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Fuel Cells: Technologies for Fuel Processing [Kietas viršelis]

Edited by (National Energy Technology Laboratory, US Department of Energy, Morgan Town, WV, USA), Edited by (National Energy Technology Laboratory, US Department of En), Edited by (Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA, USA)
  • Formatas: Hardback, 568 pages, aukštis x plotis: 235x191 mm, weight: 1280 g
  • Išleidimo metai: 08-Apr-2011
  • Leidėjas: Elsevier Science Ltd
  • ISBN-10: 0444535632
  • ISBN-13: 9780444535634
Kitos knygos pagal šią temą:
  • Formatas: Hardback, 568 pages, aukštis x plotis: 235x191 mm, weight: 1280 g
  • Išleidimo metai: 08-Apr-2011
  • Leidėjas: Elsevier Science Ltd
  • ISBN-10: 0444535632
  • ISBN-13: 9780444535634
Kitos knygos pagal šią temą:
This book covers all aspects of fuel processing: fundamental chemistry, different modes of reforming, catalysts, catalyst deactivation, fuel desulfurization, reaction engineering, novel reforming concepts, thermodynamics, heat and mass transfer issues, system design, recent research and development, etc., which makes it one single source of information for scientists and engineers. It serves as an excellent self-instruction book for those new to fuel cells, and as a comprehensive resource for experts in the area of fuel processing. It can be used as a reference book for advanced level university courses in this area.
  • Chapters written by experts in each area
  • Extensive bibliography supporting each chapter
  • Detailed index
  • Up-to-date diagrams and full colour illustrations


This book covers all aspects of fuel processing: fundamental chemistry, different modes of reforming, catalysts, catalyst deactivation, fuel desulfurization, reaction engineering, novel reforming concepts, thermodynamics, heat and mass transfer issues, system design, recent research and development, etc., which makes it one single source of information for scientists and engineers. It serves as an excellent self-instruction book for those new to fuel cells, and as a comprehensive resource for experts in the area of fuel processing. It can be used as a reference book for advanced level university courses in this area.
  • Chapters written by experts in each area
  • Extensive bibliography supporting each chapter
  • Detailed index
  • Up-to-date diagrams and full colour illustrations

