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1 Introduction: Basic Definitions |
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1 | (26) |
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1 | (1) |
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1.2 Property and Variables |
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2 | (1) |
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2 | (1) |
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1.4 Measures of Amounts and Fractions |
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3 | (2) |
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5 | (1) |
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6 | (2) |
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Example 1.1 Conversion of temperature units |
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7 | (1) |
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8 | (2) |
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Example 1.2 Pressure calculations |
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9 | (1) |
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Example 1.3 Pressure conversions |
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10 | (1) |
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Example 1.4 Absolute pressure estimations |
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10 | (1) |
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10 | (2) |
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12 | (7) |
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1.9.1 Thermodynamic Equilibrium State |
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13 | (1) |
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1.9.2 Ideal-Gas Equation of State |
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13 | (1) |
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1.9.3 Saturated Liquid and Saturated Vapor State |
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14 | (1) |
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14 | (2) |
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Example 1.5 Energy change during evaporation |
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16 | (1) |
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Example 1.6 Energy change during condensation |
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16 | (1) |
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1.9.5 Saturated Liquid-Vapor Mixture |
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17 | (1) |
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Example 1.7 Quality of a saturated liquid and vapor mixture of a steam |
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17 | (1) |
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1.9.6 Partial Pressure and Saturation Pressure |
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18 | (1) |
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Example 1.8 Estimation of saturated vapor pressure |
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18 | (1) |
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19 | (8) |
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21 | (5) |
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26 | (1) |
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2 Energy and Energy Types |
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27 | (44) |
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27 | (1) |
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28 | (2) |
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28 | (1) |
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29 | (1) |
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2.3 Non Renewable Energy Sources |
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30 | (7) |
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31 | (1) |
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2.3.2 Petroleum (Crude Oil) |
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32 | (1) |
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2.3.3 Petroleum Fractions |
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33 | (2) |
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35 | (1) |
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36 | (1) |
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2.4 Heating Value of Fuels |
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37 | (5) |
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37 | (1) |
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Example 2.1 Energy consumption by a car |
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38 | (1) |
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Example 2.2 Fuel consumption by a low and a high-mileage car |
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38 | (3) |
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Example 2.3 Daily consumption of natural gas by a city |
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41 | (1) |
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Example 2.4 Energy consumed by a car |
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41 | (1) |
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2.5 Renewable Energy Resources |
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42 | (14) |
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43 | (1) |
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43 | (5) |
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2.5.3 Biomass and Bioenergy |
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48 | (3) |
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Example 2.5 Gross heating value estimations |
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51 | (2) |
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53 | (1) |
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54 | (1) |
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55 | (1) |
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2.5.7 Projection on Renewable Energy Contributions |
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56 | (1) |
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56 | (1) |
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57 | (2) |
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Example 2.6 Electricity consumption of a laptop computer |
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59 | (1) |
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59 | (1) |
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60 | (1) |
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2.10 Energy and Global Warming |
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60 | (3) |
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Example 2.7 Carbon dioxide emission from natural gas combustion |
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62 | (1) |
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2.11 Tackling the Global Warming |
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63 | (8) |
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Example 2.8 Consumption of coal and emission of carbon dioxide from coal |
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63 | (1) |
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Example 2.9 Reducing air pollution by geothermal heating |
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64 | (1) |
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Student Concern of Global Warning |
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64 | (1) |
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65 | (3) |
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68 | (3) |
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3 Mechanical Energy and Electrical Energy |
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71 | (28) |
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71 | (1) |
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72 | (1) |
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Example 3.1 Calculation of the kinetic energy for a flowing fluid |
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72 | (1) |
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Example 3.2 Kinetic energy of a car |
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73 | (1) |
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73 | (2) |
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Example 3.3 Potential energy change of water |
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74 | (1) |
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Example 3.4 Energy of an elevator |
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75 | (1) |
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75 | (3) |
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Example 3.5 Pressure energy of a hydraulic turbine |
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76 | (1) |
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76 | (1) |
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Example 3.6 Pumping water |
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77 | (1) |
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Example 3.7 Calculation of the power needed to pump water |
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77 | (1) |
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78 | (1) |
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78 | (1) |
