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El. knyga: Bioenergy Systems for the Future: Prospects for Biofuels and Biohydrogen

Edited by (Chemistry Department, University of Calabria, Italy), Edited by (Senior Researcher, ITM-CNR, University of Calabria, Italy), Edited by (Professor, Department of Biotechnology, Chemistry and Pharmacy, University of Siena, Italy)
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Bioenergy Systems for the Future: Prospects for Biofuels and Biohydrogen examines the current advances in biomass conversion technologies for biofuels and biohydrogen production, including their advantages and challenges for real-world application and industrial-scale implementation.

In its first part, the book explores the use of lignocellulosic biomass and agricultural wastes as feedstock, also addressing biomass conversion into biofuels, such as bioethanol, biodiesel, bio-methane, and bio-gasoline. The chapters in Part II cover several different pathways for hydrogen production, from biomass, including bioethanol and bio-methane reforming and syngas conversion. They also include a comparison between the most recent conversion technologies and conventional approaches for hydrogen production.

Part III presents the status of advanced bioenergy technologies, such as applications of nanotechnology and the use of bio-alcohol in low-temperature fuel cells. The role of advanced bioenergy in a future bioeconomy and the integration of these technologies into existing systems are also discussed, providing a comprehensive, application-oriented overview that is ideal for engineering professionals, researchers, and graduate students involved in bioenergy.

  • Explores the most recent technologies for advanced liquid and gaseous biofuels production, along with their advantages and challenges
  • Presents real-life application of conversion technologies and their integration in existing systems
  • Includes the most promising pathways for sustainable hydrogen production for energy applications

