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Biopolymer Grafting: Applications [Minkštas viršelis]

(Cranfield University UK)
  • Formatas: Paperback / softback, 540 pages, aukštis x plotis: 235x191 mm, weight: 1110 g
  • Serija: Advances in Polymers and Fibers
  • Išleidimo metai: 21-Sep-2017
  • Leidėjas: Elsevier Science Publishing Co Inc
  • ISBN-10: 0128104627
  • ISBN-13: 9780128104620
Kitos knygos pagal šią temą:
Biopolymer Grafting: ApplicationsDidesnis paveikslėlis
  • Formatas: Paperback / softback, 540 pages, aukštis x plotis: 235x191 mm, weight: 1110 g
  • Serija: Advances in Polymers and Fibers
  • Išleidimo metai: 21-Sep-2017
  • Leidėjas: Elsevier Science Publishing Co Inc
  • ISBN-10: 0128104627
  • ISBN-13: 9780128104620
Kitos knygos pagal šią temą:
Pastovi nuoroda: https://www.kriso.lt/db/9780128104620.html
Raktažodžiai:

Biopolymer Grafting: Applications presents the latest research and developments in the practical application of these methods in industry, both to enable polymer scientists and engineers to keep up with the latest research trends, as well as to propose ideas for further research and application. Research into bio-based polymers has become increasingly prevalent. However, due to challenges related to the properties of these materials compared to synthetic polymers-such as their resistance to chemicals or weather-uptake has not dramatically increased yet.

As a result, improvements in surface modification of bio-polymers through graft copolymerization are enormously important, because they will widen the scope of their applications. Relevant industries for application of these methods include automotive, construction, food, packaging, agriculture, textiles and paper. This book provides an overview of the developments made in the area of biopolymer-based graft polymers. Advantages, disadvantages and suggestions for future works are discussed, assisting materials scientists and researchers in mapping out the future of these new "green" materials through value addition to enhance their use.

  • Helps researchers and product developers understand the applications and limitations of biopolymer copolymers or copolymers of natural polymers
  • Offers a roadmap to future applications development in a range of different industries, including automotive, biomedical and packaging
  • Increases familiarity with a range of biopolymer grafting processes, enabling materials scientists and engineers to improve material properties and widen the range of potential biopolymer applications

Daugiau informacijos

The latest research and development in applications of biopolymer grafting methods-a roadmap for applications development in a range of industries
List of Contributors
xv
About the Editor xvii
Preface xix
Chapter 1 Applications of Graft Copoiymerization: A Revolutionary Approach
1(44)
Anupama Setia
1 Introduction
1(44)
1.1 Graft Copoiymerization
3(1)
1.2 Concept of Molecular Brushes
3(1)
1.3 Approaches for Graft Copoiymerization
4(16)
1.4 Applications
20(12)
1.5 Conclusion
32(1)
References
32(13)
Chapter 2 Grafting of Hydroxyapatite for Biomedical Applications
45(36)
Pau Turon
Luis J. del Valle
Carlos Aleman
Jordi Puiggali
1 Introduction
45(1)
2 Control of Size and Morphology of Hydroxyapatite Crystals: Ion Substitution of Hydroxyapatite
46(3)
3 Hydroxyapatite Exfoliated Nanoplates by Surface Modification
49(1)
4 Surface Modification of Hydroxyapatite to Improve Protein Adsorption
50(1)
5 Antibacterial Coatings for Hydroxyapatite Particles
51(2)
6 Scaffolds and Membranes Based on Electrospun Nanofibers Containing Hydroxyapatite
53(3)
7 Polymer Grafting on Hydroxyapatite Surfaces
56(7)
8 Cross-Linked Structures Based on Hydroxyapatite Surfaces
63(5)
9 Conclusions
68(13)