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79 | (8) |
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79 | (1) |
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Example 3.8 Power conversions |
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80 | (1) |
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81 | (1) |
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Example 3.9 Expansion and compression work of an ideal gas |
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82 | (1) |
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Example 3.10 Isothermal compression work |
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83 | (1) |
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3.7.3 Isentropic Process Work |
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83 | (1) |
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Example 3.11 Isentropic compression of air |
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84 | (1) |
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3.7.4 Polytropic Process Work |
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84 | (1) |
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Example 3.12 Calculation of work done by a piston on an ideal gas |
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84 | (1) |
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Example 3.13 Polytropic expansion of air |
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85 | (1) |
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86 | (1) |
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Example 3.14 Estimation of shaft power |
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86 | (1) |
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86 | (1) |
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Example 3.15 Estimation of spring work |
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87 | (1) |
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87 | (4) |
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3.8.1 Electric Potential Energy |
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88 | (1) |
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3.8.2 Estimation of Electrical Energy |
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89 | (1) |
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89 | (1) |
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90 | (1) |
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Example 3.16 Estimation of electrical work |
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91 | (1) |
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91 | (8) |
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92 | (6) |
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98 | (1) |
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4 Internal Energy and Enthalpy |
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99 | (48) |
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99 | (2) |
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101 | (6) |
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Example 4.1 Unit conversions of heat capacity |
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103 | (1) |
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Example 4.2 Calculation of internal energy change |
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104 | (1) |
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Example 4.3 Determination of state properties |
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105 | (1) |
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Example 4.4 Heat value of a saturated liquid and vapor mixture of a steam |
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106 | (1) |
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107 | (12) |
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108 | (1) |
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109 | (1) |
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4.3.3 Heating with Phase Change |
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110 | (1) |
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Example 4.5 Calculation of heat of vaporization using Antoine equation and Clasius-Clapeyron equation |
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111 | (1) |
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Example 4.6 Estimation of change of enthalpy with sensible and latent heat |
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112 | (1) |
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Example 4.7 Estimation of heat of vaporization at another temperature |
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113 | (1) |
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113 | (2) |
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Example 4.8 Estimation of standard heat of reaction |
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115 | (1) |
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Example 4.9 Estimation of standard heats of reaction from standard heats of formation |
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116 | (1) |
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4.3.5 Standard Heat of Combustion |
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117 | (1) |
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Example 4.10 Determination of standard heats of reaction |
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118 | (1) |
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Example 4.11 Estimation of standard heats of combustion from standard heats of formation |
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118 | (1) |
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4.4 Effect of Temperature on the Heat of Reaction |
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119 | (2) |
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Example 4.12 Estimation of standard heat of reaction at a temperature other than 298 K |
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120 | (1) |
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4.5 Standard Enthalpy Changes |
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121 | (1) |
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4.6 Adiabatic Flame Temperature |
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121 | (3) |
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Example 4.13 Maximum flame temperature |
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122 | (2) |
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4.7 Air Pollution from Combustion Processes |
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124 | (1) |
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124 | (2) |
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Example 4.14 Estimation of partial enthalpies |
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124 | (2) |
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4.9 Heat Measurements by Calorimeter |
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126 | (1) |
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Example 4.15 Measurement of heat capacity of a metal in a calorimeter |
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126 | (1) |
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4.10 Psychrometric Diagram |
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127 | (3) |
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Example 4.16 Determination of air properties on a psychrometric chart |
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129 | (1) |
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130 | (3) |
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Example 4.17 Estimation of radiation heat transfer |
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132 | (1) |
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133 | (1) |
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134 | (1) |
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135 | (12) |
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136 | (9) |
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145 | (2) |
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147 | (28) |
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147 | (1) |
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148 | (2) |
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150 | (3) |
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5.3.1 Unsteady-State Flow Systems |
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150 | (1) |
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5.3.2 Steady-State Flow Systems |
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151 | (1) |
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Example 5.1 Closed system energy balance calculations |
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152 | (1) |
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153 | (1) |
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154 | (2) |
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Example 5.2 Exergy loss calculations |
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155 | (1) |
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156 | (9) |
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5.6.1 Turbines Compressors and Pumps |
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156 | (1) |
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Example 5.3 Turbine calculations |