Daugiau informacijos

Recent advances, challenges, and future perspectives for the liquid and gaseous biofuels industry
List of contributors
xi
Preface xv
Section A Biomass to bioenergy
1(184)
1 Biomass: An overview
3(40)
C. Bonechi
M. Consumi
A. Donati
G. Leone
A. Magnani
G. Tamasi
C. Rossi
1.1 Introduction
3(2)
1.2 Chemical characterisation of biomass
5(13)
1.3 Agriculture and forestry biomass for energy production
18(6)
1.4 Energy from biomass, a resource to exploit
24(16)
1.5 Conclusions
40(3)
Acknowledgments
40(1)
References
40(1)
Further Reading
41(2)
2 Technological aspects of nonfood agricultural lignocellulose transformations
43(18)
H. Honkanen
J. Kataja
Abbreviations
43(1)
2.1 Introduction
43(1)
2.2 Material flows of biomasses from agriculture
43(5)
2.3 Energy use pathways of biomasses from agriculture
48(10)
2.4 Conclusions
58(3)
References
58(1)
Further Reading
59(2)
3 Production of bioalcohol and biomethane
61(26)
K. Ghasemzadeh
E. Jalilnejad
A. Basile
Abbreviations
61(1)
3.1 Introduction
61(1)
3.2 Biofuels
62(18)
3.3 Membrane processes for biofuels production
80(3)
3.4 Conclusion and future trends
83(4)
References
83(3)
Further Reading
86(1)
4 Light olefins/bio-gasoline production from biomass
87(62)
A. Bakhtyari
M.A. Makarem
M.R. Rahimpour
4.1 Introduction
87(1)
4.2 Gasoline and olefins
88(1)
4.3 Why bio-gasoline and bio-olefin?
89(1)
4.4 Feedstocks obtained from biomass
90(1)
4.5 Routes to bio-olefin and bio-gasoline
91(5)
4.6 Gasification
96(1)
4.7 Bio-oil upgrading
97(1)
4.8 Hydrodeoxygenation
97(5)
4.9 Catalytic upgrading
102(2)
4.10 Biomass/bio-oil to olefins
104(10)
4.11 Glycerol to olefins
114(3)
4.12 Biomass/bio-oil to gasoline
117(17)
4.13 Catalyst deactivation and coke formation
134(2)
4.14 Food vs fuel
136(1)
4.15 Conclusion, further studies, and outlook
136(13)
References
136(12)
Further Reading
148(1)
5 Anaerobic biodigestion for enhanced bioenergy generation in ethanol biorefineries: Understanding the potentials of vinasse as a biofuel
149(36)
L.T. Fuess
M.L. Garcia
5.1 Introduction
150(3)
5.2 Vinasse characterization: Suitability for bioenergy generation
153(1)
5.3 Bioenergy generation from vinasse: Input data and estimates
154(8)
5.4 Potentials of vinasse as a bioenergy source
162(12)
5.5 Outlook: Prospects for AD as the core treatment technology in ethanol plants
174(2)
5.6 Concluding remarks
176(9)
Acknowledgments
176(1)
References
177(8)
Section B Hydrogen production
185(234)
6 Thermodynamic analysis of ethanol reforming for hydrogen production
187(30)
G. Tamasi
C. Bonechi
A. Magnani
G. Leone
A. Donati
S. Pepi
C. Rossi
6.1 Introduction
187(8)
6.2 Calculation method
195(1)
6.3 Analysis of thermodynamic properties for the single reactions
196(16)
6.4 Conclusion
212(5)
Acknowledgments
212(1)
References
212(5)
7 Catalysts for conversion of synthesis gas
217(62)
V. Palma
C. Ruocco
M. Martino
E. Meloni
A. Ricca
7.1 Introduction
218(2)
7.2 Fischer-Tropsch synthesis
220(25)
7.3 Methanol synthesis
245(9)
7.4 NH3 synthesis
254(6)
7.5 Other Processes
260(19)
References
265(14)
8 Distributed H2 production from bioalcohols and biomethane in conventional steam reforming units
279(42)
A. Vita
C. Italiano
L. Pino
8.1 Introduction
280(3)
8.2 Biomass feedstocks: routes and technologies for biofuels generation
283(7)
8.3 Biofuels reforming for distributed hydrogen production
290(7)
8.4 Novel catalytic formulations for steam reforming process
297(17)
8.5 Conclusion
314(7)
References
314(6)
Web List
320(1)
9 H2 production from bioalcohols and biomethane steam reforming in membrane reactors
321(24)
A. Iulianelli
F. Dalena
A. Basile
Abbreviations
321(1)
Symbols
321(1)
9.1 Introduction
322(1)
9.2 Inorganic MRs
323(6)
9.3 Hydrogen production in MRs from bio-alcohols reforming
329(8)
9.4 Conclusions
337(8)
References
339(5)
Further Reading
344(1)
10 Formation of hydrogen-rich gas via conversion of lignocellulosic biomass and its decomposition products
345(28)
J. Grams
A.M. Ruppert
10.1 Introduction
345(1)
10.2 High-temperature conversion of lignocellulosic biomass towards hydrogen rich gas
345(13)
10.3 Hydrogen not only as a source of energy
358(2)
10.4 Catalysts used for FA decomposition
360(4)
10.5 Decomposition of formic acid to hydrogen and subsequent hydrogenation reaction
364(1)
10.6 Summary
365(8)
References
366(7)
11 Advancements and confinements in hydrogen production technologies
373(46)
S. Nanda
K. Li
N. Abatzoglou
A.K. Dalai
J.A. Kozinski
11.1 Introduction
373(2)
