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Functionalized Graphene Nanocomposites and Their Derivatives: Synthesis, Processing and Applications [Minkštas viršelis]

Edited by (Mohammed VI Polytechnic University, Benguerir, Morocco), Edited by (Director of Polymer Processing Laborat), Edited by (Department of Chemical and Petroleum Engineering, College of Engineering, United Arab Emirates University, Al Ain, United Arab Emirates)
  • Formatas: Paperback / softback, 368 pages, aukštis x plotis: 235x191 mm, weight: 700 g
  • Serija: Micro & Nano Technologies
  • Išleidimo metai: 08-Nov-2018
  • Leidėjas: Elsevier Science Publishing Co Inc
  • ISBN-10: 012814548X
  • ISBN-13: 9780128145487
Kitos knygos pagal šią temą:
Functionalized Graphene Nanocomposites and Their Derivatives: Synthesis, Processing and ApplicationsDidesnis paveikslėlis
  • Formatas: Paperback / softback, 368 pages, aukštis x plotis: 235x191 mm, weight: 700 g
  • Serija: Micro & Nano Technologies
  • Išleidimo metai: 08-Nov-2018
  • Leidėjas: Elsevier Science Publishing Co Inc
  • ISBN-10: 012814548X
  • ISBN-13: 9780128145487
Kitos knygos pagal šią temą:
Pastovi nuoroda: https://www.kriso.lt/db/9780128145487.html
Raktažodžiai:

Functionalized Graphene Nanocomposites and Their Derivatives: Synthesis, Processing and Applications explains how the functionalization technique is used to create graphene nanocomposites, also exploring its current uses in industrial applications. Graphene-based nanocomposites are one of the major advancements in polymer-based materials, thus the synthesis, nanoscale dimensions, high aspect ratio, mechanical, electrical and thermal properties of graphene and its derivative have all been major areas of research in the last decade. This important reference covers these updates and is a critical book for those working in the fields of materials processing and characterization.

  • Explains how graphene is functionalized and used in the fabrication of nanocomposites for a range of applications
  • Explores why the properties of functionalized graphene make it such a useful, versatile material
  • Describes, in detail, the functionalization process for utilization in graphene
List of Contributors
xv
About the Editors xix
Preface xxi
Chapter 1 Chemical Preparation and Functionalization Techniques of Graphene and Graphene Oxide
1(9)
Marya Raji
Nadia Zari
Abou el kacem Qaiss
Rachid Bouhfid
1 Introduction
1(2)
2 Synthesis of Graphene and Graphene Oxide
3(7)
2.1 Bottom-Up Graphene
3(3)
2.2 Top-Down Graphene
6(4)
3 Functionalization Techniques of Graphene and Graphene Oxide
10(5)
3.1 Covalent Modification
10(3)
3.2 Noncovalent Modification
13(2)
4 Conclusion
15(6)
References
15(6)
Chapter 2 Surface Functionalization of Graphene-Based Nanocomposites by Chemical Reaction
21(8)
Oubenali Mustapha
Mohamed El Mehdi Mekhzoum
Rachid Bouhfid
Abou el kacem Qaiss
1 Introduction
21(2)
2 Methods for Production Functionalized Graphene by Electrophilic Reactions/Polymer Nanocomposite
23(6)
2.1 Functionalized Graphene by Electrophilic Reactions
23(2)
2.2 Nanocomposites Based on Functionalized Graphene by Electrophilic Reactions and Polymeric Matrices
25(4)
3 Applications of Functionalized Graphene-Based Polymer Matrices
29(10)