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157 | (1) |
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Example 5.4 Compressor calculations |
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157 | (1) |
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Example 5.5 Pump power calculation |
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158 | (1) |
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5.6.2 Nozzles and Diffusers |
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159 | (1) |
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Example 5.6 Nozzle calculations |
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159 | (1) |
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160 | (1) |
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Example 5.7 Mixing chamber calculations |
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160 | (1) |
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161 | (1) |
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Example 5.8 Throttling process calculations |
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162 | (1) |
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Example 5.9 Throttling of a refrigerant |
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162 | (1) |
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163 | (1) |
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Example 5.10 Heat exchanger calculations |
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163 | (1) |
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5.6.6 Pipe and Duct Flows |
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164 | (1) |
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5.7 Energy Balance in a Cyclic Process |
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165 | (10) |
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166 | (7) |
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173 | (2) |
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175 | (54) |
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175 | (1) |
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6.2 Electric Power Production |
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175 | (3) |
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Example 6.1 Power production by an adiabatic steam turbine |
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177 | (1) |
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6.3 Transmission of Energy |
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178 | (2) |
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6.3.1 Distributed Energy Resources |
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179 | (1) |
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6.4 Power Producing Engine Cycles |
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180 | (9) |
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Example 6.2 Steam power production |
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181 | (1) |
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Example 6.3 Steam flow rate calculation in a power plant |
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182 | (1) |
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183 | (1) |
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Example 6.4 Power output from a Carnot cycle |
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183 | (1) |
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184 | (2) |
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Example 6.5 Analysis of a simple ideal Rankine cycle |
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186 | (1) |
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187 | (1) |
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188 | (1) |
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189 | (1) |
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6.5 Improving the Power Production in Steam Power Plants |
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189 | (6) |
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6.5.1 Modification of Operating Conditions of the Condenser and Boiler |
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189 | (1) |
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6.5.2 Reheating the Steam |
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190 | (1) |
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Example 6.6 Simple reheat Rankine cycle in a steam power plant |
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190 | (2) |
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192 | (1) |
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Example 6.7 Power output of ideal regenerative Rankine cycle |
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192 | (2) |
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6.5.4 Reheat-Regenerative Rankine Cycle |
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194 | (1) |
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Example 6.8 Ideal reheat-regenerative cycle |
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194 | (1) |
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6.6 Geothermal Power Plants |
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195 | (2) |
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Example 6.9 A steam power plant using a geothermal energy source |
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196 | (1) |
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197 | (3) |
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Example 6.10 Energy output in a cogeneration plant |
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198 | (1) |
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Example 6.11 Estimation of process heat in a cogeneration plant |
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199 | (1) |
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200 | (1) |
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201 | (1) |
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Example 6.12 Hydroelectric power output |
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202 | (1) |
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202 | (3) |
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Example 6.13 Windmill power estimations |
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204 | (1) |
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205 | (2) |
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207 | (1) |
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208 | (4) |
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6.13.1 Direct Methanol Fuel Cells |
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210 | (1) |
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6.13.2 Microbial Fuel Cell |
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211 | (1) |
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6.14 Biomass and Bioenergy Production |
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212 | (4) |
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6.14.1 Bioethanol Production |
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213 | (1) |
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6.14.2 Biodiesel and Green Diesel Production |
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213 | (2) |
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6.14.3 Energy from Solid Waste |
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215 | (1) |
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6.15 Other Energy Production Opportunities |
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216 | (1) |
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6.16 Levelized Energy Cost |
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216 | (2) |
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218 | (1) |
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218 | (11) |
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6.18.1 Ecological Planning |
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219 | (1) |
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6.18.2 Coal-Fired Power Plants |
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220 | (1) |
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6.18.3 Nuclear Power Plants |
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220 | (1) |
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221 | (5) |
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226 | (3) |
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229 | (76) |
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229 | (2) |
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7.2 Series of Energy Conversions |
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231 | (1) |
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7.3 Conversion of Chemical Energy of Fuel to Heat |
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232 | (2) |
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7.3.1 Heating Value of a Fuel |
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232 | (1) |
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Example 7.1 Estimation of lower heating value from higher heating value |
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233 | (1) |
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Example 7.2 Estimating the heating values from the standard heat of combustion |