Daugiau informacijos

An essential guide to this cutting-edge technology and its industry applications
Preface vii
Editors Biography ix
Contributors xi
1 Introduction to Fuel Processing 1(10)
1.1 Clean Energy
1(1)
1.2 Fuel Cells
2(1)
1.3 Fuel Processors
2(1)
1.4 Reforming Modes
3(1)
1.5 Thermal Integration of the Fuel Processor and Fuel Cell
4(1)
1.6 Challenges for Fuel Cells and Fuel Processors
4(2)
1.7 Scope of This Book
6(1)
References
7(4)
2 Fuel Cells 11(18)
2.1 Introduction
11(3)
2.2 Fuel Cell Fundamentals
14(3)
2.3 Fuel Cell Degradation
17(1)
2.4 Fuel Cell Operation
18(2)
2.5 Fuel Cell Types
20(6)
References
26(3)
3 Fuels for Fuel Cells 29(20)
3.1 Introduction
29(1)
3.2 Fossil Fuels
30(13)
3.3 Oxygenated Fuels
43(4)
References
47(2)
4 Steam Reforming for Fuel Cells 49(24)
4.1 Routes to Hydrogen
50(1)
4.2 Steam Reforming of Natural Gas
50(9)
4.3 Steam Reforming of Other Feedstocks
59(3)
4.4 Hydrogen Production
62(6)
4.5 Conclusions
68(1)
References
68(5)
5 Catalytic Partial Oxidation 73(56)
5.1 Introduction
74(1)
5.2 Thermodynamics
75(5)
5.3 Reaction Mechanisms and Kinetics
80(12)
5.4 Light Hydrocarbons
92(14)
5.5 Higher Hydrocarbons
106(10)
5.6 Oxygenated Hydrocarbons
116(4)
5.7 Future Development and Applications
120(3)
References
123(6)
6 Oxidative Steam Reforming 129(62)
6.1 Introduction
130(1)
6.2 Thermodynamics
131(7)
6.3 Mechanism
138(6)
6.4 Kinetics
144(3)
6.5 Catalytic OSR of Hydrocarbons
147(32)
6.6 Future Work
179(2)
References
181(10)
7 Dry (CO2) Reforming 191(32)
7.1 Introduction
192(1)
7.2 Thermodynamics
192(2)
7.3 Catalysts for Dry Reforming of Methane
194(10)
7.4 Reaction Mechanism and Kinetics of Dry Reforming of Methane
204(3)
7.5 Dry Reforming of Ethane
207(1)
7.6 Dry Reforming of Propane
208(2)
7.7 Reforming of Higher Hydrocarbons
210(1)
7.8 Dry Reforming of Oxygenated Hydrocarbons
210(3)
7.9 Summary
213(1)
References
214(9)
8 Plasma Reforming for H2-Rich Synthesis Gas 223(38)
8.1 Introduction
224(1)
8.2 Types of Plasmas Used in Fuel Processing Applications
225(6)
8.3 Plasma as an Alternative to Traditional Catalysts in Fuel Reforming
231(8)
8.4 Plasma Reforming of Methane
239(3)
8.5 Plasma Reforming of Liquid Hydrocarbons
242(9)
8.6 Combined Plasma-Catalytic Reforming of Hydrocarbon Fuels into Hydrogen-Rich Synthesis Gas
251(3)
8.7 Conclusions and Future Trends
254(1)
References
255(6)
9 Nonconventional Reforming Methods 261(24)
9.1 Scope of the
Chapter
261(1)
9.2 Decomposition of Hydrocarbons
262(4)
9.3 Supercritical Reforming
266(6)
9.4 Non-catalytic Thermal Reforming in Porous Media
272(4)
9.5 Radio Frequency (RF)-Assisted Reforming
276(1)
9.6 Pre-reforming
277(3)
References
280(5)
10 Deactivation of Reforming Catalysts 285(32)
10.1 Scope of This
Chapter
286(1)
10.2 Introduction, General Mechanisms for Fuel Reforming
286(1)
10.3 Thermally Induced Deactivation
287(3)
10.4 Sulfur Poisoning
290(9)
10.5 Coke/Carbon Deposition
299(7)
10.6 Kinetics of the Deactivation Processes
306(3)
10.7 Conclusions
309(1)
References
310(7)
11 Desulfurization for Fuel Cells 317(44)
11.1 Introduction 318 11.2. Scope
319(1)
11.3 Gas Phase Desulfurization Upstream of Reformer
320(12)
11.4 Liquid Phase Desulfurization Upstream of Reformer
332(10)
11.5 Syngas Desulfurization Downstream of Reformer or Gasifier
342(8)
11.6 Integration of Sulfur Removal
350(1)
11.7 Conclusions and Future Directions
351(2)
References
353(8)
12 Syngas Conditioning 361(48)
12.1 Introduction 36212.1. Water Gas Shift
363(10)
12.2 Preferential Oxidation (PrOX)
373(17)
12.3 Selective Catalytic Methanation of CO (SMET)
390(9)
References
399(10)
13 Direct Reforming Fuel Cells 409(42)
13.1 Introduction
410(2)
13.2 Thermodynamics
412(1)
13.3 Benefits of Internal Reforming
412(3)
13.4 Carbon Formation
415(4)
13.5 Experimental Studies on Low O/C Operation
419(7)
13.6 Kinetics of Steam Reforming on Nickel-YSZ Anodes
426(5)
13.7 Poisons for SOFC Anodes
431(11)
13.8 Concluding Remarks
442(1)
References
443(8)
14 Reactor Design for Fuel Processing 451(66)
14.1 Design Requirements of the Fuel Processing Unit
452(13)
14.2 Design Requirements of WGS Unit
465(1)
14.3 Design Requirements of Carbon Monoxide Removal Unit
466(3)
14.4 Design Requirements of Desulfurization Unit
469(1)
14.5 Types of Reactors Used in Fuel Processing
470(20)
14.6 Modeling and Design of Fuel Processing Reactors
490(17)
Acknowledgments
507(1)
References
507(10)
15 Balance of Plant 517(10)
15.1 Introduction
517(1)
15.2 Fuel, Air, and Water Management
517(4)
15.3 Fuel Injection System
521(1)
15.4 Heat Management Systems
522(1)
15.5 Other Components
523(2)
15.6 Conclusion and Future Directions
525(1)
References
526(1)
Appendix A 527(2)
Appendix B 529(8)
Appendix C 537(2)
Index 539