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El. knyga: Chemistry of Environmental Engineering [Wiley Online]

(University of Leoben, Austria)
  • Formatas: 336 pages
  • Išleidimo metai: 02-Jun-2020
  • Leidėjas: Wiley-Scrivener
  • ISBN-10: 1119707862
  • ISBN-13: 9781119707868
  • Wiley Online
  • Kaina: 212,46 €*
  • * this price gives unlimited concurrent access for unlimited time
  • Formatas: 336 pages
  • Išleidimo metai: 02-Jun-2020
  • Leidėjas: Wiley-Scrivener
  • ISBN-10: 1119707862
  • ISBN-13: 9781119707868
"The focus of this book is the chemistry of environmental engineering and its applications, with a special emphasis on the use of polymers in this field. It explores the creation and use of polymers with special properties such as viscoelasticity and interpenetrating networks; examples of which include the creation of polymer-modified asphalt as well as polymers with bacterial adhesion properties. The text contains the issues of polymerization methods, recycling methods, wastewater treatment, types of contaminants, such as microplastics, organic dyes, and pharmaceutical residues"--

The focus of this book is the chemistry of environmental engineering and its applications, with a special emphasis on the use of polymers in this field. It explores the creation and use of polymers with special properties such as viscoelasticity and interpenetrating networks; examples of which include the creation of polymer-modified asphalt as well as polymers with bacterial adhesion properties.  The text contains the issues of polymerization methods, recycling methods, wastewater treatment, types of contaminants, such as microplastics, organic dyes, and pharmaceutical residues.

After a detailed overview of polymers in Chapter 1, their special properties are discussed in the following chapter. Among the topics is the importance of polymers to water purification procedures, since their use in the formation of reverse osmosis membranes do not show biofouling. Chapter 3 details special processing methods, such as atom transfer radical polymerization, enzymatic polymerization, plasma treatment, and several other methods, can be used to meet the urgent demands of industrial applications.  Chapter 4 addresses the important environmental issue of recycling methods as they relate to several types of materials such as PET bottles, tire rubbers, asphalt compositions, and other engineering resins. And wastewater treatment is detailed in Chapter 5, in which the types of contaminants, such as microplastics, organic dyes and pharmaceutical residues, are described and special methods for their proper removal are detailed along with types of adsorbents, including biosorbents. Still another important issue for environmental engineering chemistry is pesticides. Chapter 6 is a thorough description of the development and fabrication of special sensors for the detection of certain pesticides. A detailed presentation of the electrical uses of polymer-based composites is given in Chapter 7, which include photovoltaic materials, solar cells, energy storage and dielectric applications, light-emitting polymers, and fast-charging batteries. And recent issues relating to food engineering, such as food ingredient tracing, protein engineering, biosensors and electronic tongues, are presented in Chapter 8. Finally, polymers used for medical applications are described in Chapter 9. These applications include drug delivery, tissue engineering, porous coatings and also the special methods used to fabricate such materials.

