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Chemistry of Matter Waves 2013 ed. [Kietas viršelis]

  • Formatas: Hardback, 243 pages, aukštis x plotis: 235x155 mm, weight: 5148 g, XIV, 243 p., 1 Hardback
  • Išleidimo metai: 21-Aug-2013
  • Leidėjas: Springer
  • ISBN-10: 9400775776
  • ISBN-13: 9789400775770
Kitos knygos pagal šią temą:
  • Formatas: Hardback, 243 pages, aukštis x plotis: 235x155 mm, weight: 5148 g, XIV, 243 p., 1 Hardback
  • Išleidimo metai: 21-Aug-2013
  • Leidėjas: Springer
  • ISBN-10: 9400775776
  • ISBN-13: 9789400775770
Kitos knygos pagal šią temą:

?The quantum and relativity theories are considered to underpin all of science. This monograph argues against this premise on the basis of the incompatibility of the two theories and on some untenable philosophical implications of the quantum model.



The quantum and relativity theories of physics are considered to underpin all of science in an absolute sense. This monograph argues against this proposition primarily on the basis of the two theories' incompatibility and of some untenable philosophical implications of the quantum model. Elementary matter is assumed in both theories to occur as zero-dimensional point particles. In relativity theory this requires the space-like region of the underlying Minkowski space-time to be rejected as unphysical, despite its precise mathematical characterization. In quantum theory it leads to an incomprehensible interpretation of the wave nature of matter in terms of a probability function and the equally obscure concept of wave-particle duality. The most worrisome aspect about quantum mechanics as a theory of chemistry is its total inability, despite unsubstantiated claims to the contrary, to account for the fundamental concepts of electron spin, molecular structure, and the periodic table of the elements. A remedy of all these defects by reformulation of both theories as nonlinear wave models in four-dimensional space-time is described.
1 Of Electrons and Molecules
1(10)
1.1 Introduction
1(1)
1.2 Electrons in Chemistry
1(4)
1.2.1 Wave-Particle Duality
3(1)
1.2.2 The Schrodinger Approximation
3(1)
1.2.3 Four-Dimensional Waves
4(1)
1.2.4 Nonlinear Schrodinger Equation
5(1)
1.3 Molecular Structure
5(6)
1.3.1 Molecular Modelling
6(2)
1.3.2 Atomic and Molecular Structure
8(1)
References
9(2)
2 The Classical Background
11(14)
2.1 Introduction
11(3)
2.1.1 The Copernican Revolution
13(1)
2.2 Newtonian Physics
14(1)
2.3 Daltonian Chemistry
15(3)
2.4 The Aftermath
18(7)
2.4.1 Dalton's Legacy
18(2)
2.4.2 Classical Mechanics
20(3)
References
23(2)
3 Great Discoveries
25(30)
3.1 Introduction
25(1)
3.2 Periodic Table of the Elements
26(11)
3.2.1 Static Model of Chemical Affinity
29(4)
3.2.2 The Planetary Quantum Model
33(3)
3.2.3 The New Periodic Table
36(1)
3.3 The Electromagnetic Field
37(10)
3.3.1 Wave Theory of Light
37(2)
3.3.2 Magnetism
39(1)
3.3.3 Electrostatics
40(3)
3.3.4 Electromagnetism
43(3)
3.3.5 Maxwell's Theory
46(1)
3.4 Electromagnetic Radiation
47(4)
3.4.1 General Theory of Wave Motion
48(3)
3.5 Conclusion
51(4)
References
52(3)
4 Theoretical Response
55(24)
4.1 Introduction
55(2)
4.1.1 The Electromagnetic Field
55(1)
4.1.2 Periodicity of Atomic Matter
56(1)
4.1.3 Theories in Conflict
57(1)
4.2 The Theory of Relativity
57(9)
4.2.1 Special Relativity
58(5)
4.2.2 General Relativity
