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El. knyga: Engineering Chemistry: Fundamentals and Applications

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  • Formatas: PDF+DRM
  • Išleidimo metai: 23-May-2019
  • Leidėjas: Cambridge University Press
  • Kalba: eng
  • ISBN-13: 9781108579209
Kitos knygos pagal šią temą:
Engineering Chemistry: Fundamentals and ApplicationsDidesnis paveikslėlis
  • Formatas: PDF+DRM
  • Išleidimo metai: 23-May-2019
  • Leidėjas: Cambridge University Press
  • Kalba: eng
  • ISBN-13: 9781108579209
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Gain a detailed understanding of the fundamental concepts of chemistry and their engineering applications with this fully revised second edition. Catering to the needs of first and second semester undergraduate students from all branches of engineering taking courses on engineering chemistry, it offers new material on topics such as periodic properties, structure and bonding, gaseous states, ionic equilibrium, oxidation and reduction, Werner's coordination theory, Sidgwick coordination theory, valence bond theory, crystal field theory, bonding in coordination compounds, and isomerism in coordination compounds. Lucid language and an easy-to-learn approach help students to understand the basic concepts, use them to construct engineering materials, and solve problems associated with them. Each chapter is further strengthened by numerous examples and review questions.

Daugiau informacijos

Written in lucid language, the book offers a detailed treatment of fundamental concepts of chemistry and its engineering applications.
Preface to Second Edition xix
Preface to First Edition xxi
Acknowledgements xxv
1 Fuels 1(102)
1.1 Introduction
1(1)
1.2 Classification of Fuels
1(1)
1.3 Characteristics of a Good Fuel
2(2)
1.4 Calorific Value
4(2)
1.5 Determination of Calorific Value
6(10)
1.6 Solid Fuels
16(1)
1.7 Analysis of Coal
17(12)
1.8 Carbonisation of Coal
29(6)
1.9 Liquid Fuels
35(1)
1.10 Refining of Petroleum
36(2)
1.11 Cracking
38(3)
1.12 Synthetic Petrol
41(4)
1.13 Knocking
45(2)
1.14 Octane Rating
47(1)
1.15 Diesel Engine Fuels
48(1)
1.16 Knocking in Diesel Engine
48(1)
1.17 Cetane Rating/Cetane Number
49(1)
1.18 Reforming
49(2)
1.19 Non Petroleum Fuels, Power Alcohol and Aviation Fuel
51(2)
1.20 Gaseous Fuels
53(1)
1.21 Natural Gas
53(1)
1.22 Compressed Natural Gas (CNG)
54(1)
1.23 Liquified Petroleum Gas
54(1)
1.24 Coal Gas
55(1)
1.25 Oil Gas
56(1)
1.26 Producer Gas
57(2)
1.27 Water Gas
59(1)
1.28 Analysis of Flue Gas
60(2)
1.29 Combustion Calculations
62(13)
1.30 Renewable Sources of Energy
75(12)
1.31 Nuclear Fuels
87(7)
Summary
94(2)
Review Questions
96(2)
Multiple Choice Questions
98(5)
2 Water 103(106)
2.1 Introduction
103(1)
2.2 Sources of Water
104(1)
2.3 Effect of Water on Rocks and Minerals
105(1)
2.4 Common Impurities of Water
106(2)
2.5 Water Quality Standards
108(3)
2.6 Hardness of Water
111(8)
2.7 Disadvantages of Hard Water
119(1)
2.8 Water for Industries
120(2)
2.9 Boiler Problems with Hard Water
122(8)
2.10 Softening Methods: External Treatment Process
130(26)
2.11 Municipal Water Supply
156(7)
2.12 Desalination of Water
163(4)
2.13 Defluoridation
167(2)
2.14 Waste Water Management
169(4)
2.15 Chemical Analysis of Water
173(30)
Summary
203(2)
Review Questions
205(1)
Multiple Choice Questions
206(3)
3 Corrosion 209(46)
3.1 Introduction
209(1)
3.2 Effects of Corrosion
209(1)
3.3 Theories/Mechanism of Corrosion
210(7)
