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El. knyga: Carbon Dioxide Utilization for Global Sustainability: Proceedings of the 7th International Conference on Carbon Dioxide Utilization, Seoul, Korea, October 12-16, 2003

Edited by (Korea Research Institute of Chemical Technology, Daejeon, Korea), Edited by (Korea Research Institute of Chemical Technology, Daejeon, Korea), Edited by (Department of Chemistry, Inha University, Incheon, Korea)
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Addressing global environmental problems, such as global warming is essential to global sustainability. Continued research leads to advancement in standard methods and produces new data. Carbon Dioxide Utilization for Global Sustainability: Proceedings of the 7th ICCDU (International Conference on Carbon Dioxide Utilization) reflects the most recent research results, as well as stimulating scientific discussions with new challenges in advancing the development of carbon dioxide utilization. Drawing on a wealth of information, this well structured book will benefit students, researchers and consultants looking to catch up on current developments in environmental and chemical engineering.

* Provides comprehensive data on CO2 utilisation
* Contains up-to-date information, including recent research trends
* Is written for students, researchers and consultants in environmental and chemical engineering

Daugiau informacijos

* Provides comprehensive data on CO2 utilisation * Contains up-to-date information, including recent research trends * Is written for students, researchers and consultants in environmental and chemical engineering
Preface xiii
Chairman's Remark xv
Organizing committee xvii
International advisory board xvii
International scientific committee xvii
Local advisory board xviii
Local organizing committee xviii
Supporting organizations xviii
Supporting organizations for technical excursion xix
I. Heterogeneous catalysis of CO2
Heterogeneous catalytic reactions with CO2: Status and perspectives
1(8)
G. Centi
S. Perathoner
Chemicals from CO2 via heterogeneous catalysis at moderate conditions
9(8)
Y. Sun
Synthetic hydrocarbon fuels and CO2 utilization
17(8)
G. Schaub
D. Unruh
M. Rohde
Design of copper based hybrid catalysts for CO2 hydrogenation
25(8)
Y.-K. Park
J.-K. Jeon
S.-K. Ihm
Plasma enhanced preparation of highly dispersed Ni/Al2O3 catalyst for CO2 reforming of Methane
33(8)
D. Cheng
Q. Xia
C. Liu
Synthesis of dimethyl carbonate by transesterification over CaO/carbon solid base catalysts
41(6)
T. Wei
M. Wang
W. Wei
Y. Sun
B. Zhong
The synthesis of clean fuels by F-T reaction from CO2 rich biosyngas
47(8)
J.-S. Ryu
K.-W. Lee
M.-J. Choi
H.-S. Yoo
Reduction of carbon dioxide using metal powders
55(6)
H. Katsumata
K. Matsushita
S. Kaneco
T. Suzuki
K. Ohta
Catalytic hydrogenation of CO2 to methanol over Pd/ZnO: Metalsupport interaction
61(6)
C.-H. Kim
J.S. Lee
D.L. Trimm
CAMERE Process for methanol synthesis from CO2 hydrogenation
67(6)
O.-S. Joo
K.-D. Jung
Y. Jung
Product distribution analysis for catalytic reduction of CO2 in a bench scale fixed bed reactor
73(6)
S.-B. Lee
J.-S. Kim
W.-Y. Lee
K.-W. Lee
M.-J. Choi
Process evaluation of biomass to liquid fuel production system with gasification and liquid fuel synthesis
79(6)
T. Minowa
T. Hanaoka
S. Yokoyama
Novel catalysts for gasification of biomass with high energy efficiency
85(6)
T. Miyazuwa
M. Asadullah
M. Nurunnabi
B. Li
K. Kunimori
K. Tomishige
Improving carbon utilization in biomass conversion to synthetic hydrocarbons via Fischer-Tropsch synthesis