Acknowledgments
70(1)
References
70(11)
Chapter 3 Grafting of Hydrophilic Monomers Onto Cellulosic Polymers for Medical Applications
81(34)
Nursel Pekel Bayramgil
1 Introduction
81(2)
2 Modifications of Cellulosic Polymers
83(10)
2.1 Grafting
85(2)
2.2 Commonly Used Monomers for Grafting Onto Cellulose
87(6)
3 Basic Medical Applications of Hydrophilic Monomer Grafted Cellulosic Polymers
93(15)
3.1 Drug Delivery
93(4)
3.2 Hemodialysis
97(5)
3.3 Platelet Adhesion
102(2)
3.4 Antimicrobial Activity
104(2)
3.5 Others
106(2)
4 Conclusion
108(7)
References
108(6)
Further Reading
114(1)
Chapter 4 Surface Functionalization With Biopolymers via Plasma-Assisted Surface Grafting and Plasma-Induced Graft Polymerization-Materials for Biomedical Applications
115(38)
Agnieszka Kyziot
Karol Kyziot
1 Introduction
115(2)
2 Fundamentals of Grafting Techniques
117(6)
2.1 Grafting Polymerization
119(1)
2.2 "Grafting From", "Grafting to", and "Grafting Through" Approaches
120(3)
3 Surface Modification of Biomaterials by Grafting Techniques
123(14)
3.1 Factors Influencing the Properties of Surfaces With Grafted Biopolymers
124(6)
3.2 Biocompatibility of Functionalized Surfaces
130(4)
3.3 Surface Modifications Imparting Drug Delivery Functionality
134(3)
4 Surface Functionalization of Biomaterials by Plasma-Induced Grafting Polymerization
137(6)
5 Conclusions and Future Perspectives
143(10)
References
145(8)
Chapter 5 Synthesis and Application as Programmable Water Soluble Adhesive of Polyacrylamide Grafted Gum Tragacanth (GT-g-PAM)
153(52)
Pinki Pal
Jay Prakash Pandey
Gautam Sen
1 Introduction
153(20)
1.1 Classification of Polymers
155(1)
1.2 Chemical Bonding in Polymers
155(1)
1.3 Types of Primary Bonds
156(1)
1.4 Secondary Bonding Forces
156(1)
1.5 Synthetic Versus Natural Polymer
157(1)
1.6 Gum Tragacanth
158(1)
1.7 Grafting: A Promising Technique for Modification
159(2)
1.8 Methods of Graft Copoiymerization
161(7)
1.9 Microwave Radiation: A Viable Case
168(1)
1.10 The Present Study: Microwave-Assisted Method of Graft Copoiymerization
169(1)
1.11 Adhesive
169(1)
1.12 Theories of Adhesion
169(4)
2 Experimental
173(13)
2.1 Materials
173(1)
2.2 Synthesis of GT-g-PAM by Microwave-Assisted Process
173(2)
2.3 Characterization
175(1)
2.4 Instrumental Analysis
176(1)
2.5 Fourier Transform Infrared Spectrophotometry
177(5)
2.6 Investigation of Adhesive Property of Graft Copolymer
182(4)
3 Results and Discussions
186(12)
3.1 Synthesis of GT-g-PAM by Microwave-Assisted Process
186(4)
3.2 Characterization
190(1)
3.3 Instrumental Analysis
191(2)
3.4 Determination of Adhesive Strength
193(5)
4 Conclusion
198(7)
Acknowledgments
198(1)
References
199(6)
Chapter 6 Radiation Grafting of Biopolymers and Synthetic Polymers: Synthesis and Biomedical Applications
205(46)
Victor H. Pino-Ramos
H. Ivan Melendez-Ortiz
Alejandro Ramos-Ballesteros
Emilio Bucio
1 Introduction
205(1)
2 Biopolymers
206(6)
2.1 Natural Biopolymers
206(4)
2.2 Synthetic Biopolymers
210(2)
3 Properties of Biopolymers
212(9)
3.1 Density
213(1)
3.2 Solubility
213(1)
3.3 Mechanical Properties
214(1)
3.4 Thermal Properties
215(2)
3.5 Biodegradability
217(1)
3.6 Properties of Main Petroleum-Based Biopolymers
218(3)
4 Grafting Methods Applied to Biopolymers
221(3)
4.1 Conventional Method by Chemical Means
222(1)
4.2 Microwave Method
222(2)
4.3 High Energy Radiation Methods
224(1)
5 Radiation Grafting of Biopolymers
224(8)
5.1 Radiation Grafting of Chitosan
226(2)
5.2 Radiation Grafting of Cellulose
228(3)
5.3 Radiation Grafting of Alginate
231(1)
5.4 Radiation Grafting of Gelatin
232(1)
6 Biomedical Applications
232(5)
6.1 Polymers in Biomedical Uses
233(1)
6.2 Application of Stimuli Responsive Polymers
234(3)
7 Potential Medical Devices
237(1)
7.1 Lysozyme Immobilization Onto PVC Urinary Catheters
