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1 | (44) |
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2 | (11) |
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3 | (1) |
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4 | (2) |
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6 | (1) |
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7 | (2) |
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9 | (4) |
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12 | (1) |
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13 | (5) |
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13 | (1) |
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14 | (4) |
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17 | (1) |
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18 | (12) |
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Discrete probability distributions |
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19 | (1) |
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Continuous probability distributions |
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20 | (1) |
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21 | (1) |
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22 | (1) |
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Linear transformation and the variance |
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23 | (1) |
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24 | (6) |
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27 | (1) |
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27 | (3) |
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Temperature and the Boltzmann factor |
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30 | (15) |
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30 | (1) |
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31 | (2) |
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The microstates and macrostates |
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33 | (1) |
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A statistical definition of temperature |
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34 | (2) |
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36 | (1) |
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36 | (4) |
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Applications of the Boltzmann distribution |
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40 | (5) |
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44 | (1) |
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44 | (1) |
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II. Kinetic theory of gases |
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45 | (28) |
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The Maxwell--Boltzmann distribution |
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46 | (8) |
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The velocity distribution |
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46 | (1) |
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47 | (2) |
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48 | (1) |
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The mean kinetic energy of a gas molecule |
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48 | (1) |
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49 | (1) |
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Experimental justification |
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49 | (5) |
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52 | (2) |
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54 | (8) |
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55 | (1) |
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55 | (1) |
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The number of molecules travelling in a certain direction at a certain speed |
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55 | (1) |
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The number of molecules hitting a wall |
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56 | (1) |
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56 | (2) |
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58 | (4) |
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59 | (3) |
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62 | (6) |
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62 | (2) |
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64 | (4) |
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67 | (1) |
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The mean free path and collisions |
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68 | (5) |
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68 | (1) |
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The collision cross-section |
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69 | (2) |
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71 | (2) |
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72 | (1) |
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III. Transport and thermal diffusion |
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73 | (30) |
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Transport properties in gases |
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74 | (14) |
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74 | (5) |
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79 | (2) |
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81 | (3) |
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84 | (4) |
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86 | (1) |
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87 | (1) |
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The thermal diffusion equation |
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88 | (15) |
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Derivation of the thermal diffusion equation |
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88 | (1) |
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The one-dimensional thermal diffusion equation |
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89 | (3) |
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92 | (1) |
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The thermal diffusion equation for a sphere |
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92 | (3) |
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95 | (2) |
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97 | (1) |
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98 | (5) |
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99 | (4) |
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103 | (18) |
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104 | (10) |
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104 | (2) |
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A system in thermal equilibrium |
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104 | (1) |
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104 | (2) |
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The first law of thermodynamics |
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106 | (2) |
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108 | (6) |
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111 | (3) |
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Isothermal and adiabatic processes |
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114 | (7) |
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114 | (2) |
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Isothermal expansion of an ideal gas |
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116 | (1) |
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Adiabatic expansion of an ideal gas |
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117 | (1) |
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117 | (4) |
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119 | (2) |
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121 | (42) |
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Heat engines and the second law |
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122 | (14) |
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The second law of thermodynamics |
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122 | (1) |
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123 | (3) |
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126 | (1) |
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Equivalence of Clausius and Kelvin statements |
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127 | (1) |
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127 | (2) |
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Heat engines running backwards |
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129 | (1) |
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130 | (6) |
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133 | (1) |
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133 | (3) |
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136 | (17) |
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136 | (1) |
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136 | (2) |
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138 | (2) |
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140 | (2) |
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The statistical basis for entropy |
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142 | (1) |
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143 | (2) |
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145 | (1) |
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146 | (7) |
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149 | (4) |
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153 | (10) |
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Information and Shannon entropy |
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153 | (2) |
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Information and thermodynamics |
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155 | (1) |
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156 | (2) |
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158 | (5) |
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161 | (1) |
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161 | (2) |
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VI. Thermodynamics in action |
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163 | (36) |
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164 | (18) |
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164 | (1) |
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165 | (1) |
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166 | (1) |
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167 | (1) |
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168 | (2) |
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170 | (12) |
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178 | (4) |
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Rods, bubbles and magnets |
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182 | (11) |
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182 | (3) |
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185 | (1) |
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186 | (7) |
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192 | (1) |
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193 | (6) |
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Different statements of the third law |
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193 | (2) |
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Consequences of the third law |
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195 | (4) |
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198 | (1) |
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VII. Statistical mechanics |
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199 | (74) |
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200 | (9) |
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200 | (3) |
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203 | (2) |
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Translational motion in a monatomic gas |
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203 | (1) |
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Rotational motion in a diatomic gas |
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203 | (1) |
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Vibrational motion in a diatomic gas |
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204 | (1) |
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The heat capacity of a solid |
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205 | (1) |
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205 | (2) |
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207 | (2) |
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208 | (1) |
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209 | (12) |
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Writing down the partition function |
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210 | (1) |
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Obtaining the functions of state |
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211 | (7) |
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218 | (1) |
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Combining partition functions |
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218 | (3) |
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219 | (2) |
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Statistical mechanics of an ideal gas |
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221 | (11) |
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221 | (2) |
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223 | (1) |
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224 | (1) |
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Functions of state of the ideal gas |
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225 | (3) |