Preface xi
1 Special Polymers
1(62)
1.1 Poly(ethylene)
1(6)
1.1.1 Metallocene Poly(ethylene)
1(5)
1.1.2 Geomembranes
6(1)
1.2 Poly(styrene)
7(4)
1.2.1 Syndiotactic Poly(styrene)
7(4)
1.3 Poly(ethylene terephthalate)
11(1)
1.3.1 Blends of Poly(ethylene terephthalate) and Poly(phenylene sulfide)
11(1)
1.4 Silicones
12(13)
1.4.1 Silicon Nanocrystals and Silicon-Polymer Hybrids
12(1)
1.4.2 Surfactants
13(12)
1.5 Self-healing Polymers
25(7)
1.5.1 Multiphasic Copolymer
26(2)
1.5.2 Hydrophobic Coatings
28(1)
1.5.3 Microcapsule Based Self-Healing
28(1)
1.5.4 Tunable Mechanical Strengths
29(1)
1.5.5 Bioinspired Pathways
30(2)
1.6 Fibers and Smart Polymers
32(10)
1.6.1 Natural Fiber Reinforced Polymer Composites
32(3)
1.6.2 Shape Memory Systems
35(6)
1.6.3 Smart Polymers
41(1)
1.7 Porous Materials
42(12)
1.7.1 Preparation Methods
42(6)
1.7.2 Polymer Foams
48(2)
1.7.3 Porous Polymer Monoliths
50(1)
1.7.4 Concrete
51(3)
References
54(9)
2 Special Properties of Polymers
63(36)
2.1 Viscoelasticity
63(1)
2.2 Impact response of Hybrid Carbon/Glass Fiber Reinforced Polymer Composites
63(1)
2.3 Mechanical Properties
64(6)
2.3.1 Real Elastic Network Theory
64(1)
2.3.2 Interpenetrating Polymer Network Hydrogels
65(1)
2.3.3 Flax Fabric Reinforced Polymer
66(1)
2.3.4 Asphalt
66(4)
2.4 Bacterial Adhesion
70(24)
2.4.1 Influence of Stiffness
72(2)
2.4.2 Bioactive Sulfone Polymers
74(8)
2.4.3 Functionalized Dopamine
82(1)
2.4.4 Sub-micrometer Structures
83(2)
2.4.5 Mechanically Modulated Microgel Coatings
85(1)
2.4.6 Conductive Polymers
86(1)
2.4.7 Reverse Osmosis Membranes
87(7)
References
94(5)
3 Processing Methods
99(44)
3.1 Radiation Processing
99(1)
3.2 Additive Manufacturing
99(2)
3.3 Atom Transfer Radical Polymerization
101(4)
3.3.1 Vinyl Macromonomers of Poly(styrene)
101(1)
3.3.2 Ultrasound Atom Transfer Radical Polymerization
102(1)
3.3.3 Near-Infrared Sensitized Photoinduced Atom-Transfer Radical Polymerization
103(2)
3.4 Reversible Addition-Fragmentation Chain Transfer Polymerization
105(3)
3.5 Enzymatic Polymerization
108(3)
3.6 Surface Patterning
111(2)
3.6.1 Nonthermal Plasma Technology
111(2)
3.7 Friction Welding
113(4)
3.7.1 ABS and Poly(amide)s
114(3)
3.8 Interfacial Engineering
117(1)
3.9 Plasma Treatment
118(18)
3.9.1 Mineralization of Plasma Treated Polymer Surfaces
118(1)
3.9.2 Wetting Properties
119(2)
3.9.3 Vapor Phase Graft Polymerization
121(2)
3.9.4 Effect of Plasma Treatment Frequency
123(1)
3.9.5 Plasma Treatment in Textile Industry
124(2)
3.9.6 Antimicrobial Surfaces
126(4)
3.9.7 Non-Thermal Plasma Treatment of Agricultural Seeds
130(2)
3.9.8 Special Materials
132(4)
References
136(7)
4 Recycling
143(22)
4.1 Recycling Methods
143(8)
4.1.1 Primary Recycling
143(1)
4.1.2 Secondary Recycling
143(1)
4.1.3 Tertiary Recycling
144(1)
4.1.4 Quaternary Recycling
144(1)
4.1.5 Melt Filtration
145(3)
4.1.6 Hydrothermal Recycling
148(1)
4.1.7 Quality of Postconsumer Plastics
149(2)
4.2 Materials
151(10)
4.2.1 Poly(propylene) Waste
151(1)
4.2.2 PET Bottles
152(4)
4.2.3 Engineering Epoxy Resin
156(1)
4.2.4 Carbon Nanotube-Filled Polycarbonate
157(1)
4.2.5 Asphalt Compositions
158(2)
4.2.6 Tire Rubbers
160(1)
References
161(4)
5 Wastewater Treatment
165(18)
5.1 Properties and Contaminants
165(8)
5.1.1 Microplastics
167(1)
5.1.2 Organic Dyes
168(1)
5.1.3 Pharmaceutical Residues in Wastewater
169(2)
5.1.4 Passively Aerated Biological Filter
171(2)
5.2 Adsorbents
173(8)