3.1 Acrylonitrile Butadiene Styrene
30(1)
3.2 Polyamides
31(3)
3.3 Poly(vinylidene fluoride)
34(1)
3.4 Polypropylene/Polyethylene
35(4)
4 Conclusion
39(8)
References
39(8)
Chapter 3 Functionalized Graphene and Thermoset Matrices-Based Nanocomposites: Mechanical and Thermal Properties
47(7)
Nabil Bouhfid
Marya Raji
Mohammed-ouadi Bensalah
Abou el kacem Qaiss
1 Introduction
47(1)
2 Synthesis Methods of Graphene
48(2)
3 Graphene Properties
50(4)
3.1 Problematic
53(1)
4 Fuctionalized Graphene Nanocomposites Preparation
54(11)
4.1 Surface Modification of Graphene
54(1)
4.2 Thermoset Graphene Nanocomposites Preparation
55(1)
5 Nanocomposite Properties
56(5)
5.1 Thermal Properties
56(1)
5.2 Mechanical Properties
57(3)
5.3 Torsional Properties
60(1)
6 Conclusion
61(4)
References
62(3)
Chapter 4 Functionalized Graphene Nanocomposites in Air Filtration Applications
65(5)
Aneeya K. Samantara
Satyajit Hatha
Sudarsan Raj
1 Overview and Background
65(2)
2 Synthesis of Graphene
67(2)
3 Properties
69(1)
3.1 Chemical Properties
69(1)
3.2 Physical Properties
70(1)
4 Functionalization and Composite Preparation
70(21)
4.1 Porous Graphene
70(2)
4.2 Doped Graphene
72(1)
4.3 Polymerization
73(1)
4.4 Composites
74(2)
5 Air Filtration by Functionalized Graphene
76(6)
6 Summary and Perspective
82(9)
References
83(8)
Chapter 5 Functionalized Graphene Nanocomposites for Water Treatment
91(18)
Showkat Ahmad Bhawani
Abu Tariq
Abdul Moheman
Zainab Ngaini
1 Introduction
91(1)
2 Chemical Functionalization of Graphene
92(8)
2.1 Covalent Functionalization
92(6)
2.2 Noncovalent Functionalization of Graphene
98(2)
3 Applications of Functionalized Graphene-Based Composites
100(9)
3.1 Decontamination of Water Through Physical/Chemical Adsorption
100(1)
3.2 Detection of Heavy Metal Ions Using Graphene-Based Sensors
100(1)
3.3 Photocatalystic Degradation of Environmental Pollutants
101(1)
References
102(7)
Chapter 6 Rheological Properties of Functionalized Graphene and Polymeric Matrices-Based Nanocomposites
109(12)
Hamid Essabir
Marya Raji
Rachid Bouhfid
Abou el kacem Qaiss
1 Introduction
109(1)
2 Nanocomposites-Based Graphene and Polymeric Matrix
110(1)
3 Processing Techniques of Graphene-Based Nanocomposites
111(1)
4 Functionalization of Graphene
112(1)
4.1 Noncovalent Functionalization
112(1)
4.2 Covalent Functionalization of Graphene
112(1)
5 Nanocomposites Characterization
113(4)
5.1 Functionalized Graphene Oxide (Silane) Preparation
113(1)
5.2 Nanocomposites Manufacturing
114(1)
5.3 Mechanical Properties
114(2)
5.4 Rheological Properties on Torsional Mode
116(1)
6 Conclusion
117(4)
References
118(2)
Further Reading
120(1)
Chapter 7 Functionalized Graphene-Reinforced Foams Based on Polymer Matrices: Processing and Applications
121(36)
Xiao Yuan Chen
Amaya Romero
Antonio Paton-Carrero
Maria Prado Lavin-Lopez
Luz Sanchez-Silva
Jose Luis Valverde
Serge Kaliaguine
Denis Rodrigue
1 Introduction
121(2)
2 Production of Graphene
123(3)
3 Applications of Graphene-Based Polymer Foams
126(20)
3.1 Polyurethane Foams
127(5)
3.2 Silicone Foams
132(1)
3.3 Polystyrene Foams
133(5)
3.4 Poly(methyl methacrylate) Foams
138(2)
3.5 Poly(vinylidene fluoride) Foams
140(1)
3.6 Polyimide Foams
141(3)
3.7 Other Foams
144(2)
4 Discussion and Conclusions
146(11)
References