63(3)
4.3 Quantum Theory
66(13)
4.3.1 Global Gauge Invariance
67(2)
4.3.2 Wave Mechanics
69(5)
4.3.3 Local Gauge Invariance
74(2)
4.3.4 Space-Time Manifold and Tangent Space
76(1)
4.3.5 The Periodic Function
77(1)
References
78(1)
5 State of the Art
79(12)
5.1 Introduction
79(2)
5.2 Chemistry at the Crossroads
81(8)
5.2.1 The Bonding Model
82(2)
5.2.2 Molecular Structure
84(2)
5.2.3 Stereochemistry
86(1)
5.2.4 The Particle Problem
86(1)
5.2.5 Reaction Mechanisms
87(1)
5.2.6 Atomic Periodicity
88(1)
5.3 Conclusion
89(2)
References
89(2)
6 The Forgotten Dimension
91(26)
6.1 Introduction
91(2)
6.2 The Classical World
93(1)
6.3 Non-classical World
93(2)
6.3.1 Potential Theory
94(1)
6.4 The Spin Function
95(4)
6.4.1 Four-Dimensional Action
97(1)
6.4.2 Spin Correlation
98(1)
6.5 The Time Enigma
99(3)
6.5.1 Quantum Potential
100(1)
6.5.2 Time Flow
101(1)
6.6 Space-Time Curvature
102(3)
6.6.1 Space-Time Topology
103(2)
6.7 Quantum Effects
105(12)
6.7.1 Exclusion Principle
105(1)
6.7.2 Wave-Particle Duality
106(1)
6.7.3 Quantum Probability
107(3)
6.7.4 Measurement Problem
110(2)
6.7.5 Uncertainty Principle
112(1)
6.7.6 Fine-Structure Constant
113(1)
References
113(4)
7 Nonlinear Chemistry
117(36)
7.1 Introduction
117(1)
7.2 Wave Model of the Electron
118(13)
7.2.1 Wave Mechanics
119(3)
7.2.2 Matter Waves
122(5)
7.2.3 Two-Wave Models
127(1)
7.2.4 Fine-Structure Parameter
128(3)
7.3 Nonlinear Systems
131(15)
7.3.1 Hydrodynamic Analogy
132(1)
7.3.2 Schrodinger Oscillator
132(2)
7.3.3 Korteweg-de Vries Equation
134(1)
7.3.4 Solitons
135(1)
7.3.5 Soliton Eigenvalues
136(1)
7.3.6 Soliton Models
137(3)
7.3.7 Electronic Solitons
140(6)
7.4 Chemical Aspects
146(7)
7.4.1 Solving the Equation
148(1)
7.4.2 Chemical Interaction
148(1)
References
149(4)
8 Matter-Wave Mechanics
153(28)
8.1 Introduction
153(2)
8.2 The Aether and Matter
155(10)
8.2.1 Alarming Phenomena
156(1)
8.2.2 Generation of Mass
157(1)
8.2.3 Space-Time Topology
157(7)
8.2.4 The Vacuum
164(1)
8.3 The Wave Model
165(4)
8.3.1 Projective Solution
166(3)
8.4 Matter in Space-Time
169(12)
8.4.1 Fibonacci Numbers
170(8)
References
178(3)
9 Chemical Wave Structures
181(26)
9.1 Introduction
181(1)
9.2 Electronic Structures
182(3)
9.2.1 Numbers and Waves
183(2)
9.3 Atomic Structure
185(1)
9.4 Chemical Concepts
186(16)
9.4.1 Atomic Size
186(2)
9.4.2 The Bohr-de Broglie Model
188(2)
9.4.3 Ionization Radii
190(1)
9.4.4 Electronegativity
191(1)
9.4.5 Covalent Interaction
192(1)
9.4.6 Bond Order
193(1)
9.4.7 General Covalence
194(2)
9.4.8 Atomic Polarizability
196(2)
9.4.9 Atomic Radii
198(4)
9.4.10 Final Results
202(1)
9.5 Molecular Structure
202(2)
9.5.1 Molecular Modelling
203(1)
9.6 Reaction Mechanism
204(3)
References
205(2)
10 A Fresh Start
207(28)
10.1 Introduction
207(1)
10.2 The Copenhagen Interpretation
208(8)
10.2.1 Quantum Mechanics
209(1)
10.2.2 The Quantum Postulate
210(3)
10.2.3 Atomic Model
213(3)
10.2.4 Quantum Chemistry
216(1)
10.3 Two New Models
216(6)
10.3.1 Superconductivity
216(2)
10.3.2 Cold Fusion
218(4)
10.4 The Common Wave Model
222(2)
10.4.1 The Periodic Function
223(1)
10.5 New Horizons
224(7)
10.5.1 Nanostructures
224(5)
10.5.2 Quasicrystals
229(2)
10.6 Future Prospects
231(4)
10.6.1 The Space-Time Vacuum
231(1)
10.6.2 Perceptions in Linear Tangent Space
232(1)
10.6.3 Four-Dimensional Reality
232(1)
References
233(2)
Index 235