11.2 Hydrogen generation technologies
375(17)
11.3 Advancements in hydrogen production technologies
392(11)
11.4 Confinements in hydrogen production technologies
403(6)
11.5 Conclusion and future prospects
409(10)
Acknowledgements
410(1)
References
410(9)
Section C Bioenergy technology aspects/status
419(182)
12 Nanocomposites for "nano green energy" applications
421(30)
Liangdong Fan
Muhammad Afzal
Chuanxin He
Bin Zhu
12.1 Introduction
422(3)
12.2 Nanocomposite electrolytes
425(10)
12.3 Nanocomposite anodes
435(4)
12.4 Nanocomposite cathodes
439(4)
12.5 Conclusions and outlook
443(8)
Acknowledgments
444(1)
References
444(7)
13 Integration of membrane technologies into conventional existing systems in the food industry
451(30)
A. Cassano
C. Conidi
13.1 Introduction
452(1)
13.2 Fruit juice processing
453(6)
13.3 Wine processing
459(4)
13.4 Agrofood wastewaters
463(11)
13.5 Conclusions and future trends
474(7)
References
475(6)
14 Integration of microalgae into an existing biofuel industry
481(40)
M.R. Rahimpour
P. Biniaz
M.A. Makarem
14.1 Introduction
481(3)
14.2 An introduction to microalgae
484(7)
14.3 From biomass to extracted oil sequence
491(9)
14.4 Biofuel production
500(5)
14.5 Conclusion
505(16)
References
508(13)
15 Low-temperature solid oxide fuel cells with bioalcohol fuels
521(20)
Rizwan Raza
Muhammad Kaleem Ullah
Muhammad Afzal
Asia Rafique
Amjad Ali
Sarfraz Arshad
Bin Zhu
15.1 Introduction
522(6)
15.2 Case study of the research
528(9)
15.3 Case study of the application
537(1)
15.4 Conclusion
537(4)
References
538(3)
16 Biomass gasification producer gas cleanup
541(18)
S. Adhikari
N. Abdoulmoumine
H. Nam
O. Oyedeji
16.1 Introduction
541(1)
16.2 Producer gas impurities
541(3)
16.3 Operating conditions and their implications on producer gas impurities
544(3)
16.4 Producer gas cleanup
547(4)
16.5 Producer gas regulations and gas clean-up system (BAT plan)
551(8)
References
555(4)
17 Bioenergy production from second- and third-generation feedstocks
559(42)
F. Dalena
A. Senatore
A. Tursi
A. Basile
17.1 Introduction
560(2)
17.2 ABE process
562(3)
17.3 Second generation feedstocks
565(9)
17.4 Third generation feedstocks
574(16)
17.5 Conclusion and future trends
590(11)
References
591(10)
Index 601
Francesco Dalena, degree in Chemistry with Ph.D. on Translational medicine” at the Chemistry Department of the University of Calabria (Italy), is expert in "Chemistry of advanced materials". His research field ranges from the bioenergy sector to inorganic membrane reactors, to chemical kinetics and to the chemistry of artistic masterpiece. He is editor of various books, such as: "Hydrogen Production, Separation and Purification for Energy", 2016, IET Pub.; "Alcohol and bioalcohol: characteristic, proprieties and use", 2014, Nova Pub., Methanol: Science and Engineering”, Elsevier Pub. Angelo Basile, a Chemical Engineer with a Ph.D. in Technical Physics, was a senior Researcher at the ITM-CNR as a responsible for the research related to both ultra-pure hydrogen production and CO2 capture using Pd-based Membrane Reactors. He is a reviewer for 165 int. journals, an editor/author of more than 50 scientific books and 140 chapters on international books on membrane science and technology; with various patens (7 Italian, 2 European, and 1 worldwide). He is a referee of 1more than 150 international scientific journals and a Member of the Editorial Board of more than 20 of them. Basile is also an associate editor of the: Int. J. Hydrogen Energy; Asia-Pacific Journal of Chemical Eng.; journal Frontiers in Membrane Science and Technology; and co-Editor-in-chief of the Int. J. Membrane Science & Technol.



Claudio Rossi is full professor of Physical Chemistry at the Department of Biotechnology, Chemistry and Pharmacy of the University of Siena, coordinator of the NMR spectroscopy activity and responsible for the University of Siena of the research in the Agrifood sector. He has authored more than 200 scientific publications in qualified international journals and co-authored 2 Italian patents. Referee of numerous scientific journals in the field of Pure and Applied Chemistry. Claudio Rossi was the coordinator of six European projects funded by EU. He was the Director of the Department of Chemical and Biosystem Sciences of the University of Siena in the period 2002-2008. He was tutor of numerous students during the preparation of their PhD thesis and Master.
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