3.4 Types of Corrosion
217(7)
3.5 Passivity
224(1)
3.6 Galvanic Series
225(1)
3.7 Factors Influencing Corrosion
226(2)
3.8 Protection against Corrosion (Corrosion Control)
228(7)
3.9 Methods of Application of Metal Coatings
235(4)
3.10 Electroplating
239(6)
3.11 Electroless Plating
245(3)
Summary
248(2)
Review Questions
250(1)
Multiple Choice Questions
251(4)
4 Phase Rule 255(52)
4.1 Introduction
255(1)
4.2 Explanation of Terms
255(8)
4.3 Phase Diagram
263(1)
4.4 Water System
264(2)
4.5 Sulphur System
266(3)
4.6 Two-Component Systems
269(1)
4.7 Construction of Phase Diagrams
270(3)
4.8 Lead-Silver System
273(4)
4.9 Zinc-Magnesium System
277(3)
4.10 Iron-Carbon Alloy System
280(7)
4.11 Metal and Alloys
287(1)
4.12 Properties of Metals
287(3)
4.13 Alloys
290(1)
4.14 Purpose of Making Alloys
290(1)
4.15 Classification of Alloys
291(2)
4.16 Special Effects of Alloying Elements
293(1)
4.17 Alloy Steels and Their Applications
294(3)
4.18 Non-Ferrous Alloys
297(3)
4.19 Heat Treatment of Steel
300(2)
Summary
302(1)
Review Questions
303(1)
Multiple Choice Questions
304(3)
5 Engineering Materials 307(45)
5.1 Cement
307(11)
5.2 Gypsum (CaSO4.2H2O)
318(1)
5.3 Plaster of Paris (2CaSO4.H2O or CaSO4.1/2H20)
318(1)
5.4 Lime
319(1)
5.5 Glass
320(10)
5.6 Refractories
330(10)
5.7 Abrasives
340(2)
5.8 Insulating Materials
342(3)
Summary
345(2)
Review Questions
347(2)
Multiple Choice Questions
349(3)
6 Polymers 352(79)
6.1 Introduction
352(1)
6.2 Classification of Polymers
352(6)
6.3 Functionality
358(1)
6.4 Mechanism of Polymerisation
359(8)
6.5 Polymerisation Techniques
367(1)
6.6 Molecular Weight of Polymers
368(3)
6.7 Plastics
371(5)
6.8 Individual Polymers
376(11)
6.9 Rubbers (Elastomers)
387(6)
6.10 Fibres
393(7)
6.11 Speciality Polymers
400(8)
6.12 Properties of Polymers
408(8)
6.13 Degradation of Polymer
416(2)
6.14 Polymer Composites
418(3)
6.15 Adhesives
421(2)
Summary
423(2)
Review Questions
425(1)
Multiple Choice Questions
426(5)
7 Lubricants 431(24)
7.1 Introduction
431(1)
7.2 Functions of Lubricants
432(1)
7.3 Mechanism of Lubrication
432(4)
7.4 Classification of Lubricants
436(4)
7.5 Synthetic Lubricants
440(1)
7.6 Lubricating Emulsions
441(1)
7.7 Properties of Lubricants
442(8)
7.8 Selection of Lubricants for Different Types of Machinery
450(1)
Summary
451(1)
Review Questions
452(1)
Multiple Choice Questions
453(2)
8 Periodic Properties 455(26)
8.1 Introduction
455(1)
8.2 Basic Concepts
455(4)
8.3 Periodicity in Properties
459(1)
8.4 Types of Elements on the Basis of Their Electronic Configuration
460(1)
8.5 Periodic Trends in Properties of Elements
461(4)
8.6 Ionisation Enthalpy
465(2)
8.7 Electron Gain Enthalpy
467(2)
8.8 Electronegativity
469(4)
8.9 Polarising Power and Polarisability: Fajan's Rule
473(2)
8.10 Oxidation State
475(2)
Summary
477(1)
Review Questions
478(1)
Multiple Choice Questions
478(3)
9 Acid-base, Oxidation-Reduction and Intermolecular Forces 481(34)
9.1 Introduction
481(1)
9.2 Arrhenius Concept
481(1)
9.3 Bronsted-Lowry Concept
482(3)
9.4 The Solvent System Definition of Acids and Bases
485(1)
9.5 Lewis Concept of Acid and Base
486(2)
9.6 Hard Soft Acids and Bases
488(3)
9.7 Solubility Equilibria
491(2)
9.8 Common Ion Effect
493(2)
9.9 Oxidation and Reduction
495(1)
9.10 Oxidation Number (Oxidation State)
495(1)
9.11 Application of Principles of Oxidation and Reduction in Metallurgy
496(3)
9.12 Ellingham Diagram: Thermodynamical Aspect of the Reduction Process
499(3)
9.13 Molecular Interactions
502(3)