91(6)
D. Unruh
M. Rohde
G. Schaub
Fischer-Tropsch synthesis with CO2-containing syngas from biomass - Kinetic analysis of fixed bed reactor model experiments
97(6)
M. Rohde
D. Unruh
P. Pias
K.-W. Lee
G. Schaub
Hydrogen production from woody biomass by novel gasification using CO2 sorbent
103(6)
T. Hanaoka
S. Fujimoto
T. Yoshida
K. Kamei
M. Harada
Y. Suzuki
S. Yokoyama
T. Minowa
A feasibility study of synthesis of oxygenates directly from methane and carbon dioxide using dielectric-barrier discharges
109(10)
J. Wang
C. Liu
B. Eliassion
Synthesis gas production from CO2 and H2O with nonthermal plasma
119(6)
S. Futamura
H. Kabashima
CO2 reduction by blast furnace top gas recycling combined with waste hydrocarbon gasification
125(6)
J.-O. Choi
J.-G. Kim
Microwave-assisted reactions of oxiranes with carbon dioxide in ionic liquids
131(6)
M. Nuchter
B. Ondruschka
J. Hoffmann
A. Tied
CO2 reforming of n-heptane on a Ni/Al2O3 catalyst
137(4)
K.J. Puolakka
A.O.I. Krause
Hexaaluminate catalysts of the novel process of syngas production through catalytic oxidation and steam-CO2 reforming of methane
141(4)
O. Yokota
T. Tanaka
Z. Hou
T. Yashima
Redox behavior of Cu-ferrite for CO2 decomposition
145(4)
H.C. Shin
S.C. Choi
C. S. Kim
O.-S. Joo
K.-D. Jung
CO2 reforming by CH4 over Ni-YSZ modified catalysts
149(4)
D.J. Moon
J.W. Ryu
D.M. Kung
B.G. Lee
B.S. Ahn
The interaction between CO2 and CH4 on Ru-Co-catalysts
153(4)
L.B. Shapovalova
G.D. Zakumbaeva
I.A. Shlygina
A.A. Shyrtbueva
Selective formation of light olefins by the cracking of heavy naphtha over acid catalysts
157(4)
S.Y. Han
C.W. Lee
J.R. Kim
N.S. Han
W.C. Choi
C.-H. Shin
Y.-K. Park
Effect of additives and a preparation method on catalytic activity of Cu/ZnO/ZrO2 system in the carbon dioxide hydrogenation to methanol
161(4)
J. Stoczynski
R. Grabowski
A. Koztowska
M. Lachowska
J. Skrzypek
Selective formation of ethylene carbonate from ethylene glycol and carbon dioxide over CeO2-ZrO2 solid solution catalysts
165(4)
K. Tomishige
H. Yasuda
M. Nurunnabi
B. Li
K. Kunimori
Effects of palladium particle size in hydrogenation of carbon dioxide to methanol over Pd/ZnO catalysts
169(4)
D. Lee
J.-Y. Lee
J.S. Lee
Ga, Mn and Mg promoted copper/zinc/zirconia - catalysts for hydrogenation of carbon dioxide to methanol
173(4)
M. Lachowska
J. Skrzypek
Catalytic hydrogenation of carbon dioxide to light olefins in a fluidized bed reactor
177(4)
J.-S. Kim
S.-B. Lee
M.-J. Choi
Y.K Lee
K.-W. Lee
Synthesis of dimethyl carbonate from CH3OH and CO2 with Ce1-xZrxO2 catalysts
181(4)
G.B. Han
N.K. Park
J.H. Jun
W.C. Chang
B.G. Lee
B.S. Ahn
S.O. Ryu
T.J. Lee
The effect of catalyst pore structure change into the selectivity and conversion of CO2 hydrogenation over Fe-K/γ-Al2O3
185(4)
S.-C. Lee
J.-H. Jang
B.-Y. Lee
T. Jeong
S.-J. Choung
Tri-reforming of CH4 using CO2 for production of synthesis gas to dimethyl ether
189(4)
S.-H. Lee
W. Cho
W.-S. Ju
Y.-S. Baek
J.-S. Chang
S.-E. Park
Carbon dioxide reduction technology with SOFC system
193(4)
D.J. Moon
J.W. Ryu
S.D. Lee
Synthesis of dimethyl carbonate from urea and methanol over metal oxides
197(4)
M. Wang
N. Zhao
W. Wei
Y. Sun
Development of heterogeneous catalyst system for esterification of free fatty acid contained in used vegetable oil
201(4)
H.-J. Kim
B.-S. Kang
M.-J. Kim
D.-K. Kim
J.-S. Lee
K.-Y. Lee
Investigation of synthesis gas production from natural gas and CO2 by microwave plasma technology
205(4)
W. Cho
W.-S. Ju
S.-H. Lee
Y.-S. Baek
Y.C. Kim
