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Part I Basic Concepts in Frustrated Magnetism |
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1 Geometrically Frustrated Antiferromagnets: Statistical Mechanics and Dynamics |
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3 | (20) |
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3 | (2) |
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5 | (1) |
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1.3 Some Experimental Facts |
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6 | (2) |
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1.4 Classical Ground State Degeneracy |
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8 | (2) |
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10 | (4) |
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1.6 Ground State Correlations |
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14 | (3) |
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17 | (4) |
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21 | (2) |
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21 | (2) |
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2 Introduction to Quantum Spin Liquids |
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23 | (22) |
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23 | (4) |
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2.2 Basic Building Blocks of VBC and RVB Physics: The Valence Bonds |
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27 | (2) |
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2.3 Valence-Bond Crystals |
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29 | (4) |
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2.3.1 Zeroth-Order VBC Wave Function |
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30 | (1) |
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2.3.2 Quantum Fluctuations in VBCs |
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31 | (1) |
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32 | (1) |
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2.4 Resonating-Valence-Bond Spin Liquids |
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33 | (3) |
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2.5 VBCs or RVB Spin Liquids on Kagome and Pyrochlore Lattices? |
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36 | (2) |
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38 | (7) |
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39 | (6) |
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Part II Probing Frustrated Magnets |
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3 Neutron Scattering and Highly Frustrated Magnetism |
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45 | (34) |
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45 | (2) |
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3.2 What Neutron Scattering Measures |
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47 | (11) |
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3.2.1 Scattering Triangle |
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47 | (1) |
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3.2.2 Partial Differential Cross Section |
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48 | (1) |
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3.2.3 Relation to Sample Properties |
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49 | (1) |
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3.2.4 Scattering from Atomic Magnetic Moments |
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50 | (1) |
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3.2.5 Orientation Factor and Form Factor |
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50 | (1) |
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3.2.6 General Expression for the Neutron Scattering |
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51 | (1) |
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52 | (1) |
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52 | (1) |
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3.2.9 Static Approximation |
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52 | (1) |
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3.2.10 Wavevector Dependent Magnetic Moment and Susceptibility |
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53 | (1) |
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3.2.11 Fully Ordered Magnet |
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54 | (1) |
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3.2.12 Magnet with Full or Partial Disorder |
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55 | (1) |
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3.2.13 Validity of the Static Approximation |
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55 | (1) |
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3.2.14 Generalised Susceptibility |
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56 | (1) |
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3.2.15 Neutron Spectroscopy |
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57 | (1) |
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3.3 Typical Neutron Scattering Patterns |
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58 | (7) |
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58 | (1) |
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58 | (2) |
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60 | (1) |
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3.3.4 Conventional Magnet Above TC |
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60 | (1) |
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3.3.5 Conventional Magnet Below TC |
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61 | (1) |
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3.3.6 Cooperative Paramagnet |
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62 | (1) |
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3.3.7 Absent Pinch Points |
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63 | (1) |
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3.3.8 Dynamical Signature of Cooperative Paramagnetism |
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64 | (1) |
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65 | (11) |
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3.4.1 Cooperative Paramagnet States |
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65 | (5) |
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70 | (4) |
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74 | (2) |
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76 | (3) |
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77 | (2) |
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4 NMR and μSR in Highly Frustrated Magnets |
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79 | (28) |
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4.1 Basic Aspects of NMR and μSR Techniques |
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79 | (12) |
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4.1.1 Line Shift and Line Width |
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80 | (3) |
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4.1.2 Nuclear and Muon Spin-Lattice Relaxation Rate 1/T1 |
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83 | (2) |
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4.1.3 μSR: The Static Case |
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85 | (3) |
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4.1.4 μSR: The Dynamic Case |
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88 | (3) |
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4.2 From Zero- to Three-Dimensional Frustrated Magnets |
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91 | (16) |
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91 | (1) |
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4.2.2 Antiferromagnets on a Square Lattice with Competing Interactions: The J1-J2 Model |
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92 | (3) |
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4.2.3 Magnetic Frustration on a Triangular Lattice |