149(8)
Chapter 8 Functionalized Graphene Aerogel: Structural and Morphological Properties and Applications
157(20)
Anish Khan
Aftab Aslam Parwaz Khan
Mohammed Omaish Ansari
Imran Khan
Mohammad Mujahid A.H. Khan
Abdullah M. Asiri
Aleksandr Evhenovych Kolosov
P. Senthamaraikannan
1 Introductions
157(1)
2 Morphological Study
158(3)
3 Application
161(7)
4 Properties
168(1)
5 Graphene Aerogels in Energy Storage Applications
168(4)
6 Graphene Aerogels in Gas Sensing Applications
172(5)
References
173(4)
Chapter 9 Comparison Between Functionalized Graphene and Carbon Nanotubes: Effect of Morphology and Surface Group on Mechanical, Electrical, and Thermal Properties of Nanocomposites
177(28)
M.R. Mansor
S.H.S.M. Fadzullah
N.A.B. Masripan
G. Omar
M.Z. Akop
1 Introduction to Graphene and Carbon Nanotube Nanocomposites
177(5)
2 Fundamental Aspects on Morphology and Surface Group of Graphene and Carbon Nanotube Nanocomposites
182(3)
3 Effect of Morphology and Surface Group to Mechanical Properties of Graphene and Carbon Nanotube Nanocomposites
185(3)
3.1 Introduction
185(1)
3.2 Tensile Strength and Young's Modulus of Different Carbon Nanomaterials With Polymer Composites
186(2)
3.3 Fracture Toughness of Nanocomposite Materials
188(1)
4 Effect of Filler Concentration, Fabrication, and Modification on Electrical Properties of Graphene and Carbon Nanotube Nanocomposites
188(4)
4.1 The electrical conductivity mechanism
189(1)
4.2 Effect of Concentration
189(1)
4.3 Effect of Fabrication
190(1)
4.4 Effect of Filler Modification
191(1)
5 Effect of Morphology and Surface Group to Thermal Properties of Graphene and Carbon Nanotube Nanocomposites
192(4)
5.1 Thermal Conductivity and Coefficient of Thermal Expansion on Graphene-Based Polymer Nanocomposites
193(1)
5.2 Effect of Thermal Conductivity With Filler Contents of Graphene and Multiwalled Carbon Nanotubes
194(1)
5.3 Effect of Graphene Platelets and Carbon Nanotubes on the Thermal Properties of Epoxy Composites
195(1)
6 Conclusion and Future Works
196(9)
Acknowledgments
197(1)
References
197(8)
Chapter 10 Functionalized Graphene Reinforced Hybrid Nanocomposites and Their Applications
205(14)
N. Saba
Mohammad Jawaid
1 Introduction
205(1)
2 Graphene and Its Synthesis
206(2)
3 Graphene Properties and Applications
208(2)
4 Functionalized Graphene
210(1)
5 Hybrid Nanocomposites
211(1)
6 Functionalized Graphene---Reinforced Hybrid Polymer Nanocomposites
212(1)
7 Applications of Functionalized Graphene Hybrid Nanocomposites
212(2)
8 Conclusion
214(5)
Acknowledgments
215(1)
References
215(4)
Chapter 11 Functionalized Graphene-Based Nanocomposites for Energy Applications
219(26)
Deepak Verma
Kheng Lim Goh
1 Graphene: A Brief History or Introduction
219(1)
2 Graphene: A Brief History
220(1)
2.1 Properties and Characteristics
220(1)
3 Graphene Preparation Methods
220(2)
3.1 Mechanical Exfoliation
220(1)
3.2 Chemical Vapor Deposition
220(1)
3.3 Liquid-Phase Exfoliation
221(1)
3.4 Electrochemical Exfoliation
221(1)
3.5 Reduction of Graphene Oxide
221(1)
4 Development of Graphene Reinforced Polymer Composites
222(1)
4.1 Solution Mixing
222(1)
4.2 Melt Blending
223(1)
4.3 In Situ Polymerization
223(1)
4.4 High Shear Mixing---Calendering
223(1)
5 Properties of Graphene-Based Reinforced Polymer Composites