237(1)
7.2 Functionalized Prodrug Onto Polypropylene Films for Drug Delivery of Salicylic Acid
237(1)
7.3 IPNs Grafted of N-isopropylacrylamide and Acrylic Acid Onto Polyurethane Catheters for Medical Devices
238(1)
8 Conclusions
238(13)
Acknowledgments
239(1)
References
239(12)
Chapter 7 Derivatized Chitosan: Fundamentals to Applications
251(34)
Deepali Rahangdale
Anupama Kumar
1 Introduction
251(3)
2 Modification of Chitosan
254(13)
2.1 Physical Modification
254(2)
2.2 Chemical Modification
256(11)
3 Density Functional Theory
267(2)
4 Molecular Imprinting Technique
269(1)
5 Applications
270(7)
5.1 Dye Removal
270(1)
5.2 Antibacterial Activity
271(2)
5.3 Metal Ion Removal
273(2)
5.4 Wastewater Treatment
275(2)
5.5 Biomedical Applications
277(1)
6 Conclusion
277(8)
References
278(7)
Chapter 8 Grafted Copolymerized Chitosan and Its Applications as a Green Biopolymer
285(50)
May-Yuan Wong
Bahman Amini Horri
Babak Salamatinia
1 Introduction
285(2)
2 Polyethylene Glycol-g-Chitosan
287(11)
2.1 Synthesis of Polyethylene Glycol-g-Chitosan via Schiff Base Reaction Scheme
288(1)
2.2 Synthesis of Polyethylene Glycol-g-Chitosan via Genipin Cross-Linking Reaction
289(2)
2.3 Synthesis of Semiinterpenetrating Networks Polyethylene Glycol-Chitosan via Glutaraldehyde Cross-Linking
291(1)
2.4 Synthesis of Polyethylene Glycol-Chitosan via Carbodiimide Cross-Linking
292(1)
2.5 Synthesis of Polyethylene Glycol-Chitosan Composite via Blending
292(1)
2.6 Synthesis of o-Substituted Polyethylene Glycol-o-Chitosan
293(1)
2.7 Application of Polyethylene Glycol-g-Chitosan in Immunotherapy
294(1)
2.8 Application of Polyethylene Glycol-g-Chitosan in In Vitro Cancer Model
295(1)
2.9 Application of Polyethylene Glycol-g-Chitosan in Gene Transfection Therapy
296(2)
3 Polyvinyl alcohol)-g-Chitosan
298(1)
3.1 Synthesis of Chitosan-g-Poly(vinyl alcohol) via Radiation Technique
299(1)
4 Alkylated Chitosans
299(2)
4.1 Synthesis of N-Alkylated-Grafted Chitosan (Hydroxymethylated-g-Chitosan)
300(1)
4.2 Synthesis of Disaccharide-Grafted Chitosan
300(1)
4.3 Synthesis of Amylose-Grafted Chitosan
301(1)
5 Polyacrylamide-g-Chitosan
301(11)
5.1 Synthesis of Polyacrylic Acid-g-Chitosan
301(1)
5.2 Synthesis of Polyacrylamide-g-Hydroxyethylcellulose-g-Chitosan
301(1)
5.3 Synthesis of Polyacrylate-g-Chitosan Doped Metal Ions
302(1)
5.4 Application of Polyacrylamide-Grafted Chitosan and Polyacrylic Acid--Grafted Chitosan for Adsorption of Dyes
303(1)
5.5 Application of Polyacrylate-Polyacrylamide-g-Chitosan, PAMCS in Enhanced Oil Recovery
304(1)
5.6 Synthesis of Polyacrylamide-g-Chitosan Nanobeads via Atom Transfer Radical Polymerization Approach
305(1)
5.7 Synthesis of Polyacrylamide-g-Chitosan Nanorug via "Grafting-Through" Approach
306(3)
5.8 Synthesis of Polyacrylamide-g- Polystyrene-g-Chitosan Hybrid Molecular Brush Prepared via Grafting-to Approach
309(1)
5.9 Synthesis of Hydrophobically Modified Chitosan-g-Magnetic Nanoparticles
310(1)
5.10 Synthesis of Fe3O4-Magnetic Nanoparticle-M Chitosan Nanoparticles
310(2)
6 Cyclodextrin-Linked Chitosans
312(2)
6.1 Cyclodextrins-Chitosan With Adamantane
312(1)
6.2 Chitosan-Grafted Polyethylene Glycol Methacrylate Mixed With α-CD Composite
313(1)
7 Protein-Grafted Chitosan
314(2)
7.1 Collagen-Chondroitin-Sulfate-Chitosan
314(1)
7.2 Polylysine-Grafted-Chitosan
315(1)
7.3 Polyethylene Glycol-poly(L-alanine-co-L-phenyl alanine)-Grafted Chitosan
315(1)
8 Catechol-g-Chitosan
316(1)
9 Acid-Grafted Chitosan
317(5)
9.1 Azidobenzoic-g-Chitosan Hydrogel
317(1)
9.2 Polylactic Acid-g-Chitosan
318(1)
9.3 Polymaleic Acid-g-Chitosan
319(1)
9.4 Polylactic Acid--Grafted Chitosans
319(3)
10 Others
322(5)
10.1 Chitosan-Graphene Oxide: The Making of Antimicrobial Film
322(1)
