.2.1 Tin Dioxide (TiO2) Nanoparticles |
|
|
507 | (1) |
|
19.2.2.2 Zinc Oxide Nanoparticles (ZnO NPs) |
|
|
508 | (1) |
|
19.2.2.3 Iron Oxides Nanoparticles |
|
|
508 | (1) |
|
|
509 | (1) |
|
19.2.4 Nanocomposite Membranes |
|
|
509 | (1) |
|
19.2.5 Modes of Action of These Nanofluids |
|
|
509 | (7) |
|
19.2.5.1 Carbon-Based Nano-Adsorbents (CNTs) for Organic Expulsion |
|
|
509 | (1) |
|
19.2.5.2 Heavy Metal Removal |
|
|
510 | (1) |
|
19.2.5.3 Metal-Based Nano-Adsorbents |
|
|
510 | (1) |
|
19.2.5.4 Polymeric Nano-Adsorbents |
|
|
511 | (1) |
|
19.2.5.5 Nanofiber Membranes |
|
|
511 | (1) |
|
19.2.5.6 Some Applications of Nanofluids in the Treatment of Water |
|
|
512 | (1) |
|
19.2.5.7 Informatics and AI Nanofluid-Enhanced Water Treatment |
|
|
513 | (3) |
|
19.3 Conclusion and Recommendation to Knowledge |
|
|
516 | (1) |
|
|
516 | (9) |
Index |
|
525 | |