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233 | (1) |
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7.4 Thermal Efficiency of Energy Conversions |
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234 | (1) |
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7.5 Ideal Fluid-Flow Energy Conversions |
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235 | (4) |
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Example 7.3 Maximum work (ideal work) calculations |
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237 | (1) |
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Example 7.4 Isentropic turbine efficiency |
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238 | (1) |
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239 | (2) |
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Example 7.5 Estimation of lost work |
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239 | (1) |
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Example 7.6 Estimation of a minimum power required in a compressor |
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240 | (1) |
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7.7 Efficiency of Mechanical Conversions |
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241 | (2) |
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Example 7.7 Heat loss in an electric motor |
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242 | (1) |
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Example 7.8 Mechanical efficiency of a pump |
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243 | (1) |
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7.8 Conversion of Thermal Energy by Heat Engines |
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243 | (30) |
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Example 7.9 Thermal efficiency of a heat engine |
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246 | (1) |
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Example 7.10 Fuel consumption of a car |
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246 | (1) |
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7.8.1 Air-Standard Assumptions |
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247 | (1) |
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7.8.2 Isentropic Processes of Ideal Gases |
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247 | (1) |
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7.8.3 Conversion of Mechanical Energy by Electric Generator |
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248 | (1) |
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7.8.4 Carnot Engine Efficiency |
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249 | (2) |
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7.8.5 Endoreversible Heat Engine Efficiency |
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251 | (1) |
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7.8.6 Rankine Engine Efficiency |
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252 | (1) |
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Example 7.11 Steam turbine efficiency and power output |
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252 | (2) |
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Example 7.12 Estimation of thermal efficiency of a Rankine cycle |
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254 | (2) |
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7.8.7 Brayton Engine Efficiency |
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256 | (2) |
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Example 7.13 Simple ideal Brayton cycle calculations with variable specific heats |
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258 | (1) |
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Example 7.14 Thermal efficiency of an actual Brayton cycle with variable specific heats |
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259 | (2) |
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Example 7.15 Ideal Brayton cycle with constant specific heats |
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261 | (1) |
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7.8.8 Otto Engine Efficiency |
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262 | (2) |
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Example 7.16 Efficiency calculations of ideal Otto engine with variable specific heats |
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264 | (2) |
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Example 7.17 Efficiency calculations of an ideal Otto cycle with constant specific heats |
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266 | (1) |
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7.8.9 Diesel Engine Efficiency |
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267 | (1) |
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Example 7.18 Thermal efficiency of an ideal Diesel engine with the constant specific heats |
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268 | (1) |
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Example 7.19 Thermal efficiency of an ideal Diesel engine with variable specific heats |
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269 | (2) |
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7.8.10 Ericsson and Stirling Engine Efficiency |
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271 | (1) |
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7.8.11 Atkinson Engine Efficiency |
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272 | (1) |
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7.9 Improving Efficiency of Heat Engines |
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273 | (1) |
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273 | (3) |
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Example 7.20 Efficiency of a hydraulic turbine |
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274 | (1) |
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Example 7.21 Pumped energy in a hydropower plant |
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275 | (1) |
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276 | (1) |
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Example 7.22 Efficiency of a wind turbine |
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276 | (1) |
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7.12 Geothermal Electricity |
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277 | (1) |
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7.13 Ocean Thermal Energy Conversion |
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277 | (1) |
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7.14 Thermoelectric Effect |
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278 | (1) |
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7.15 Efficiency of Heat Pumps and Refrigerators |
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278 | (7) |
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279 | (2) |
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Example 7.23 Heat pump calculations |
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281 | (1) |
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281 | (1) |
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Example 7.24 Analysis of a refrigeration cycle |
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282 | (2) |
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Example 7.25 Heat rejection by a refrigerator |
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284 | (1) |
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Example 7.26 Coefficient of performance of a vapor-compression refrigeration cycle |
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284 | (1) |
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7.16 Efficiency of Fuel Cells |
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285 | (1) |
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7.17 Energy Conversions in Biological Systems |
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286 | (19) |
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7.17.1 Energy Conversion by Oxidative Phosphorylation |
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286 | (1) |
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7.17.2 Energy from Photosynthesis |
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287 | (1) |
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287 | (1) |
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287 | (1) |
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7.17.5 Converting Biomass to Biofuels |
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288 | (1) |
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289 | (13) |
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302 | (3) |
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305 | (38) |
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8.1 Energy Storage and Regulation |
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305 | (2) |
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305 | (2) |
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307 | (1) |
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8.2 Types of Energy Storage |
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307 | (1) |