9.14 Real Gases and Critical Phenomenon
505(5)
Summary
510(1)
Review Questions
511(1)
Multiple Choice Questions
511(4)
10 Atomic Structure and Chemical Bonding 515(84)
10.1 Introduction
515(1)
10.2 Dual Nature of Radiation
516(1)
10.3 Dual Nature of Matter: de Broglie Equation
516(6)
10.4 Heisenberg's Uncertainty Principle
522(3)
10.5 Schrodinger Wave Equation
525(4)
10.6 Particle in a One Dimensional Box
529(6)
10.7 Particle in a Three Dimensional Box
535(3)
10.8 Schrodinger Wave Equation for Hydrogen and Hydrogen-Like System
538(6)
10.9 Huckel Molecular Orbital (HMO) Theory for Conjugate System
544(9)
10.10 Chemical Bonding
553(1)
10.11 Hybridisation of Orbitals
554(13)
10.12 Molecular Orbital Theory
567(19)
10.13 Bonding in Metals - Metallic Bond
586(6)
Summary
592(1)
Review Questions
593(2)
Multiple Choice Questions
595(4)
11 Solid State 599(59)
11.1 Introduction
599(1)
11.2 Types of Solids
599(2)
11.3 Crystal Lattice and Unit Cell
601(1)
11.4 Bravais Lattice
602(2)
11.5 Types of Unit Cells and Number of Atoms per Unit Cell
604(2)
11.6 Packing of Crystals
606(3)
11.7 Interstitial Sites or Interstitial Voids
609(1)
11.8 Coordination Number and Radius Ratio
609(3)
11.9 Packing Efficiency and Atomic Radius
612(4)
11.10 Calculation of Density of a Crystal from Its Edge Length
616(4)
11.11 Braggs Law: X-Ray Study of Crystals
620(2)
11.12 Structures of Simple Ionic Compounds
622(6)
11.13 Imperfection in Solids
628(3)
11.14 Semiconductors
631(12)
11.15 Superconductors
643(5)
11.16 Magnetic Materials
648(1)
11.17 Fullerenes
649(2)
11.18 Graphite
651(1)
Summary
652(1)
Review Questions
653(1)
Multiple Choice Questions
654(4)
12 Liquid Crystals 658(10)
12.1 Introduction
658(1)
12.2 Characteristics of Liquid Crystals
659(1)
12.3 Classification of Liquid Crystals
660(5)
Summary
665(1)
Review Questions
665(1)
Multiple Choice Questions
666(2)
13 Chemical Kinetics 668(89)
13.1 Introduction
668(1)
13.2 Rate of Reaction
669(3)
13.3 Average Rate and Instantaneous Rate
672(3)
13.4 Rate Law Expression
675(1)
13.5 Velocity Constant or Rate Constant
676(1)
13.6 Factors Influencing Reaction Rate
677(1)
13.7 Reaction Mechanism
678(3)
13.8 Order and Molecularity of Reaction
681(5)
13.9 Kinetic Equation of Different Orders/Integrated Rate Reactions
686(20)
13.10 Half-life of a Reaction
706(5)
13.11 Methods of Determining the Order of a Reaction
711(9)
13.12 Concept of Activation Energy
720(2)
13.13 Variation of Reaction Rates with Temperature - Arrhenius Equation
722(5)
13.14 Theories of Reaction Rates
727(5)
13.15 Potential Energy of Surfaces
732(6)
13.16 Catalysis
738(7)
Summary
745(3)
Review Questions
748(2)
Additional Problems
750(3)
Multiple Choice Questions
753(4)
14 Surface Chemistry 757(36)
14.1 Introduction
757(1)
14.2 Adsorption
757(2)
14.3 Factors Affecting Adsorption
759(2)
14.4 Types of Adsorption
761(1)
14.5 Type of Adsorption Isotherms
762(5)
14.6 Applications of Adsorption
767(1)
14.7 Colloidal State
768(2)
14.8 Classification of Colloids
770(3)
14.9 Preparation of Colloids
773(4)
14.10 Purification of Colloidal Solutions
777(1)
14.11 Properties of Colloidal Solutions
778(5)
14.12 Stability of Colloids
783(1)
14.13 Protective Colloids
783(1)
14.14 Emulsion
784(2)
14.15 Micelles
786(1)
14.16 Applications of Colloids
787(1)
Summary
788(1)
Review Questions
788(1)
Multiple Choice Questions
789(4)
15 Thermodynamics 793(97)
15.1 Introduction
793(1)
15.2 Terminology of Thermodynamics
793(5)
15.3 Zeroth Law of Thermodynamics
798(1)
15.4 First Law of Thermodynamics
