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El. knyga: Cellulose Nanocrystal/Nanoparticles Hybrid Nanocomposites: From Preparation to Applications

Edited by (Professor of Chemical Engineering at Laval University in Quebec City, Canada), Edited by (Director of Polymer Processing Laboratory, Institute of Nanomaterials and Nanotechnology (Nanotech), Rabat, Morocco), Edited by (Mohammed VI Polytechnic University, )
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Cellulose Nanocrystal/Nanoparticles Hybrid Nanocomposites: From Preparation to Applications presents a broad survey of the main innovations in the field of functionalized cellulose at the nanoscale and for hybrid nanoparticles-based nanocomposites for industrial application. The book covers the properties and applications of cellulose, including particle extraction, synthesis, functionalization of cellulose at the nanoscale, and hybrid nanoparticles and their processing and characterizations. Readers will find this to be a single and comprehensive reference for future research on polymer-based nanocomposites.

Hybrid nanocomposites based on cellulose at the nanoscale, and hybridized with other reinforcement agents represent a key advance in polymer-based materials. Cellulose is considered the most abundant polymer on the planet and an essential renewable resource. There is considerable research interest in the simple extraction and synthesis, nanoscale dimensions, high aspect ratio, mechanical, electrical and thermal properties of cellulose at the nanoscale and its hybridized materials. Nanocomposites and bio-nanocomposites with hybrid reinforcements, for example, are novel materials with enhanced properties due to the integration of cellulose with other nanoparticles, and new methods have been developed to extract cellulose at the nanoscale. The extracted cellulose shows potential applications in nanocomposites, and functionalization techniques are essential to create enhanced nanocomposites, particularly for hybrid nanoparticles.

  • Presents the state-of-the-art in functionalized cellulose at the nanoscale, along with industrial applications of hybrid-nanoparticles-based nanocomposites
  • Details the properties and applications of cellulose at the nanoscale and for hybrid nanocomposites
  • Gives updates on hybrid nanoparticles, including the processing and characterization of nanocomposites
  • Brings together expertise from chemistry, polymer science, engineering and manufacturing
Contributors xi
1 Cellulose nanocrystal/nanoparticles hybrid nanocomposites: From preparation to applications
Mohamed El Mehdi Mekhzoum
Khadija El Bourakadi
Abou el Kacem Qaiss
Rachid Bouhfid
1.1 Introduction
1(2)
1.2 Cellulose nanocrystal: Structure, source, and properties
3(6)
1.3 Production of cellulose nanocrystals
9(3)
1.4 Cellulose nanocrystal/nanoparticles hybrid nanocomposites
12(5)
1.5 Conclusion
17(1)
References
17(10)
2 Characterization techniques for hybrid nanocomposites based on cellulose nanocrystals/nanofibrils and nanoparticles
Khadija El Bourakadi
Rachid Bouhfid
Abou el Kacem Qaiss
2.1 Introduction
27(1)
2.2 Cellulose: Chemical structure, properties, and application
28(3)
2.3 Characterization of cellulose-based hybrid nanocomposites
31(28)
2.3.1 Structural characterization
31(15)
2.3.2 Morphological characterization
46(7)
2.3.3 Thermal properties
53(3)
2.3.4 Mechanical properties
56(1)
2.3.5 Dynamic mechanical analysis (DMA)
57(2)
2.4 Conclusion
59(1)
References
60(5)
3 Hybrid nanocomposites based on cellulose nanocrystals/nanofibrils and carbon nanotubes: From preparation to applications
Farnaz Shahamati Fard
Hossein Kazemi
Frej Mighri
Denis Rodrigue
3.1 Introduction
65(2)
3.2 Thermoplastic polyurethanes
67(3)
3.3 Flexible sensors
70(14)
3.4 Adsorption
84(4)
3.5 Optoelectronic applications
88(1)
3.6 Wearable electronic devices
89(1)
3.7 Supercapacitors
90(1)
3.8 Soy proteins reinforcement
91(1)
3.9 Conclusion
91(1)
References
92(7)
4 Hybrid nanocomposites based on cellulose nanocrystals/nanofibrils and silver nanoparticles: Antibacterial applications