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95 | (2) |
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4.2.4 μSR and NMR in the Spin-1/2 Kagome Lattice ZnCu3(OH)6Cl2 |
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97 | (1) |
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4.2.5 The Problem of μ+ Relaxation in Some Kagome Lattices |
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98 | (3) |
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4.2.6 Persistent Dynamics and Lattice Distortions in the Pyrochlore Lattice |
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101 | (2) |
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103 | (4) |
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5 Optical Techniques for Systems with Competing Interactions |
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107 | (24) |
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107 | (1) |
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5.2 Inelastic Light-Scattering |
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108 | (2) |
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5.3 Inelastic Phonon Light-Scattering |
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110 | (1) |
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5.4 Inelastic Magnetic, Quasielastic, and Electronic Light Scattering |
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111 | (4) |
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115 | (1) |
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5.6 Spins, Phonons, and Light |
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116 | (2) |
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5.7 Spin-Phonon Interaction in Cr Spinels |
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118 | (4) |
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5.8 Exciton-Magnon Absorption in KCuF3 |
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122 | (9) |
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124 | (7) |
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Part III Frustrated Systems |
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6 The Geometries of Triangular Magnetic Lattices |
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131 | (24) |
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131 | (1) |
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6.2 Two-Dimensional Structures |
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132 | (9) |
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6.2.1 Planes of Edge-Sharing Triangles |
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132 | (4) |
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6.2.2 Planes of Corner-Sharing Triangles |
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136 | (5) |
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6.3 Three-Dimensional Structures |
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141 | (10) |
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6.4 Note on Synthesis of the Compounds |
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151 | (1) |
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151 | (4) |
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152 | (3) |
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7 Highly Frustrated Magnetism in Spinels |
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155 | (22) |
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155 | (1) |
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156 | (1) |
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7.3 Basic Electronic Configuration |
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157 | (1) |
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7.4 Uniqueness of the Spinel as a Frustrated Magnet |
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157 | (2) |
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7.5 Materials Overview of Spinels |
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159 | (2) |
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7.6 Frustration in Selected Spinels |
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161 | (11) |
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7.6.1 Pyrochlore Antiferromagnets in Spinel Oxides - B-site Frustration |
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161 | (6) |
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7.6.2 Frustrated Spins on Spinel A Sites |
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167 | (1) |
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7.6.3 Frustrated Magnets based on Cation-ordered Spinels: The Hyper-Kagome Lattice of Na4Ir3O8 |
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168 | (3) |
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7.6.4 Charge Frustration in Mixed-valent Spinels |
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171 | (1) |
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172 | (5) |
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173 | (4) |
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8 Experimental Studies of Pyrochlore Antiferromagnets |
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177 | (30) |
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177 | (1) |
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8.2 The Cubic Pyrochlores |
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178 | (2) |
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8.3 The Spin Liquid Ground State in Tb2Ti2O7 |
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180 | (5) |
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8.4 Ordered Ground States in Tb2Ti2O7 |
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185 | (5) |
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8.5 Structural Fluctuations in the Spin Liquid State of Tb2Ti2O7 |
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190 | (5) |
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8.6 Magnetic Order and Fluctuations in Tb2Sn2O7 |
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195 | (8) |
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8.6.1 Phase Transitions and Fluctuations in Gd2Ti2O7 and Gd2Sn2O7 |
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198 | (5) |
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203 | (4) |
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204 | (3) |
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9 Kagome Antiferromagnets: Materials Vs. Spin Liquid Behaviors |
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207 | (34) |
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9.1 A Short Theoretical Survey: What would be the Ideal Kagome Antiferromagnet? |
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208 | (2) |
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210 | (8) |
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9.2.1 Synthesis and the Jarosite Crystal Structure: Idealized and Disordered |
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210 | (5) |
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9.2.2 Fe jarosites: S = 5/2 Kagome Antiferromagnets |
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215 | (2) |
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9.2.3 Cr Jarosites- S = 3/2 Kagome Antiferromagnets |
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217 | (1) |
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218 | (1) |
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218 | (7) |
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218 | (1) |
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219 | (1) |
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220 | (2) |
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9.3.4 Non-magnetic Defects |
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222 | (2) |
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224 | (1) |
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9.4 Towards S = 1/2 Ideal Compounds |
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225 | (8) |
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225 | (3) |
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9.4.2 Herbertsmithite: "An end to the Drought of Quantum Spin Liquids [ 100]" |