798(13)
15.5 Heat Capacity
811(2)
15.6 The First Law of Thermodynamics and Ideal Gases
813(3)
15.7 Isothermal Processes in Ideal Gases
816(2)
15.8 Adiabatic Processes in Ideal Gases
818(9)
15.9 Applications of First Law of Thermodynamics
827(3)
15.10 Laws of Thermochemistry
830(4)
15.11 Kirchhoff's Equation
834(4)
15.12 Joule-Thomson Effect
838(2)
15.13 Limitations of the First Law: Need for the Second Law
840(1)
15.14 Statements of the Second Law of Thermodynamics
841(6)
15.15 Entropy
847(1)
15.16 Second Law of Thermodynamics in Terms of Entropy
848(2)
15.17 Evaluation of Entropy
850(6)
15.18 Entropy Changes in a Reversible Process
856(1)
15.19 Entropy Change in a Irreversible Process
857(1)
15.20 Entropy of Mixing
858(3)
15.21 Free Energy Function (G) and Work Function(A)
861(5)
15.22 Gibbs-Helmholtz Equation
866(2)
15.23 Claypeyron-Clausius Equation
868(3)
15.24 Vant Hoff Isotherm
871(2)
15.25 Maxwell's Thermodynamic Relations
873(2)
15.26 Spontaneity and Equilibrium
875(3)
Summary
878(5)
Review Questions
883(2)
Multiple Choice Questions
885(5)
16 Electrochemistry 890(78)
16.1 Introduction
890(1)
16.2 Types of Conductors
890(1)
16.3 Conductance in Electrolytic Solutions
891(7)
16.4 Factors Affecting Conductance
898(2)
16.5 Kohlrausch's Law of Independent Migration of Ions
900(4)
16.6 Conductometric Titration
904(4)
16.7 Electrochemical Cell
908(2)
16.8 Electrode Potential and EMF of a Galvanic Cell
910(2)
16.9 Measurement of Electrode Potential
912(1)
16.10 Electrochemical Series
913(5)
16.11 Nernst Equation
918(7)
16.12 Thermodynamic Functions and Electrochemical Cells
925(3)
16.13 Types of Electrodes
928(6)
16.14 Determination of Fluoride by Ion Selective Electrode Method
934(2)
16.15 Determination of pH
936(6)
16.16 Concentration Cells
942(3)
16.17 Batteries
945(7)
16.18 Fuel Cells
952(5)
Summary
957(6)
Review Questions
963(2)
Multiple Choice Questions
965(3)
17 Spectroscopy 968(79)
17.1 Introduction
968(1)
17.2 Basic Terms and Principles of Spectroscopy
968(9)
17.3 Electronic (UV-Visible) Spectroscopy
977(12)
17.4 IR Spectroscopy
989(18)
17.5 Rotational Spectroscopy of Diatomic Molecules
1007(7)
17.6 Vibrational-Rotational Spectra for a Diatomic Molecule
1014(1)
17.7 Nuclear Magnetic Resonance Spectroscopy
1015(17)
17.8 Raman Spectroscopy
1032(5)
Summary
1037(3)
Review Questions
1040(2)
Multiple Choice Questions
1042(5)
18 Photochemistry 1047(30)
18.1 Introduction
1047(1)
18.2 Significance of Photochemistry
1048(1)
18.3 Laws Governing Light Absorption
1049(1)
18.4 Laws of Photochemistry
1049(2)
18.5 Quantum Yield or Quantum Efficiency
1051(5)
18.6 Electronic Excitation
1056(1)
18.7 Jablonski Diagram
1056(2)
18.8 Photophysical Processes
1058(2)
18.9 Photosensitisation
1060(1)
18.10 Semiconductor Photochemistry
1061(3)
18.11 Supramolecular Chemistry
1064(3)
18.12 Supramolecular Photochemistry
1067(3)
18.13 Introduction to Optical Sensors
1070(3)
Summary
1073(1)
Review Questions
1074(1)
Multiple Choice Questions
1075(2)
19 Fundamentals of Organic Chemistry 1077(86)
19.1 Introduction
1077(1)
19.2 Cleavage of Covalent Bonds
1077(1)
19.3 Attacking Reagents
1078(2)
19.4 Electron Displacements in Covalent Bonds
1080(13)
19.5 Reaction Intermediates
1093(10)
19.6 Types of Organic Reactions
1103(6)
19.7 Mechanism of Nucleophilic Substitution Reactions
1109(6)
19.8 Mechanism of Electrophilic Substitution Reactions
1115(6)
19.9 Mechanism of Elimination Reactions
1121(3)
19.10 Important Name Reactions
1124(9)
19.11 Stereochemistry