Carlo Santulli
4.1 Introduction
99(6)
4.1.1 Nanocellulose from ligno-cellulosic materials
99(3)
4.1.2 Bacterial cellulose
102(3)
4.2 Antibacterial properties of nanosilver
105(1)
4.3 Application of nanosilver on nanocellulose
106(2)
4.4 Novel preparation methods for improved biocompatibility
108(1)
4.5 Conclusions
109(1)
References
110(5)
5 Hybrid materials from cellulose nanocrystals for wastewater treatment
Hanane Chakhtouna
Hanane Benzeid
Nadia Zari
Abou el Kacem Qaiss
Rachid Bouhfid
5.1 Introduction
115(1)
5.2 Cellulose nanocrystals generalities: From synthesis to application as a potential adsorbent in wastewater treatment field
116(3)
5.2.1 Synthesis, structure, and morphology
116(2)
5.2.2 Cellulose nanocrystals as a potential adsorbent in wastewater treatment
118(1)
5.3 Hybrid materials from cellulose nanocrystals for wastewater treatment
119(16)
5.3.1 CNC/polymer hybrid materials
120(6)
5.3.2 CNC/metal or metal oxide hybrid materials
126(5)
5.3.3 CNC/magnetic hybrid materials
131(2)
5.3.4 CNC/carbonaceous hybrid materials
133(2)
5.4 Conclusion
135(1)
References
136(5)
6 Hybrid nanocomposites based on cellulose nanocrystals/nanofibrils and titanium oxide: Wastewater treatment
Ateeq Rahman
V.S.R. Rajasekhar Pullabhotla
Likius Daniel
Veikko Uahengo
6.1 Introduction
141(5)
6.2 Characterization of nanocellulose (cellulose nanocrystals and cellulose nanofibrils)
146(1)
6.3 Treatment of contaminated water with nanocellulose/nanocellulose based nanohybrid composites
147(1)
6.4 Removal of oil from waste water
147(11)
6.4.1 Removal of drugs with cellulose nanohybrid fibrils
149(1)
6.4.2 Separation processes and wastewater treatment
150(1)
6.4.3 Cellulose nanomaterials in membranes for waste water treatment
150(2)
6.4.4 TiO2 photocatalysts for waste water treatment
152(1)
6.4.5 Methods for the synthesis of TiO2
152(2)
6.4.6 Application of TiO2-composite material in the wastewater treatment
154(1)
6.4.7 Photocatalytic reactions using TiO2/TiO2-composite
155(3)
6.5 Conclusions
158(1)
Acknowledgments
158(1)
Funding
158(1)
Conflict of interest
158(1)
References
158(7)
7 Hybrid nanocomposites based on cellulose nanocrystals/nanofibrils and zinc oxides: Energy applications
Kalsoom Jan
7.1 Cellulose and derivatives from renewable sources
165(1)
7.2 Types of cellulose
165(1)
7.2.1 Cellulose nanofibrils (CNF)
166(1)
7.2.2 Cellulose nanocrystals (CNC)
166(1)
7.2.3 Bacterial nanocellulose (BNC)
166(1)
7.3 Metal oxide-based cellulose nanohybrid composites
166(2)
7.3.1 Zinc-oxide based cellulose hybrid nanocomposite
167(1)
7.3.2 Synthesis methods and surface modification
167(1)
7.3.3 Cellulose/ZnO energy and sensing properties
168(1)
7.4 Cellulose-based composites for energy applications
168(3)
7.4.1 State of art
168(1)
7.4.2 Cellulose-based material for energy conversion
169(2)
7.5 Cellulose for energy storage
171(6)
7.5.1 Cellulose in sodium-ion battery (SIB)
171(1)
7.5.2 Cellulose-based lithium-ion batteries (LIB)
172(2)
7.5.3 Supercapacitors
174(1)
7.5.4 Cellulose as electrodes for pseudo-capacitors
175(1)
7.5.5 Cellulose nanomaterials for nanogenerator developments
176(1)
7.6 Summary
177(1)
References
177(4)
8 Cellulose nanocrystal (CNC): Inorganic hybrid nanocomposites
Marya Raji
Hamid Essabir
Hala Bensalah
Kamal Guerraoui
Rachid Bouhfid
Abou el Kacem Qaiss
8.1 Introduction
181(1)
8.2 Cellulose nanocrystals
182(3)
8.2.1 General overview on the chemistry and properties of cellulose
182(3)
8.2.2 Extraction techniques of cellulose nanocrystals
185(1)
8.3 Cellulose nanocrystals: Inorganic hybrid nanocomposites
185(8)
8.3.1 Synthesis of cellulose-inorganic hybrid nanocomposites
186(3)
8.3.2 Characterization of cellulose-inorganic hybrid nanocomposites
189(4)
8.3.3 Cellulose-inorganic hybrid nanocomposites applications
193(1)
8.4 Conclusion
193(5)
References
198(7)
9 Hybrid nanocomposites based on cellulose nanocrystals/nanofibrils with graphene and its derivatives: From preparation to applications
Lakkoji Satish
Ayonbala Baral
Aneeya K. Samantara
