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How to Succeed in Organic Chemistry [Minkštas viršelis]

(Senior Lecturer in Organic Chemistry and Deputy Director of Learning and Teaching, School of Chemistry, Cardiff University)
  • Formatas: Paperback / softback, 520 pages, aukštis x plotis x storis: 243x172x21 mm, weight: 900 g
  • Išleidimo metai: 03-Mar-2020
  • Leidėjas: Oxford University Press
  • ISBN-10: 0198851294
  • ISBN-13: 9780198851295
Kitos knygos pagal šią temą:
How to Succeed in Organic ChemistryDidesnis paveikslėlis
  • Formatas: Paperback / softback, 520 pages, aukštis x plotis x storis: 243x172x21 mm, weight: 900 g
  • Išleidimo metai: 03-Mar-2020
  • Leidėjas: Oxford University Press
  • ISBN-10: 0198851294
  • ISBN-13: 9780198851295
Kitos knygos pagal šią temą:
Pastovi nuoroda: https://www.kriso.lt/db/9780198851295.html
Raktažodžiai:
'How to succeed in organic chemistry' gives the reader a solid understanding of the principles of organic reaction mechanisms, such that they can draw structures, stereoisomers and reaction mechanisms with confidence. Throughout, the author speaks the language of students to build their confidence and interest.

At heart, the book promotes active learning to ensure the necessary skills become so ingrained that they become something students simply cannot forget, and do not need to revise. As such, the book structures learning so that the reader encounters the right things at the right time, helping to 'internalise' key concepts.

Concepts, explanations and examples are presented in short, easy-to-read chapters, each of which explores one of a number of themes, including 'Basics', 'Habits', 'Common error', 'Reaction detail', and 'Practice'.

Digital formats and resources How to Succeed in Organic Chemistry is supported by online resources and is available for students and institutions to purchase in a variety of formats. - The e-book includes more than 60 author videos which are embedded in the text, and these discuss and offer solutions to problems posed in the text, providing a fully immersive experience and extra learning support. www.oxfordtextbooks.co.uk/ebooks - These videos are also available as a stand-alone online resource for use alongside the print book, where lecturers can also access the figures from the book for use in their teaching.

Recenzijos

I liked the slightly informal tone of writing, almost as if I was being taught one-to-one by the author. It felt personal and honest, as if the author wrote the book to help me personally. * Stephen Robertson, student, University of York * This book would be a chemistry student's friend. It is different to any I have read before. There is a comforting level of informality, where you felt like your friend was going through and explaining things to you. * Yasmine Biddick, student, University of Birmingham * This text represents a new way to teach organic chemistry and produce independent, critically thinking chemists; it acknowledges the connected world in which students live and utilises that to avoid the traditional endless lists of reactions for rote learning. Instead, this text focuses on the discipline and practice required by the novice and gives them the tools to become an expert. * Dr Jennifer Slaughter, Department of Chemistry, University of Manchester * This is a unique textbook that does something no other text does - it speaks the language of the modern student and is formatted with that in mind. * Professor Mark Bagley, Department of Chemistry, University of Sussex *