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228 | (5) |
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233 | (2) |
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233 | (1) |
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234 | (1) |
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234 | (1) |
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235 | (6) |
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236 | (5) |
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Part IV Specific Effects in Frustrated Magnets |
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10 Magnetization Plateaus |
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241 | (28) |
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241 | (1) |
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10.2 Mechanisms for Formation of Magnetization Plateaus |
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242 | (9) |
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243 | (1) |
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10.2.2 Quantized Plateaus |
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244 | (1) |
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245 | (1) |
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10.2.4 Superfluid-Insulator Transition |
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246 | (1) |
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10.2.5 `Quantum' Plateaus |
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247 | (2) |
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10.2.6 High-Order Plateaus |
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249 | (1) |
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10.2.7 Transition into Plateaus |
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250 | (1) |
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10.3 Experimental Observation of Magnetization Plateaus |
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251 | (13) |
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10.3.1 `Classical' Plateaus in Triangular and Pyrochlore Lattices |
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252 | (3) |
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10.3.2 SrCu2(BO3)2 and the Shastry-Sutherland Model |
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255 | (3) |
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10.3.3 `Quantum' Plateaux and Spin Superstructure in SrCu2(BO3)2 |
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258 | (3) |
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10.3.4 Phase Diagram of SrCu2(BO3)2 |
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261 | (2) |
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10.3.5 RB4: A New Family of Shastry-Sutherland System |
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263 | (1) |
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264 | (5) |
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264 | (5) |
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11 Spin-Lattice Coupling in Frustrated Antiferromagnets |
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269 | (24) |
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269 | (1) |
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11.2 Spin-Driven Jahn-Teller Effect in a Tetrahedron |
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270 | (8) |
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11.2.1 Generalized Coordinates and Forces |
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271 | (2) |
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11.2.2 Four S = 1/2 Spins on a Tetrahedron |
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273 | (2) |
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11.2.3 Four Classical Spins on a Tetrahedron |
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275 | (1) |
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11.2.4 Color Notation and Other Useful Analogies |
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276 | (1) |
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11.2.5 Spin-Jahn-Teller Effect on a Triangle |
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276 | (2) |
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11.3 Models with Local Phonon Modes |
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278 | (2) |
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11.3.1 Half-Magnetization Plateau in ACr2O4 Spinels |
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279 | (1) |
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11.4 Collective Spin-Jahn-Teller Effect on the Pyrochlore Lattice |
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280 | (2) |
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11.5 Collective Jahn-Teller Effect in CdCr2O4 |
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282 | (7) |
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11.5.1 Spiral Magnetic Order in CdCr2O4 |
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283 | (1) |
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11.5.2 Theory of Spiral Magnetic Order |
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284 | (5) |
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11.6 Summary and Open Questions |
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289 | (4) |
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290 | (3) |
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293 | (38) |
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293 | (1) |
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12.2 Water Ice, Pauling Entropy, and Anderson Model |
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294 | (4) |
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12.2.1 Water Ice and Pauling Model |
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294 | (2) |
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12.2.2 Cation Ordering in Inverse Spinels and Antiferromagnetic Pyrochlore Ising Model |
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296 | (2) |
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12.3 Discovery of Spin Ice |
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298 | (11) |
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12.3.1 Rare-Earth Pyrochlore Oxides: Generalities |
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298 | (1) |
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12.3.2 Microscopic Hamiltonian: Towards an Effective Ising Model |
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299 | (5) |
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12.3.3 Discovery of Spin Ice in Ho2Ti2O7 |
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304 | (1) |
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12.3.4 Nearest-Neighbor Ferromagnetic (111) Ising Model and Pauling's Entropy |
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305 | (2) |
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12.3.5 Residual Entropy of Dy2Ti2O7 and Ho2Ti2O7 |
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307 | (2) |
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12.4 Dipolar Spin-Ice Model |
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309 | (10) |
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12.4.1 Competing Interactions in the Dipolar Spin-Ice Model |
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309 | (3) |
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312 | (4) |
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12.4.3 Loop Monte Carlo Simulations and Phase Diagram of Dipolar Spin Ice |
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316 | (2) |
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12.4.4 Origin of Ice Rules in Dipolar Spin Ice |
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318 | (1) |
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12.5 Current Research Topics in Spin Ices and Related Materials |
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319 | (6) |
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12.5.1 Magnetic-Field Effects |
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319 | (3) |