CO2 hydrate kinetics in electrolyte solutions containing clay minerals
209(4)
J. Lee
J. Park
M.-K. Chun
K. Lee
J.-H. Lee
J.-M. Kang
H. Lee
II. Homogemeous catalysis of CO2
New catalysts for the conversion of urea into carbamates and carbonates with C1 and C2 alcohols
213(8)
M. Aresta
A. Dibenedetto
C. Devita
O.A. Bourova
O.N. Chupakhin
Group 5 (V, Nb and Ta) element-alkoxides as catalysts in the trans-esterification of ethylene-carbonate with methanol, ethanol and allyl alcohol
221(6)
M. Aresta
A. Dibenedetto
C. Pastore
Hydroformylation with carbon dioxide using ionic liquid media
227(6)
K. Tominaga
Y. Sasaki
Ionic liquid-derived imidazolium metal halides for the coupling reaction of ethylene oxide and CO2
233(6)
O.-S. Kwon
J. Palgunadi
H. Lee
J.Y. Bae
B.S. Ahn
H.S. Kim
S.-H. Lee
Aliphatic polycarbonate synthesis by alternating copolymerization of carbon dioxide with cyclohexene oxide using heterogeneous zinc complex
239(4)
I. Kim
M.J. Yi
S.H. Pyun
D. W. Park
C.-S. Ha
Alternating copolymerization of carbon dioxide and epoxide [ 1] Aluminum Schiff base complex - quartenary ammonium salt systems as novel initiators
243(4)
H. Sugimoto
H. Ohtsuka
S. Inoue
Alternating copolymerization of carbon dioxide and epoxide [ 2] The first example of polycarbonate synthesis from 1-atm carbon dioxide by manganese porphyrin
247(4)
H. Sugimoto
H. Ohshima
S. Inoue
Semifluorinated block copolymer surfactants for water-in-CO2 microemulsions
251(4)
K.T. Lim
H.J. Kim
S.-H. Jin
S.-J. Choi
Y.S. Gal
Aliphatic polycarbonate synthesis by alternating copolymerization of carbon dioxide with cyclohexene oxide using β-diiminate zinc complex
255(4)
S.M. Kim
I. Kim
D.W. Park
C.-S. Ha
Synthesis of poly(DOMA-co-AN) by addition of carbon dioxide to poly(GMA-co-AN) and the miscibility behavior of its blends with PEI
259(4)
J.-H. Hur
D.-O. Lim
K.-H. Kim
I. Kim
H.-C. Woo
D.-W. Park
Half-sandwich complexes with dihydroxy polypyridine: water-soluble, highly efficient catalysts for hydrogenation of bicarbonate attributable to electron-donating ability of oxyanion on catalyst ligand
263(4)
Y. Himeda
N. Onozawa-Komatsuzaki
H. Sugihara
H. Arakawa
K. Kasuga
Synthesis of propylene carbonate from carbon dioxide and propylene oxide using ionic liquids
267(4)
D.-W. Park
J.-H. Hur
E.-S. Jeong
S.-W. Park
I. Kim
III. Electro and photocatalytic reduction of CO2
Spectroscopic characterization of intermediates in CO2 reduction with rhenium photocatalysts
271(6)
E. Fujita
Y. Hayashi
S. Kita
B.S. Brunschwig
Electrochemical reduction of CO2 at alloy electrode in methanol
277(6)
S. Kaneco
H. Yamauchi
H. Katsumata
T. Suzuki
K. Ohta
Photoactivation of Ti centers in mesoporous silicate sieve under visible and UV light
283(6)
W. Lin
H. Frei
Photocatalytic reduction of CO2 with H2O on Ti-containing mesoporous silica hydrophobically modified using fluoride ions
289(6)
H. Yamashita
M. Okazaki
K. Ikeue
M. Anpo
Effect of CO2 concentration on growth and photosynthesis of spirulina platensis
295(4)
S.-G. Kim
C.-S. Park
Y.-H. Park
S.-T. Lee
H.-M. Oh
High performance photocatalytic reduction of CO2 with H2O by TiSBA-15 mesoporous material
299(4)
J.-S. Hwang
J.-S. Chang
S.-E. Park
K. Ikeue
M. Anpo
IV. CO2 as oxidant
New CO2 chemistry -- recent advances in utilizing CO2 as an oxidant and current understanding on its role
303(12)
S.-E. Park
J.S. Yoo
Tri-reforming of methane over Ni catalysts for CO2 conversion to syngas with desired H2/CO ratios using flue gas of power plants without CO2 separation
315(8)
C. Song
W. Pan
S.T. Srimat
J. Zheng
Y. Li
Y.-H. Wang
B.-Q. Xu
Q.-M. Zhu