Foreword xi
Inspiration xv
Acknowledgements xvii
Additional Resources xix
Style and Substance xxi
SECTION 1 LAYING THE FOUNDATIONS
1(2)
Basics 1 Structures of Organic Compounds
3(10)
Habit 1 Always Draw Structures with Realistic Geometry
11(2)
Basics 2 Functional Groups and `R' Groups
13(6)
Basics 3 Naming Organic Compounds
19(10)
Practice 1 Drawing Structures from Chemical Names
26(3)
Basics 4 Isomerism in Organic Chemistry-Constitutional Isomers
29(15)
Practice 2 Constitutional Isomers and Chemical Names
31(2)
Habit 2 Identifying When a Formula is Possible
33(3)
Practice 3 Double Bond Equivalents
36(3)
Common Error 1 Formulae, Functional Groups, and Double Bond Equivalents
39(3)
Habit 3 Ignore What Doesn't Change
42(2)
Basics 5 Electronegativity, Bond Polarization, and Inductive Effects
44(4)
Practice 4 Bond Polarization and Electronegativity
46(2)
Basics 6 Bonding in Organic Compounds
48(14)
Practices Hybridization
59(3)
Basics 7 Bonding and Antibonding Orbitals
62(3)
Basics 8 Introduction to Curly Arrows
65(18)
Fundamental Reaction Type 1 Nucleophilic Substitution at Saturated Carbon
72(4)
Practice 6 Electronegativity in Context
76(2)
Fundamental Reaction Type 2 Elimination Reactions
78(5)
SECTION 2 BUILDING ON THE FOUNDATIONS
83(2)
Basics 9 Breaking Bonds-Linking Curly Arrows and Molecular Orbitals
85(10)
Common Error 2 Curly Arrows
93(2)
Basics 10 Conjugation and Resonance
95(10)
Basics 11 Thermodynamic Definitions
105(3)
Basics 12 Bond Dissociation Energy
108(3)
Basics 13 Calculating Enthalpy of Reaction from Bond Dissociation Energies
111(12)
Perspective 1 A Closer Look at Bond Dissociation Energies
114(4)
Practice 7 Calculating Enthalpy of Reaction from Bond Dissociation Energy
118(5)
Basics 14 Energetics and Reaction Profiles
123(5)
Basics 15 How Fast Are Reactions?
128(3)
Basics 16 Introduction to Carbocations, Carbanions, and Free-Radicals
131(9)
Basics 17 Carbocations 2-More Factors Affecting Stability
140(8)
Basics 18 Carbanions 2-Stability and pKa
148(31)
Perspective 2 A Scale for Carbocation Stability
159(8)
Common Error 3 Methyl Groups are Electron-Releasing
167(3)
Practice 8 Drawing Resonance Forms for Carbocations and Carbanions
170(6)
Common Error 4 Resonance
176(3)
Basics 19 The Hammond Postulate
179(4)
Basics 20 Conjugation and Stability-The Evidence
183(6)
Common Error 5 Carbocations and Carbanions
187(2)
Basics 21 Reactivity of Conjugated Systems
189(2)
Basics 22 Acid Catalysis in Organic Reactions Part 1
191(18)
Reaction Detail 1 Nucleophilic Substitution at Saturated Carbon
196(13)
Basics 23 What Defines a Transition State?
209(14)
Perspective 3 Bonding Beyond Hybridization
212(9)
Fundamental Knowledge Recap 1 Bond Lengths and Strengths
221(1)
Fundamental Knowledge Recap 2 pKa
222(1)
SECTION 3 A FOCUS ON SHAPE
223(5)
Habit 4 Representing Stereochemistry-Flying Wedge and Newman Projections
225(3)
Basics 24 Isomerism in Organic Chemistry-Configurational Isomers
228(32)
Habit 5 Getting Used to Drawing Stereoisomers
232(8)
Practice 9 Getting Used to Stereoisomers
240(3)
Habit 6 Assignments of Stereochemsitry--The Cahn-Ingold-Prelog Rules
243(11)
Practice 10 Assigning Stereochemistry
254(2)
Habit 7 Stereoisomers with Symmetry
256(4)
Basics 25 Properties of Stereoisomers
260(19)
Reaction Detail 2 Stereochemical Aspects of Substitution Reactions
263(8)
Common Error 6 Substitution Reactions
271(2)
Reaction Detail 3 Substitution with Retention of Configuration
273(2)
Common Error 7 Stereochemical Errors
275(4)
SECTION 4 TYPES OF SELECTIVITY
279(2)
Basics 26 Selectivity in Organic Chemistry-Chemoselectivity
281(1)
Basics 27 Selectivity in Organic Chemistry-Regioselectivity
282(1)
Basics 28 Selectivity in Organic Chemistry-Stereoselectivity
283(7)
Basics 29 Stereochemical Definitions Relating to Reactions
290(5)
SECTIONS 5 BONDS CAN ROTATE
293(2)
Basics 30 Isomerism in Organic Chemistry-Conformational Isomers
295(20)
Practice 11 Conformational Analysis
300(3)
Applications 1 Conformational Isomers 2
303(5)
Applications 2 SN2 Substitution Reactions Forming Three-Membered Rings
308(7)
Basics 31 Introduction to Cyclohexanes
315(20)
Practice 12 Drawing Cyclohexanes
326(3)
Applications 3 Substitution Reactions of Cyclohexanes
329(6)
Basics 32 Quantifying Conformers of Cyclohexanes
335(7)
Basics 33 More Conformers of Cyclohexanes and Related Compounds
342(11)
Practice 13 Drawing More Complex Cyclohexanes
347(3)
Common Error 8 Cyclohexanes
350(3)
SECTION 6 ELIMINATING THE LEARNING
353(5)
Reaction Detail 4 Elimination Reactions
358(6)
Perspective 4 A Continuum of Mechanisms
364(4)
Basics 34 More Substituted Alkenes Are More Stable
368(4)
Basics 35 Enthalpy Changes for Reactions Involving Anionic Species
372(2)
Applications 4 Stereochemistry of Elimination Reactions
375(6)
Basics 36 Stereospecificity
381(2)
Applications 5 Elimination Reactions of Cyclohexanes
383(7)
Common Error 9 Elimination Reactions
390(1)
Reaction Detail 5 Allylic Substitution
391(6)
SECTION 7 BUILDING SKILLS
397(2)
Worked Problem 1 Curly Arrows and Reaction Profiles
399(4)
Worked Problem 2 Competing SN1 Substitution and E1 Elimination
403(3)
Worked Problem 3 Competing SN2 Substitution and E2 Elimination
406(4)
Worked Problem 4 Acid Catalysis in Organic Reactions Part 2
410(4)
Worked Problem 5 Epoxide Opening Reactions
414(3)
Worked Problem 6 Is cis-Cyclohexane-1, 2-diol Really Achiral?
417(2)
Worked Problem 7 The Furst-Plattner Rule
419(4)
Worked Problem 8 SN2' Stereochemistry and Conformations
423(3)
Worked Problem 9 Complex Substitution Stereochemistry
426(4)
Worked Problem 10 Cyclization Reactions
430(4)
Solution to Problem 1 Curly Arrows and Reaction Profiles
434(4)
Solution to Problem 2 Competing SN1 Substitution and El Elimination
438(6)
Solution to Problem 3 Competing SN2 Substitution and E2 Elimination
444(5)
Solution to Problem 4 Acid Catalysis in Organic Reactions Part 2
449(5)
Solution to Problem 5 Epoxide Opening Reactions
454(3)
Solution to Problem 6 Is cis-Cyclohexane-1,2-diol Really Achiral?
457(4)
Solution to Problem 7 The Furst-Plattner Rule
461(9)
Solution to Problem 8 SN2' Stereochemistry and Conformations
470(6)
Solution to Problem 9 Complex Substitution Stereochemistry
476(6)
Solution to Problem 10 Cyclization Reactions
482(5)
Afterword 487(2)
Index 489
Dr Mark Elliott is Senior Lecturer in Organic Chemistry and Deputy Director of Learning and Teaching in the Department of Chemistry at Cardiff University. His research interests lie in the development of new synthetic methodology, and its application to target synthesis. He teaches organic chemistry at all levels of the undergraduate curriculum.