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228 | (1) |
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Heat capacity of a diatomic gas |
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229 | (3) |
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230 | (2) |
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232 | (15) |
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A definition of the chemical potential |
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232 | (1) |
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The meaning of the chemical potential |
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233 | (2) |
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235 | (1) |
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236 | (2) |
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Chemical potential as Gibbs function per particle |
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238 | (1) |
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238 | (1) |
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Particle number conservation laws |
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239 | (1) |
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Chemical potential and chemical reactions |
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240 | (7) |
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245 | (1) |
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246 | (1) |
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247 | (16) |
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The classical thermodynamics of electromagnetic radiation |
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248 | (1) |
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249 | (1) |
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250 | (2) |
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252 | (1) |
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The statistical mechanics of the photon gas |
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253 | (1) |
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254 | (3) |
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Cosmic Microwave Background radiation |
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257 | (1) |
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The Einstein A and B coefficients |
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258 | (5) |
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261 | (1) |
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262 | (1) |
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263 | (10) |
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263 | (2) |
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265 | (3) |
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268 | (5) |
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271 | (1) |
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271 | (2) |
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VIII. Beyond the ideal gas |
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273 | (80) |
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274 | (6) |
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Relativistic dispersion relation for massive particles |
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274 | (1) |
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The ultrarelativistic gas |
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274 | (3) |
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Adiabatic expansion of an ultrarelativistic gas |
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277 | (3) |
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279 | (1) |
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280 | (17) |
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280 | (8) |
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288 | (2) |
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290 | (4) |
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The law of corresponding states |
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294 | (3) |
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296 | (1) |
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297 | (8) |
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297 | (2) |
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299 | (1) |
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300 | (2) |
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302 | (3) |
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304 | (1) |
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305 | (20) |
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305 | (3) |
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Chemical potential and phase changes |
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308 | (1) |
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The Clausius--Clapeyron equation |
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308 | (5) |
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Stability & metastability |
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313 | (3) |
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316 | (2) |
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318 | (2) |
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Classification of phase transitions |
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320 | (5) |
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323 | (1) |
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323 | (2) |
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Bose--Einstein and Fermi--Dirac distributions |
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325 | (12) |
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325 | (1) |
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Wave functions of identical particles |
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326 | (3) |
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The statistics of identical particles |
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329 | (8) |
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332 | (1) |
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332 | (5) |
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Quantum gases and condensates |
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337 | (16) |
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The non-interacting quantum fluid |
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337 | (3) |
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340 | (5) |
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345 | (1) |
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Bose--Einstein condensation (BEC) |
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346 | (7) |
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351 | (1) |
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352 | (1) |
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353 | (80) |
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354 | (7) |
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Sound waves under isothermal conditions |
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355 | (1) |
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Sound waves under adiabatic conditions |
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355 | (1) |
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Are sound waves in general adiabatic or isothermal? |
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356 | (1) |
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Derivation of the speed of sound within fluids |
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357 | (4) |
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360 | (1) |
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360 | (1) |
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361 | (7) |
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361 | (1) |
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361 | (2) |
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363 | (1) |
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The Rankine--Hugoniot conditions |
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364 | (4) |
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367 | (1) |
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367 | (1) |
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Brownian motion and fluctuations |
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368 | (18) |
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368 | (3) |
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371 | (1) |
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372 | (1) |
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Fluctuations and the availability |
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373 | (2) |
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375 | (3) |
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378 | (8) |
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385 | (1) |
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385 | (1) |
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Non-equilibrium thermodynamics |
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386 | (12) |
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386 | (1) |
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387 | (1) |
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Proof of the Onsager reciprocal relations |
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388 | (3) |
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391 | (4) |
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Time reversal and the arrow of time |
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395 | (3) |
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397 | (1) |
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397 | (1) |
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398 | (15) |
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Gravitational interaction |
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399 | (5) |
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Gravitational collapse and the Jeans criterion |
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399 | (2) |
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401 | (1) |
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402 | (2) |
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404 | (1) |
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405 | (8) |
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Heat transfer by photon diffusion |
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405 | (2) |
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Heat transfer by convection |
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407 | (1) |
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408 | (4) |
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412 | (1) |
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412 | (1) |
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413 | (11) |
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Electron degeneracy pressure |
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413 | (2) |
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415 | (1) |
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416 | (2) |
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418 | (1) |
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419 | (1) |
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420 | (1) |
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Life, the Universe and Entropy |
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421 | (3) |
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423 | (1) |
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423 | (1) |
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424 | (9) |
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424 | (1) |
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The temperature profile in the atmosphere |
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425 | (2) |
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427 | (6) |
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432 | (1) |
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432 | (1) |
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433 | (1) |
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434 | (2) |
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436 | (15) |
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436 | (1) |
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436 | (3) |
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439 | (2) |
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441 | (1) |
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442 | (1) |
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443 | (1) |
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444 | (1) |
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445 | (1) |
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445 | (2) |
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447 | (1) |
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447 | (1) |
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Solution of the diffusion equation |
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448 | (1) |
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449 | (2) |
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D. The electromagnetic spectrum |
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451 | (1) |
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E. Some thermodynamical definitions |
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452 | (1) |
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F. Thermodynamic expansion formulae |
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453 | (1) |
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454 | (1) |
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H. Glossary of main symbols |
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455 | (2) |
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457 | (3) |
Index |
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460 | |