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12.5.2 Dynamical Properties and Role of Disorder |
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322 | (1) |
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12.5.3 Beyond the Dipolar Spin-Ice Model |
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322 | (1) |
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322 | (1) |
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12.5.5 Artificial Spin Ice |
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323 | (1) |
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323 | (1) |
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12.5.7 Quantum Mechanics, Dynamics, and Order in Spin Ices |
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323 | (1) |
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12.5.8 Coulomb Phase, Monopoles and Dirac Strings in Spin Ices |
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324 | (1) |
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325 | (6) |
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326 | (5) |
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13 Spin Nematic Phases in Quantum Spin Systems |
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331 | (34) |
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13.1 Introduction and Materials |
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331 | (2) |
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13.2 Multipolar States of a Single Spin |
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333 | (3) |
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13.3 Competition Between Dipoles and Quadrupoles |
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336 | (4) |
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13.3.1 The Bilinear-Biquadratic Model |
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336 | (2) |
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13.3.2 Energy Spectra of Small Clusters |
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338 | (2) |
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13.4 Quadrupolar Ordering in S = 1 Systems |
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340 | (15) |
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13.4.1 Variational Phase Diagram |
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340 | (6) |
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13.4.2 One- and Two-Magnon Instability of the Fully Polarized State |
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346 | (1) |
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13.4.3 Spin-Wave Theory for the Ferroquadrupolar Phase |
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347 | (6) |
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13.4.4 Numerical Approach |
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353 | (2) |
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13.5 From Chains to the Square Lattice |
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355 | (2) |
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13.6 Nematic Ordering in S = 1/2 Systems |
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357 | (2) |
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359 | (6) |
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360 | (5) |
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Part V Advanced Theoretical Methods and Concepts in Frustrated Magnetism |
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14 Schwinger Bosons Approaches to Quantum Antiferromagnetism |
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365 | (14) |
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14.1 SU(N) Heisenberg Models |
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365 | (1) |
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14.2 Schwinger Representation of SU(N) Antiferromagnets |
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366 | (3) |
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14.2.1 Bipartite Antiferromagnet |
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367 | (1) |
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14.2.2 Non-bipartite (Frustrated) Antiferromagnets |
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368 | (1) |
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14.3 Mean Field Hamiltonian |
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369 | (4) |
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14.3.1 Mean Field Equations |
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371 | (2) |
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14.4 The Mean Field Antiferromagnetic Ground State |
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373 | (2) |
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14.5 Staggered Magnetization in the Layered Antiferromagnet |
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375 | (4) |
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377 | (2) |
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15 Variational Wave Functions for Frustrated Magnetic Models |
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379 | (28) |
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379 | (3) |
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15.2 Symmetries of the Wave Function: General Properties |
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382 | (2) |
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15.3 Symmetries in the Two-dimensional Case |
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384 | (4) |
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15.3.1 The Marshall-Peierls Sign Rule |
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386 | (1) |
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387 | (1) |
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15.4 Connection with the Bosonic Representation |
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388 | (2) |
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15.5 Antiferromagnetic Order |
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390 | (2) |
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392 | (10) |
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15.6.1 One-dimensional Lattice |
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392 | (4) |
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15.6.2 Two-dimensional Lattice |
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396 | (6) |
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15.7 Other Frustrated Lattices |
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402 | (2) |
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404 | (3) |
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405 | (2) |
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16 Quantum Spin Liquids and Fractionalization |
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407 | (30) |
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407 | (2) |
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16.2 What is a Spin Liquid? |
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409 | (7) |
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16.2.1 Absence of Magnetic Long-Range Order (Definition 1) |
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409 | (1) |
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16.2.2 Absence of Spontaneously Broken Symmetry (Definition 2) |
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409 | (1) |
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16.2.3 Fractional Excitations (Definition 3) |
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410 | (5) |
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16.2.4 Half-odd-integer Spins and the Lieb-Schultz-Mattis-Hastings Theorem |
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415 | (1) |
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16.3 Mean Fields and Gauge Fields |
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416 | (11) |
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16.3.1 Fermionic Representation of Heisenberg Models |
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416 | (2) |
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16.3.2 Local SU(2) Gauge Invariance |
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418 | (1) |