9.1 Introduction
205(1)
9.2 Cellulose based nanocrystals/nanofibrils
206(2)
9.3 Graphene based composites
208(1)
9.4 Nanocomposites of cellulose nanocrystals/nanofibrils with graphene and its derivatives
209(1)
9.5 Solution intercalation
210(1)
9.6 Melt intercalation
210(1)
9.7 In situ polymerization
211(1)
9.8 Applications
211(5)
9.9 Conclusion
216(1)
References
217(6)
10 Hybrid nanocomposites based on cellulose nanocrystals/nanofibrils: From preparation to applications
H. Mohit
G. Hemath Kumar
M.R. Sanjay
S. Siengchin
P. Ramesh
10.1 Introduction to cellulose-based composites
223(4)
10.2 Materials and methods
227(2)
10.2.1 Materials
227(1)
10.2.2 Characterization
228(1)
10.3 Results and discussion
229(9)
10.3.1 Characteristic curves
229(1)
10.3.2 Mechanical properties
230(4)
10.3.3 Viscoelastic properties
234(3)
10.3.4 Thermal stability
237(1)
10.4 Applications of polyester hybrid composites
238(2)
10.5 Conclusion
240(1)
Acknowledgment
240(1)
References
240(7)
11 Mechanical modeling of hybrid nanocomposites based on cellulose nanocrystals/nanofibrils and nanoparticles
Fatima-Zahra Semlali Aouragh Hassani
Zineb Kassab
Mounir El Achaby
Rachid Bouhfid
Abou el Kacem Qaiss
11.1 Introduction
247(1)
11.2 Nanocomposites reinforcement
248(7)
11.2.1 Nano-reinforcements classification
249(1)
11.2.2 Nanocomposites based on cellulose reinforcement
250(5)
11.3 Cellulose based hybrid nanocomposites materials
255(5)
11.3.1 Manufacturing methods
255(1)
11.3.2 Hybrid nanocomposites mechanical properties
256(4)
11.4 Mechanical modeling of hybrid nanocomposites based on cellulose
260(6)
11.4.1 Phenomenological models
260(1)
11.4.2 Homogenization models
261(5)
11.5 Conclusion
266(1)
References
266(5)
Index 271
Denis Rodrigue is a Professor of Chemical Engineering at Laval University in Quebec City, Canada. His main research interests are related to the characterization and the modelling of the chemical, electrical, mechanical, morphological, physical, thermal and rheological properties of polymer foams and composites, based on thermoplastics and elastomers. Recently his work has concentrated on polymer recycling and long term performance. He is currently the co-editor of the Journal of Cellular Plastics and Current Applied Polymer Science. Prof. Abou el kacem Qaiss is currently working as Director of the Composites Nanocomposites Centre at the Moroccan Foundation for Advanced Science, Innovation and Research (MAScIR), Institute of Nanomaterials and Nanotechnology (Nanotech) in Rabat (Morocco).

His research areas include: hybrid reinforced/filled polymer composites, advance materials: graphene/nanoclay, lignocellulosic reinforced/filled polymer composites, modification and treatment of lignocellulosic fibres, nanocomposites and nanocellulose fibres, as well as polymer blends. So far, he has published three books, 30 chapters and more than 75 international journal papers with 25 patents to his credit. Prof. Rachid Bouhfid is currently working as an Associate Professor at Mohammed VI Polytechnic University (UM6P), Benguerir, Morocco. Before joining UM6P, he served as the Director of Research at the Moroccan Foundation for Advanced Science, Innovation, and Research (MAScIR) in Rabat, Morocco, and as an Assistant Professor at Artois University, France. Prof. Bouhfid earned his doctoral degree from Mohammed V University in Rabat, Morocco. He has over fifteen years of experience in teaching and research in organic chemistry, materials science, nanotechnology, and polymer chemistry. His main research interests include hybrid nanomaterials, reinforced polymer nanocomposites, and advanced materials such as graphene, nanoclay, cellulose nanocrystals, and nanocomposites. Throughout his career, he has developed various nanostructured materials for wastewater treatment, packaging, sensing, and biomedical applications. He has authored more than 200 research papers in SCI-indexed journals, edited six books, and co-authored over 54 book chapters.
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