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8.3 Thermal Energy Storage |
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308 | (15) |
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8.3.1 Solar Energy Storage |
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310 | (1) |
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8.3.2 Sensible Heat Storage |
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311 | (1) |
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Example 8.1 Sensible heat storage calculations |
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311 | (1) |
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8.3.3 Latent Heat Storage by Phase Changing Material |
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312 | (3) |
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Example 8.2 Heat storage calculations |
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315 | (1) |
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316 | (1) |
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8.3.5 Molten Salt Technology |
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316 | (1) |
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8.3.6 Seasonal Thermal Energy Storage |
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317 | (1) |
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8.3.7 Seasonal Solar Thermal Energy Storage for Greenhouse Heating |
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318 | (3) |
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Example 8.3 Latent heat storage calculations |
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321 | (1) |
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8.3.8 Underground Thermal Energy Storage Systems |
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321 | (1) |
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8.3.9 Aquifer Thermal Energy Storage |
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322 | (1) |
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8.3.10 Borehole Thermal Energy Systems |
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323 | (1) |
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8.4 Electric Energy Storage |
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323 | (6) |
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8.4.1 Hydroelectric Energy Storage |
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325 | (1) |
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Example 8.4 Pumped energy in a hydropower plant |
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326 | (1) |
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8.4.2 Electric Energy Storage in Battery |
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326 | (1) |
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8.4.3 Rechargeable Battery for Electric Car |
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327 | (2) |
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8.5 Chemical Energy Storage |
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329 | (4) |
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330 | (1) |
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8.5.2 Energy Storage in Biofuels |
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330 | (1) |
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8.5.3 Energy Storage in Voltaic Cell |
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331 | (2) |
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8.6 Mechanical Energy Storage |
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333 | (10) |
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8.6.1 Compressed Air Energy Storage |
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333 | (1) |
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Example 8.5 Maximum air compressed energy storage |
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334 | (1) |
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Example 8.6 Maximum air compressed energy storage in a large cavern |
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335 | (1) |
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8.6.2 Flywheel Energy Storage |
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335 | (1) |
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8.6.3 Hydraulic Accumulator |
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335 | (1) |
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336 | (1) |
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336 | (4) |
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340 | (3) |
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343 | (54) |
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9.1 Energy Conservation and Recovery |
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343 | (1) |
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9.2 Conservation of Energy in Industrial Processes |
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344 | (15) |
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9.2.1 Energy Conservation in Power Production |
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344 | (1) |
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Example 9.1 Energy conservation by regeneration in a Brayton cycle |
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345 | (3) |
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Example 9.2 Increasing the efficiency of a Rankine cycle by reducing the condenser pressure |
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348 | (2) |
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Example 9.3 Maximum possible efficiency calculation in Example 9.2 |
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350 | (1) |
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Example 9.4 Increasing the efficiency of a Rankine cycle by increasing the boiler pressure |
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351 | (1) |
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Example 9.5 Increasing the efficiency of a Rankine cycle by increasing the boiler temperature |
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352 | (1) |
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Example 9.6 Estimation of maximum possible efficiencies in Example 9.5 |
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353 | (1) |
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9.2.2 Energy Conservation in the Compression and Expansion Work |
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354 | (1) |
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Example 9.7 Energy conservation in a two-stage compression work by intercooling |
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355 | (1) |
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Example 9.8 Compressor efficiency and power input |
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356 | (1) |
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Example 9.9 Energy conservation in expansion by replacing a throttle valve with a turbine |
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357 | (1) |
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9.2.3 Conservation of Energy by High-Efficiency Electric Motors |
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358 | (1) |
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9.3 Energy Conservation in Home Heating and Cooling |
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359 | (5) |
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9.3.1 Home Heating by Fossil Fuels |
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360 | (1) |
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9.3.2 Home Heating by Electric Resistance |
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361 | (1) |
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9.3.3 Home Heating by Solar Systems |
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362 | (1) |
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Example 9.10 Heating a house by heat pump |
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363 | (1) |
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Example 9.11 Energy conservation in house heating by Carnot heat pump |
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363 | (1) |
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9.4 Energy Efficiency Standards |
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364 | (10) |
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9.4.1 Efficiency of Air Conditioner |
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365 | (1) |
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Example 9.12 Electricity cost of air conditioner |
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366 | (1) |
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9.4.2 Maximum Possible Efficiency for Cooling |
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366 | (1) |
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Example 9.13 Calculating the annual cost of power for an air conditioner |
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367 | (1) |
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Example 9.14 Reducing the cost of cooling with a unit operating at a higher SEER rating |
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367 | (1) |
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368 | (1) |