223(7)
5.1 Mechanical Properties
223(3)
5.2 Electrical Properties
226(4)
6 Graphene-Based Nanocomposites for Energy Applications
230(2)
6.1 Energy Storage
230(2)
7 Characterization of Graphene-Reinforced Composites: Morphological Studies
232(5)
8 Conclusion
237(8)
References
237(8)
Chapter 12 Electronic Applications of Functionalized Graphene Nanocomposites
245(20)
G. Omar
M.A. Salim
B.R. Mizah
A.A. Kamarolzaman
R. Nadlene
1 Introduction
245(1)
2 Graphene in Electronic Applications
245(2)
3 Graphene Nanocomposites for Microsensing Devices
247(1)
4 Graphene Nanocomposite---Filled Polymer for Stretchable Conductive Ink
248(1)
5 Graphene-Filled Polymers in Solar Cell Applications
249(3)
5.1 Principles of Graphene Solar Cells
250(2)
6 Graphene Nanocomposites for Lithium Ion Batteries
252(2)
7 Graphene Nanocomposites for Supercapacitors
254(2)
8 Graphene Nanocomposites for Electromagnetic Induction
256(2)
9 Graphene Nanocomposites for Electronic Discharge
258(1)
10 Conclusion
259(6)
References
260(5)
Chapter 13 A Corelation Between the Graphene Surface Area, Functional Groups, Defects, and Porosity on the Performance of the Nanocomposites
265(20)
Kalyani Prusty
Sunita Barik
Sarat K. Swain
1 Introduction
265(3)
2 Effect of Specific Surface Area on Graphene-Based Nanocomposites
268(1)
2.1 Brunauer---Emmett---Teller Isotherm on Graphene
268(1)
2.2 Electronic Microscopic Studies of Graphene
268(1)
3 Effect of Defects on Graphene-Based Nanocomposites
269(4)
3.1 Raman Spectra of Defects on Graphene
269(1)
3.2 Thermal Conductivity of Defects on Graphene-Based Nanocomposites
270(2)
3.3 Mechanical Properties of Defects on Graphene-Based Nanocomposites
272(1)
4 Effect of Functional Groups on Graphene-Based Nanocomposites
273(1)
4.1 Fourier Transform Infrared Spectroscopy of Functional Groups on Graphene-Based Nanocomposite
273(1)
4.2 X-Ray Photoelectron Spectroscopy of Functional Groups in Graphene
274(1)
5 Effect of Porosity on Graphene-Based Nanocomposites
274(4)
5.1 Thermal Properties of Graphene-Based Nanocomposites
277(1)
6 Conclusion
278(7)
Acknowledgments
278(1)
References
278(7)
Chapter 14 Metal Oxide-Graphene and Metal-Graphene Nanocomposites for Energy and Environment
285(10)
Mohammad Mansoob Khan
1 Introduction and Historical Developments
285(3)
1.1 Graphene
285(1)
1.2 Graphene-Based Nanocomposites
286(2)
2 Metal Oxide---Graphene---Based Nanocomposites for Energy and Environment
288(2)
3 Metal-Graphene---Based Nanocomposites for Energy and Environment
290(2)
4 Future Prospects
292(1)
5 Conclusions
292(3)
References
293(2)
Chapter 15 Functionalized Graphene Nanocomposite in Gas Sensing
295(28)
Bhargav Raval
Indrani Banerjee
1 Introduction
295(2)
2 Pristine Graphene: Preparation and Properties
297(5)
2.1 Hybridization Mechanism for Structure Formation
297(3)
2.2 Synthesis Routes for Pristine Graphene
300(1)
2.3 Properties Study of Pristine Graphene
301(1)
3 Functionalization of Graphene
302(3)
3.1 Covalent Functionalization of Graphene
303(1)
3.2 Noncovalent Functionalization of Graphene
304(1)
4 Trends and Future Applications
305(1)
5 Graphene-Based Gas Sensors
306(10)
5.1 Genesis of the Concept
306(1)
5.2 Theoretical Aspects
307(1)
5.3 Experimental Aspects
308(8)
6 Outcomes and Conclusive Aspect
