Preface |
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7 | (8) |
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Biomedical applications of EPR spectroscopy |
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15 | (18) |
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15 | (1) |
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15 | (1) |
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Reactive nitrogen species |
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16 | (1) |
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Consequences of free radical reactions with biomolecules |
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17 | (4) |
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17 | (2) |
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19 | (1) |
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20 | (1) |
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Free radicals and disease |
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21 | (6) |
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21 | (2) |
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23 | (1) |
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23 | (1) |
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24 | (1) |
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25 | (2) |
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27 | (1) |
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Selected biomedical EPR techniques |
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27 | (2) |
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27 | (1) |
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28 | (1) |
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29 | (4) |
EPR studies of radiation damage to DNA and related molecules |
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33 | (26) |
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33 | (1) |
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33 | (1) |
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Recent trends in DNA radiation chemistry |
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33 | (1) |
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34 | (1) |
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34 | (15) |
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34 | (8) |
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42 | (7) |
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49 | (7) |
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Track structure in DNA irradiated with heavy ions |
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49 | (1) |
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Studies of DNA-iron complexes |
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50 | (1) |
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Formation of 8-oxo-G in irradiated DNA by multiple one-electron oxidations |
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51 | (1) |
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Electron transfer versus differential fading of radicals |
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52 | (1) |
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Role of excited states in DNA damage-experimental and theoretical results |
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53 | (1) |
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Photoinduced radical formation in DNA |
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53 | (2) |
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DNA yields and strand breaks |
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55 | (1) |
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Electron induced cleavage of thymine dimers |
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56 | (1) |
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56 | (1) |
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56 | (3) |
Measurement of interspin distances by EPR |
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59 | (17) |
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Introduction to distance determination |
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59 | (1) |
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60 | (1) |
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60 | (1) |
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Accessibility to paramagnetic relaxation reagents |
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61 | (1) |
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Relaxation of free radicals due to nearby paramagnetic metals |
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62 | (1) |
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62 | (7) |
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Determination of relative orientations of radicals in DEER |
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67 | (1) |
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67 | (1) |
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Uncertainty in distributions |
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67 | (1) |
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Metal-metal distances by DEER |
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68 | (1) |
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Limitations of the DEER method |
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68 | (1) |
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Examples of applications of DEER |
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69 | (1) |
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69 | (2) |
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69 | (1) |
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Out-of-phase echo detection |
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70 | (1) |
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Biological studies at room temperature |
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71 | (1) |
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Sample preparation limitations |
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71 | (1) |
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71 | (1) |
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71 | (5) |
Time-resolved electron paramagnetic resonance studies of transient organic radicals |
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76 | (29) |
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76 | (1) |
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Photochemical applications |
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77 | (22) |
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78 | (2) |
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Photoreduction of sensitizers |
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80 | (2) |
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82 | (6) |
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88 | (2) |
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Addition reactions to double bonds |
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90 | (4) |
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94 | (5) |
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99 | (1) |
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100 | (1) |
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100 | (5) |
EPR of paramagnetic centres on solid surfaces |
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105 | (26) |
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105 | (1) |
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105 | (2) |
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107 | (17) |
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107 | (5) |
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112 | (2) |
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114 | (1) |
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115 | (3) |
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118 | (1) |
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119 | (2) |
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121 | (1) |
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122 | (2) |
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124 | (1) |
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124 | (2) |
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126 | (5) |
EPR of exchange coupled oligomers |
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131 | (31) |
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131 | (1) |
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131 | (2) |
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133 | (9) |
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133 | (2) |
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135 | (1) |
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136 | (1) |
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136 | (1) |
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Polymetallic cores encapsulated into polyoxometalates |
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137 | (1) |
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138 | (1) |
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Single-molecule magnets (SMMs) |
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139 | (3) |
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142 | (1) |
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143 | (13) |
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143 | (2) |
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145 | (1) |
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146 | (1) |
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Manganese (excluding photosystems) |
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147 | (1) |
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148 | (3) |
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Other iron-sulfur centres |
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151 | (2) |
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153 | (1) |
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153 | (1) |
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153 | (2) |
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155 | (1) |
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156 | (6) |
Continuous wave and pulsed EPR analyses of metalloproteins |
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162 | (22) |
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162 | (1) |
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163 | (2) |
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Detecting nuclear interactions |
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165 | (7) |
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Now you see it, now you don't |
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172 | (1) |
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Interpretation of EPR data |
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173 | (1) |
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Choosing between different experiments |
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174 | (2) |
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Example 1. The study of high-spin ferric heme proteins |
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176 | (2) |
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Example 2. The nickel-containing methyl-coenzyme M reductase |
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178 | (1) |
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179 | (1) |
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180 | (1) |
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180 | (4) |
An EPR tool box for exploring the formation and properties of ordered template mesoporous materials |
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184 | (32) |
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184 | (3) |
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Templated mesoporous materials |
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185 | (2) |
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The formation mechanism of TMM |
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187 | (4) |
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181 | (7) |
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Methods for mechanistic studies |
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188 | (2) |
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The formation of TMM with ionic templates |
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190 | (1) |
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The formation of TMM with non-ionic templates |
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191 | (1) |
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191 | (7) |
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191 | (1) |
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192 | (6) |
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EPR investigation of the formation of TMM |
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198 | (13) |
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The location of the nitroxide label in micelles |
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198 | (1) |
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199 | (4) |
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203 | (3) |
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Studies of cubic mesoporous materials |
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206 | (5) |
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Studies of wormlike mesoporous materials |
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211 | (1) |
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211 | (1) |
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212 | (1) |
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213 | (3) |
High-field pulse EPR instrumentation |
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216 | |
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216 | (1) |
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217 | (1) |
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High-field EPR spectroscopy |
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217 | (1) |
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History of high-frequency pulse EPR |
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218 | (2) |
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220 | (6) |
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220 | (3) |
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223 | (2) |
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225 | (1) |
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Averaging and pulse repetition time |
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226 | (1) |
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226 | (3) |
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Current system performance |
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226 | (1) |
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227 | (1) |
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Induction mode cavities and sample holders |
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227 | (1) |
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Pulse sources and pulse generation |
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227 | (1) |
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Phase coherent detection system |
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228 | (1) |
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Spectrometer front end system design |
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228 | (1) |
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229 | (1) |
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229 | (2) |
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Fourier transform EPR and FID detection |
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229 | (1) |
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Hyperfine and electron-dipolar spectroscopies |
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230 | (1) |
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Dynamic nuclear polarisation (DNP) |
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230 | (1) |
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231 | (1) |
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231 | |