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Example 9.15 Comparison of energy sources of electricity with natural gas for heating |
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369 | (1) |
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Example 9.16 Overall plant efficiency and required amount of coal in a coal-fired steam power plant |
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369 | (1) |
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Example 9.17 Required amount of coal in a coal-fired steam power plant |
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370 | (1) |
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9.4.4 Fuel Efficiency of Vehicles |
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371 | (1) |
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Example 9.18 Fuel consumption of a car |
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372 | (1) |
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9.4.5 Energy Conservation While Driving |
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373 | (1) |
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Example 9.19 Fuel conservation with a more fuel-efficient car |
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373 | (1) |
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9.4.6 Regenerative Braking |
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374 | (1) |
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9.5 Energy Conservation in Electricity Distribution and Smart Grid |
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374 | (3) |
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375 | (1) |
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9.5.2 Energy Conservation in Lighting |
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375 | (1) |
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Example 9.20 Conservation of energy with compact fluorescent bulbs |
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|
376 | (1) |
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376 | (1) |
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9.6 Conservation of Energy and Sustainability |
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|
377 | (1) |
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9.7 Exergy Conservation and Exergy |
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|
378 | (1) |
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9.8 Energy Recovery on Utilities Using Pinch Analysis |
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378 | (19) |
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|
379 | (2) |
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Example 9.21 Energy conservation by the pinch analysis |
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|
381 | (2) |
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383 | (11) |
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394 | (3) |
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397 | (20) |
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10.1 Energy Coupling and Gibbs Free Energy |
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397 | (1) |
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10.2 Energy Coupling in Living Systems |
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398 | (1) |
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398 | (4) |
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399 | (1) |
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10.3.2 Electron Transport Chain and Adenosine Triphosphate (ATP) Synthesis |
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400 | (1) |
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401 | (1) |
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10.4 Simple Analysis of Energy Coupling |
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402 | (2) |
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Example 10.1 Efficiency of energy conversion of photosynthesis |
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403 | (1) |
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10.5 Variation of Energy Coupling |
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404 | (4) |
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10.5.1 Regulation of Energy Coupling |
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405 | (2) |
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407 | (1) |
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10.5.3 Slippages and Leaks |
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|
408 | (1) |
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408 | (2) |
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409 | (1) |
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409 | (1) |
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410 | (7) |
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Example 10.2 Oxidation of glucose |
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|
411 | (1) |
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Example 10.3 Daily energy expenditure |
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|
411 | (1) |
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Example 10.4 Energy expenditure in small organisms |
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|
412 | (1) |
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Example 10.5 Energy expenditure in an adult organism |
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|
413 | (1) |
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414 | (1) |
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415 | (2) |
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Appendix A Physical and Critical Properties |
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|
417 | (2) |
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Table A1 Physical properties of various organic and inorganic substances |
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|
417 | (1) |
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Table A2 Critical properties |
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|
418 | (1) |
|
Appendix B Heat Capacities |
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|
419 | (4) |
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Table B1 Heat capacities in the ideal-gas state |
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|
419 | (1) |
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Table B2 Heat capacities of liquids |
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|
420 | (1) |
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Table B3 Heat capacities of solids |
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|
420 | (1) |
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Table B4 Ideal-gas specific heats of various common gases |
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|
421 | (2) |
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Appendix C Enthalpy and Gibbs Free Energy of Formations at 298.15 K |
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|
423 | (2) |
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Table C1 Standard enthalpies and Gibbs energies of formation at 298.15 K |
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|
423 | (2) |
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Appendix D Ideal Gas Properties of Some Common Gases |
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|
425 | (6) |
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Table D1 Ideal-gas properties of air |
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|
425 | (3) |
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Table D2 Ideal-gas properties of carbon dioxide, CO2 |
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|
428 | (1) |
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Table D3 Ideal-gas properties of hydrogen, H2 |
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|
429 | (2) |
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Appendix E Thermochemical Properties |
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|
431 | (10) |
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Table E1 Saturated refrigerant R-134a |
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|
431 | (1) |
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Table E2 Superheated refrigerant R-134a |
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|
432 | (4) |
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Table E3 Saturated propane |
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|
436 | (1) |
|
Table E4 Superheated propane |
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|
437 | (4) |
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|
441 | (62) |
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Table F1 Saturated steam tables in English units |
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|
441 | (3) |
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Table F2 Superheated steam tables in English units |
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|
444 | (25) |
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Table F3 Saturated steam tables in SI units |
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|
469 | (4) |
|
Table F4 Superheated steam tables in SI units |
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|
473 | (30) |
Index |
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503 | |