5.2.1 Activated Carbon
173(3)
5.2.2 Adsorbent Regeneration
176(1)
5.2.3 Ultrasound-assisted treatment
177(1)
5.2.4 Praseodymium Molybdate
178(1)
5.2.5 Biosorbents
179(2)
References
181(2)
6 Pesticides
183(16)
6.1 Pesticide Carriers
183(1)
6.2 PCL Nanocapsules
184(1)
6.3 Self-Decontamination Mechanisms
185(1)
6.4 Controlled Release of Pesticides
186(4)
6.4.1 PVA-Starch Composite Films
187(1)
6.4.2 PLA Nanofibers
188(1)
6.4.3 PBSU and PLA Nanofibers
188(1)
6.4.4 Poly(3-hydroxybutyrate)
189(1)
6.5 Sensors
190(7)
6.5.1 Biosensor for Dichlorvos
190(2)
6.5.2 Biosensor for Carbaryl
192(1)
6.5.3 Voltammetric Method for Ethyl Paraoxon
192(1)
6.5.4 Nitrogen Doped Graphene Electrode
193(1)
6.5.5 Molecularly Imprinted Sensor
194(1)
6.5.6 Ecotoxicity Evaluation
195(2)
References
197(2)
7 Electrical Uses
199(46)
7.1 Photovoltaic Materials
199(1)
7.2 Solar Cells
200(1)
7.3 Energy Storage and Dielectric Applications
200(8)
7.3.1 Polymer Nanocomposites
201(6)
7.3.2 Multiwall Carbon Nanotubes
207(1)
7.3.3 High-Temperature Dielectric Materials
208(1)
7.4 Light Emitting Polymers
208(20)
7.4.1 Circularly Polarized Light
208(2)
7.4.2 Polymer Types
210(3)
7.4.3 Color Management
213(9)
7.4.4 Light-Emitting Electrochemical Cells
222(6)
7.5 Fast Charging Batteries
228(6)
7.5.1 Charging Stages
230(2)
7.5.2 Increasing the Cycling Lifetime
232(1)
7.5.3 Lithium-Ion Batteries
232(2)
7.6 Electrical Power Cable Engineering
234(4)
7.6.1 Carbon Nanotube Cables
235(1)
7.6.2 High Voltage Alternating Current Cables for Subsea Transmission
235(3)
7.6.3 Biodegradable Polymer Cables
238(1)
References
238(7)
8 Food Engineering
245(24)
8.1 Software
245(2)
8.1.1 GUI Software Packages
245(1)
8.1.2 Food Ingredient Tracing
246(1)
8.1.3 Microbial Growth
246(1)
8.2 Materials
247(2)
8.2.1 Microbial Biopolymers
247(1)
8.2.2 Marine Polysaccharides
247(2)
8.3 Protein Engineering
249(1)
8.4 Instrumentation and Sensors
250(8)
8.4.1 Biosensors
250(3)
8.4.2 Electronic Tongues
253(1)
8.4.3 Microwave Methods
254(2)
8.4.4 Optoelectronic Sensor
256(1)
8.4.5 Digital Image Analysis
257(1)
8.5 Ultrasonic Methods
258(7)
8.5.1 Special Applications
259(1)
8.5.2 Composition of Meat
259(2)
8.5.3 Flour Quality
261(1)
8.5.4 Porosity of Bread
262(1)
8.5.5 Dairy Products
263(2)
References
265(4)
9 Medical Uses
269(38)
9.1 Drug Delivery
269(1)
9.2 Porous Bioresorbable Polymers
269(5)
9.3 Tissue Engineering
274(28)
9.3.1 Biomedical Materials
274(5)
9.3.2 Electrically Conducting Polymer
279(1)
9.3.3 Bioactive Glass
280(7)
9.3.4 Glass-based Coatings
287(3)
9.3.5 Hard Tissue Implants
290(4)
9.3.6 Membranes
294(1)
9.3.7 Textile-based Technologies
295(1)
9.3.8 Improvement of Cell Adhesion
296(1)
9.3.9 Solvent Free Fabrication
297(1)
9.3.10 Stereolithographic 3D Printing
298(1)
9.3.11 Extrusion-Based 3D Printing
299(3)
References
302(5)
Index 307(1)
Acronyms 307(4)
Chemicals 311(4)
General Index 315
Johannes Karl Fink is Professor of Macromolecular Chemistry at Montanuniversität Leoben, Austria. His industry and academic career spans more than 30 years in the fields of polymers, and his research interests include characterization, flame retardancy, thermodynamics and the degradation of polymers, pyrolysis, and adhesives. Professor Fink has published several books on physical chemistry and polymer science including A Concise Introduction to Additives for Thermoplastic Polymers (Wiley-Scrivener 2009), The Chemistry of Biobased Polymers (Wiley-Scrivener 2014), and Polymer Waste Management (Wiley-Scrivener 2018).