CO2 dehydrogenation of propane over Cr-MCM-41 catalyst
323(6)
K. Takehira
Y. Oishi
T. Shishido
T. Kawabata
K. Takaki
Q. Zhang
Y. Wang
CO2 reforming of n-heptane on a Ni/Al2O3 catalyst
329(4)
K.J. Puolakka
A.O.I. Krause
Dehydrogenation of ethylbenzene over promoted vanadium oxide catalyst with carbon dioxide: from laboratory to bench-scale test
333(6)
D.-Y. Hong
S.H. Jhung
J.-M. Lee
M.-S. Park
J.-S. Chang
S.-E. Park
Oxidative dehydrogenation of ethane with carbon dioxide over supported chromium oxide catalysts
339(4)
M. Ji
D.-Y. Hong
J.-S. Chang
V.P. Vislovskiy
J.S. Yoo
S.-E. Park
Oxidehydrogenation of ethane with CO2 over transition metal doped MCM-41 mesoporous catalysts
343(4)
Y.-L. Bi
V.C. Corberan
H. Zhuang
K.-J. Zhen
Selective formation of styrene via oxidative dehydrogenation of 4-vinylcyclohexene over ZrO2- supported iron oxide catalysts
347(4)
J.-S. Chang
D.-Y. Hong
Y.-K. Park
S.-E. Park
Catalytic transformation of cyclohexanol over mixed metal oxides with and without CO2
351(4)
V.R. Chumbhale
J.S. Kim
S.B. Lee
M.J. Choi
V. Studies in supercritical CO2
The utility of carbon dioxide in homogeneously-catalyzed organic synthesis
355(8)
P.G. Jessop
Aldol reactions of propanal using MgO catalyst in supercritical CO2
363(6)
K. Matsui
H. Kawanami
H. Hayashi
Critical point and phase envelope calculations - Some practical aspects based on CO2-mixtures
369(6)
H.A. Turunen
J.-P. Pokki
R. Raudaskoski
E. Turpeinen
E. Muurinen
K.I. Keskinen
R.L. Keiski
Evaluation of sequesterable carbon dioxide in Japanese coal samples at sub-critical and supercritical conditions
375(6)
M. M. Toribio
Y. Oshima
S. Shimada
Synthesis and characterization of poly(styrene-co-butyl acrylate) and poly(styrene-co-butyl methacrylate) in supercritical carbon dioxide
381(4)
B. Shin
W. Bae
H. Lee
H. Kim
Phenol hydrogenation over supported metal catalysts under supercritical carbon dioxide
385(4)
C.V. Rode
U.D. Joshi
T. Sato
O. Sato
M. Shirai
Synthesis of various block copolymers containing poly(L-lactide) in supercritical carbon dioxide
389(4)
H.S. Hwang
E.J. Park
Y.T. Jeong
H. Heo
K.T. Lim
Vapour pressure of CO2 as well as phase envelopes and critical points for CO2 and CH4 mixtures calculated by Aspen Plus and Flowbat simulation software
393(4)
R. Raudaskoski
E. Turpeinen
H. Turunen
K. Rahkamaa-Tolonen
R.L. Keiski
VI. CO2 separation and recovery
CO2 recovery pilot plant
397(8)
K.R. Jang
J.H. Kim
J.G. Shim
Y.M. Ahn
H.M. Eum
A 2-stage PSA process for the recovery of CO2 from flue gas and its power consumption
405(6)
S.-H. Cho
J.-H. Park
H.-T. Beum
S.-S. Han
J.-N. Kim
Novel nanoporous ``Molecular basket'' adsorbent for CO2 capture
411(6)
C. Song
X. Xu
J.M. Andresen
B.G. Miller
A. W. Scaroni
Reversible adsorption of carbon dioxide on amine-modified SBA-15 from flue gas containing water vapor
417(6)
N. Hiyoshi
K. Yogo
T. Yashima
Hollow fiber membrane contactor hybrid system for CO2 recovery
423(6)
K.-H. Lee
S.-H. Yeon
B. Sea
Y.-I. Park
Optimization of CO2 absorption process with MEA solution
429(6)
S. Kim
H.-T. Kim
B.-C. Choi
Permeability modification for CO2 EOR
435(6)
G. Tian
C. Tao
R. Qu
W. Han
J. Deng
P. Behrenbruch
Catalytic reactivity for the formation of dimethyl ether from synthesis gas over hybrid catalysts
441(4)
W.-S. Ju
C.W. Choi
S.-H. Lee
W. Cho
J.-S. Hwang
S.-E. Park
Y.-S. Baek
VII. Biology and biochemistry of CO2 utilization
Design and experimental practice of photobioreactor incorporating microalgae for efficient photosynthetic CO2 fixation performance
445(8)
Y. Watanabe
Biomass Japan strategy
453(8)
S. Yokoyama