316(7)
References
317(6)
Chapter 16 Hybridized Graphene for Chemical Sensing
323(16)
Ritu Malik
Vijay K. Tomer
Vandna Chaudhary
1 Introduction
323(3)
1.1 History of Graphene
324(1)
1.2 Definition of Graphene
324(1)
1.3 Classification of Graphene Family
325(1)
2 Properties of Graphene
326(2)
2.1 Electronic Properties of Graphene
326(1)
2.2 Mechanical Properties
327(1)
2.3 Quantum Hall Effect
328(1)
3 Synthesis of Graphene
328(3)
3.1 Mechanical Exfoliation of Graphite
329(1)
3.2 Liquid-Phase Exfoliation of Graphite
330(1)
3.3 Epitaxial Growth
330(1)
3.4 Chemical Synthesis
330(1)
4 Graphene for Chemical Sensing
331(4)
4.1 Graphene Nanocomposite---Based Sensors
331(2)
4.2 Functionalized Graphene-Based Sensors
333(2)
5 Conclusions and Future Prospects
335(4)
References
335(4)
Index 339
Dr. Mohammad Jawaid is currently affiliated with the Department of Chemical and Petroleum Engineering at United Arab Emirates University. Previously he was a senior fellow (professor) in the Laboratory of Biocomposites Technology at the Institute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia. He is an eminent scientist with more than twenty years of teaching, and research experience in composite materials. His research interests include hybrid reinforced/filled polymer composites, and advanced materials such as graphene/

nanoclay/fire retardant, lignocellulosic reinforced/filled polymer composites, and the modification and treatment of lignocellulosic fibres and solid wood, and nanocomposites and nanocellulose fibres.

Prof. Rachid Bouhfid is currently working as an Associate Professor at Mohammed VI Polytechnic University (UM6P), Benguerir, Morocco. Before joining UM6P, he served as the Director of Research at the Moroccan Foundation for Advanced Science, Innovation, and Research (MAScIR) in Rabat, Morocco, and as an Assistant Professor at Artois University, France. Prof. Bouhfid earned his doctoral degree from Mohammed V University in Rabat, Morocco. He has over fifteen years of experience in teaching and research in organic chemistry, materials science, nanotechnology, and polymer chemistry. His main research interests include hybrid nanomaterials, reinforced polymer nanocomposites, and advanced materials such as graphene, nanoclay, cellulose nanocrystals, and nanocomposites. Throughout his career, he has developed various nanostructured materials for wastewater treatment, packaging, sensing, and biomedical applications. He has authored more than 200 research papers in SCI-indexed journals, edited six books, and co-authored over 54 book chapters. Prof. Abou el kacem Qaiss is currently working as Director of the Composites Nanocomposites Centre at the Moroccan Foundation for Advanced Science, Innovation and Research (MAScIR), Institute of Nanomaterials and Nanotechnology (Nanotech) in Rabat (Morocco). His research areas include: hybrid reinforced/filled polymer composites, advance materials: graphene/nanoclay, lignocellulosic reinforced/filled polymer composites, modification and treatment of lignocellulosic fibres, nanocomposites and nanocellulose fibres, as well as polymer blends. So far, he has published three books, 30 chapters and more than 75 international journal papers with 25 patents to his credit.