1133(17)
19.12 Drugs
1150(2)
Summary
1152(4)
Review Questions
1156(2)
Multiple Choice Questions
1158(5)
20 Coordination Chemistry 1163(35)
20.1 Introduction
1163(1)
20.2 Terms Used in Coordination Chemistry
1164(1)
20.3 Nomenclature of Coordination Compounds
1165(3)
20.4 Isomerism in Coordination Compounds
1168(5)
20.5 Bonding in Coordination Compounds: Werner's Coordination Theory
1173(2)
20.6 Sidgwick Coordination Theory
1175(1)
20.7 Valence Bond Theory
1176(4)
20.8 Crystal Field Theory
1180(8)
20.9 Molecular Orbital Theory
1188(5)
Summary
1193(1)
Review Questions
1194(2)
Multiple Choice Questions
1196(2)
21 Organometallic Compounds 1198(19)
21.1 Introduction
1198(2)
21.2 General Methods of Preparation
1200(2)
21.3 Applications of Organometallics
1202(3)
21.4 Grignard Reagents
1205(9)
Summary
1214(1)
Important Dates in Organometallic Chemistry
1214(1)
Review Questions
1214(1)
Multiple Choice Questions
1215(2)
22 Green Chemistry 1217(17)
22.1 Introduction
1217(1)
22.2 Emergence of Green Chemistry
1218(1)
22.3 Twelve Principles of Green Chemistry
1218(3)
22.4 Use of Alternative Feedstock (Biofuels)
1221(2)
22.5 Use of Innocuous Reagents
1223(1)
22.6 Use of Alternative Solvents
1223(2)
22.7 Design of Safer Chemicals
1225(1)
22.8 Designing Alternative Reaction Methodology
1226(2)
22.9 Minimising Energy Consumption
1228(3)
Summary
1231(1)
Review Questions
1231(1)
Multiple Choice Questions
1232(2)
23 Nanochemistry 1234(25)
23.1 Introduction
1234(2)
23.2 Properties of Nanomaterials
1236(1)
23.3 Self-assembly
1236(6)
23.4 Preparation of Nanomaterials
1242(2)
23.5 Nanomaterials
1244(7)
23.6 Surface Characterisation Techniques
1251(1)
23.7 Applications of Nanomaterials
1252(3)
Summary
1255(1)
Review Questions
1256(1)
Multiple Choice Questions
1257(2)
24 Chemical Aspects of Biotechnology 1259(17)
24.1 Introduction
1259(1)
24.2 Applications of Biotechnology
1259(5)
24.3 Biocatalysts or Enzymes
1264(1)
24.4 Fermentation
1265(1)
24.5 General Outline of the Fermentation Process
1266(7)
Summary
1273(1)
Review Questions
1273(1)
Multiple Choice Questions
1274(2)
25 Analytical Techniques in Chemistry 1276(11)
25.1 Introduction
1276(1)
25.2 Type of Analysis
1276(3)
25.3 Separation Techniques
1279(1)
25.4 Potentiometry
1280(3)
25.5 pH metry
1283(2)
Summary
1285(1)
Review Questions
1285(1)
Multiple Choice Questions
1286(1)
26 Chemistry of Carbon and Hydrogen 1287(16)
26.1 Hydrogen
1287(1)
26.2 Preparation of Hydrogen
1287(1)
26.3 Industrial Method of Preparation of Hydrogen
1288(1)
26.4 Properties of Hydrogen
1289(1)
26.5 Isotopes of Hydrogen
1290(1)
26.6 Storage of Hydrogen
1291(1)
26.7 Compounds of Hydrogen
1292(5)
26.8 Applications of Hydrogen
1297(1)
26.9 Carbon
1297(1)
26.10 Isotopes
1297(1)
26.11 Allotropes of Carbon
1298(1)
26.12 Chemical Properties of Carbon
1299(1)
26.13 Uses
1300(1)
Summary
1300(1)
Review Questions
1301(1)
Multiple Choice Questions
1301(2)
Index 1303
Shikha Agarwal is an assistant professor in the department of chemistry at the Government Engineering College, Ajmer. She has taught courses on engineering chemistry, environmental science, spectroscopy, photochemistry and reaction mechanisms at the undergraduate and postgraduate level for several years. Her areas of interest include organic chemistry, inorganic chemistry and environmental science.
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Pastovi nuoroda: https://www.kriso.lt/db/97811085792092e.html
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