10.2 Chondroitin Sulfate-S: The Making of a Biosorbent of Caustic Dye---Containing Wastewater
322(1)
10.3 Chitosan-Glycerol Phosphate Hydrogel
323(1)
10.4 Chitosan-Alginate Hydrogel
324(1)
10.5 Polyethylene Oxide-Chitosan Blend
325(1)
10.6 Carboxymethylated Chitosan
326(1)
11 Summary
327(2)
12 Conclusion
329(6)
References
330(5)
Chapter 9 Grafting Onto Biopolymers: Application in Targeted Drug Delivery
335(56)
Saundray R. Soni
Animesh Ghosh
1 Introduction
335(6)
2 Biopolymers
341(11)
2.1 Classification of Biopolymers
341(11)
3 Biopolymers Grafting
352(7)
3.1 Grafting Strategy
352(1)
3.2 Grafting Techniques
353(6)
4 Applications as Stimuli Responsive Targeted Drug Delivery System
359(8)
4.1 Temperature Responsive Polymers: Applications in Targeted Drug Delivery System
360(3)
4.2 pH Responsive Polymers: Applications in Targeted Drug Delivery System
363(4)
5 Applications as Receptor Targeted Drug Delivery System
367(5)
5.1 Targeting via Folate Receptors
367(4)
5.2 Targeting via RGD Peptide Toward Integrin Receptors
371(1)
6 Application of Grafted Biopolymers in Controlled Drug Delivery System
372(3)
7 Concluding Remarks
375(16)
Acknowledgments
375(4)
References
379(12)
Chapter 10 Fibroin Grafting Onto Wool Fibers: Recent Advances and Applications
391(40)
Franco Ferrero
Anna Garetto
Raffaella Mossotti
Claudio Tonin
1 Introduction
391(2)
2 Grafting of Epoxy Resins Onto Wool
393(4)
3 Grafting of Epoxy Resins Onto Silk
397(3)
4 Materials
400(3)
4.1 Wool
400(1)
4.2 Fibroin
400(2)
4.3 Epoxy Resins
402(1)
5 Experimental Methods
403(3)
5.1 Laboratory Equipment
403(1)
5.2 Morphology Analyses
403(1)
5.3 Spectrophotometric and Thermal Analyses
404(1)
5.4 Determination of Amino Groups by the Ninhydrin Assay
404(1)
5.5 Epoxy Equivalent Determination
405(1)
5.6 Amino Acid Composition by High-Performance Liquid Chromatography
405(1)
6 Results and Discussion
406(20)
6.1 Grafting of Epoxides on Wool
406(11)
6.2 Fibroin Grafting on Epoxidated Wool
417(9)
7 Conclusions
426(5)
References
427(4)
Chapter 11 Grafting Modification of Wood for High Performance
431(42)
Yongfeng Li
Xiaoying Dong
1 Introduction
431(3)
2 Materials and Methods
434(4)
2.1 Materials
434(1)
2.2 Methods
435(3)
3 Grafting Modification of Wood by Polymer
438(10)
3.1 Synthesis of the Target Functional Monomer
438(2)
3.2 Grafting Modification of Wood by Copoiymerization of Glycidyl Methacrylate and the Synthesized Monomer
440(8)
4 Grafting Modification of Wood by Organic---Inorganic Hybrid Polymer Derived From the Doping Method
448(11)
5 Grafting Modification of Wood by Organic-Inorganic Hybrid Polymer Derived From the Sol-Gel Method
459(9)
6 Conclusions
468(5)
Acknowledgments
469(1)
References
469(2)
Further Reading
471(2)
Chapter 12 Processing and Characterization of Grafted Bio-composites: A Review
473(40)
Anbukarasi Kathiresan
Sivakumar Kalaiselvam
1 Introduction
473(1)
2 Graft Polymerization Process
474(32)
2.1 Grafting of Biopolymer
476(11)
2.2 Grafting of Bio-fiber
487(19)
3 Conclusion
506(7)
References
506(7)
Index 513
Vijay Kumar Thakur is Permanent Faculty in the School of Aerospace, Transport and Manufacturing Engineering, Cranfield University, UK. Previously he was a Staff Scientist in the School of Mechanical and Materials Engineering at Washington State University, USA, Research Scientist in Temasek Laboratories at Nanyang Technological University Singapore and Visiting Research Fellow in the Department of Chemical and Materials Engineering at LHU Taiwan. He spent his postdoctoral study in Materials Science & Engineering at Iowa State University, USA. He has extensive expertise in the synthesis of polymers, nano materials, nanocomposites, biocomposites, graft copolymers, high performance capacitors and electrochromic materials. He sits on the editorial board of several SCI journals.