Carbon dioxide removal and biomass production by Anabaena cylindrica IAM MI using reactor in series
461(8)
A. Wijanarko
K. Ohtaguchi
Viability and activity of microorganisms in pressurized and supercritical carbon dioxide
469(6)
B. Zhang
X. Liu
Y. Gan
Novel conversion of carbon dioxide to methanol catalyzed by sol-gel immobilized dehydrogenases
475(6)
Z. Jiang
S. Xu
H. Wu
Combined thermoneutral processes for CO2 emission avoidance and fuel saving in the metallurgical and lime industries
481(6)
M. Halmann
A. Steinfeld
VIII. Utilization of CO2 hydrates
Greenhouse gas hydrates in the ocean
487(8)
S.M. Masutani
Replacement of methane hydrate by carbon dioxide: 13C NMR study for studying a limit to the degree of substitution
495(6)
H. Lee
Y. Seo
Y.-T. Seo
D.Y. Kim
I.L. Moudrakovski
J.A. Ripmeester
Continuous CO2 clathrate hydrate formation by a motionless mixer
501(6)
H. Tajima
A. Yamasaki
F. Kiyono
A new type separation process of condensable greenhouse gases by the formation of clathrate hydrates
507(6)
K. Shiojiri
T. Okano
Y. Yanagisawa
M. Fujii
A. Yamasaki
H. Tajima
F. Kiyono
The OACE (Ocean Abyssal Carbon Experiment) research project
513(6)
R. Kojima
I. Aya
K. Yamane
S. Namie
Y. Nakajima
H. Shirota
P. G. Brewer
E.T. Peltzer
P. M. Haugan
T. Johannessen
R.G.J. Bellerby
Addition of carbon dioxide to phenylglycidyl ether using quaternary ammonium salts grafted on modified MCM-41 support
519(4)
D.-W. Park
D.-H. Shin
B.-S. Yu
K.-H. Kim
S.-W. Park
I. Kim
J.-W. Lee
Chemical absorption of carbon dioxide with NaOH in non-Newtonian w/o emulsion
523(4)
S.-W. Park
B.-S. Choi
T.-Y. Kim
J.-W. Lee
CO2 absorption and regeneration using Na and K based sorbents
527(4)
S.C. Lee
B.Y. Choi
S.J. Lee
S.Y. Jung
C.K. Ryu
J.C. Kim
Preparation of 6FDA-based polyimide membranes for CO2 gas separation
531(4)
K.-J. Kim
W.-W. So
S.-J. Moon
Chemical absorption of carbon dioxide into toluene solution of oxirane
535(4)
S.-W. Park
D.-W. Park
T.-Y. Kim
J.-W. Lee
A study about CO2 absorption process design for thermal power plant flue gas
539(4)
S.-Y. Park
B.-M. Min
J.-S. Lee
H.-M. Eum
Membrane/PSA hybrid process for carbon dioxide recovery at low concentration
543(4)
J.-K. Jeon
S.-K. Ihm
Y.-K. Park
J.S. Kim
J.-I. Dong
S. Kim
J.M. Kim
S.-S. Kim
K.-S. Yoo
Effect of isotherm selection on performance prediction of CO2 PSA process
547(4)
J.-K. Jeon
S.-K. Ihm
Y.-K. Park
J.S. Kim
S.D. Kim
S. Kim
J.M. Kim
S.-S. Kim
K.-S.Yoo
Chemical absorption of carbon dioxide with AMP in aqueous PAA solution
551(4)
S.-W. Park
B.-S. Choi
H.-I. Jung
J.-W. Lee
IX. General uses of CO2
The role of CO2 fixation in the strategy for mitigating global warming
555(6)
Y. Kaya
The preparation of metallic tungsten and flower-like structure tungsten materials with using CO/CO2 mixtures
561(4)
J.-D. Lee
D.H. Lee
N.K. Park
S.O. Ryu
W.C. Chang
T.J. Lee
On-line gas chromatographic analysis of CO2 hydrogenation products
565(4)
M. Reinikainen
M. Niemela
Synthesis of ultrafine TiO2 particles from hydrolysis of Ti(OPr)4 with PEO-b-PFOMA reverse micelles in CO2
569(4)
K.T. Lim
H.S. Hwang
S.-S. Hong
C. Park
W. Ryoo
K.P. Johnston
Synthesis of propylene carbonate from urea and propylene glycol
573(4)
Q. Li
N. Zhao
W. Wei
Y. Sun
Dissolution behavior of liquid CO2 droplets injected at the intermediate ocean depth in Clarion-Clipperton
577(4)
C.-B. Kim
N.-J. Kim
Growth and carbon fixation of cyanobacterium spirulina platensis with different nitrogen sources
581(4)
A. Choi
B.-D. Yoon
H.-S. Kim
H.-M. Oh
Author index 585(6)
Keyword index 591(6)
Other volumes in the series 597