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16.3.3 Mean-field (Spin-liquid) States |
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418 | (4) |
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16.3.4 Gauge Fluctuations |
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422 | (5) |
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427 | (5) |
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16.4.1 Short-range RVB Description |
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427 | (1) |
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16.4.2 Z2 Gauge Theory, Spinon Deconfinement, and Visons |
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428 | (2) |
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430 | (1) |
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16.4.4 How to Detect a Gapped Z2 Liquid |
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431 | (1) |
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16.5 Gapless (Algebraic) Liquids |
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432 | (1) |
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432 | (1) |
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433 | (4) |
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433 | (4) |
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437 | (44) |
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437 | (1) |
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17.2 How Quantum Dimer Models Arise |
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438 | (5) |
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17.2.1 Link Variables and Hard Constraints |
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438 | (1) |
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17.2.2 The Origin of Constraints |
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439 | (1) |
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17.2.3 Tunable Constraints |
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440 | (1) |
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17.2.4 Adding Quantum Dynamics |
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441 | (2) |
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17.3 The Quantum Dimer Model Hubert Space |
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443 | (4) |
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17.3.1 Topological Invariants |
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443 | (2) |
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445 | (1) |
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446 | (1) |
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447 | (9) |
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17.4.1 General Structure of Phase Diagrams |
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447 | (2) |
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17.4.2 Z2 RVB Liquid Phase |
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449 | (2) |
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17.4.3 U(1) RVB Liquid Phase |
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451 | (1) |
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17.4.4 Deconfined Critical Points |
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452 | (1) |
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17.4.5 Valence Bond Crystals |
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452 | (3) |
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17.4.6 Summary of Phase Diagrams |
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455 | (1) |
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17.5 The Rokhsar-Kivelson Point |
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456 | (4) |
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17.5.1 Ground-state Wavefunction |
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456 | (1) |
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17.5.2 Fractionalisation and Deconfinement |
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457 | (1) |
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17.5.3 Spatial Correlations |
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457 | (1) |
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458 | (1) |
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17.5.5 A Special Liquid Point or part of a Liquid Phase? |
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459 | (1) |
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17.6 Resonons, Photons, and Pions: Excitations in the Single mode Approximation |
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460 | (2) |
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17.7 Dualities and Gauge Theories |
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462 | (3) |
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17.7.1 Emergence of the QDM |
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463 | (1) |
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17.7.2 Continuum Limit of the Gauge Theory |
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464 | (1) |
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17.8 Height Representation |
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465 | (5) |
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470 | (1) |
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17.10 Dimer Phases in SU(2) Invariant Models |
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471 | (4) |
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17.10.1 Overlap Expansion |
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472 | (1) |
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473 | (1) |
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474 | (1) |
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17.10.4 Klein Models: SU(2) Invariant Spin Liquids |
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475 | (1) |
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475 | (6) |
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476 | (1) |
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476 | (1) |
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477 | (4) |
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18 Numerical Simulations of Frustrated Systems |
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481 | (32) |
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481 | (1) |
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18.2 Classical Monte Carlo |
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481 | (4) |
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485 | (3) |
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18.3.1 Stochastic Series Expansion (SSE) |
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485 | (2) |
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18.3.2 Green-function Monte Carlo |
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487 | (1) |
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488 | (1) |
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18.4.1 High-temperature Series |
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488 | (1) |
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18.4.2 T = 0 Perturbative Expansions for Ground- and Excited-state Properties |
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489 | (1) |
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18.5 Density-Matrix Renormalization Group (DMRG) |
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489 | (2) |
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490 | (1) |
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18.5.2 Dynamical Response Functions |
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490 | (1) |
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18.5.3 DMRG in two and more Dimensions |
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491 | (1) |
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18.6 Exact Diagonalization (ED) |
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491 | (15) |
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18.6.1 Basis Construction |
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492 | (1) |
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18.6.2 Coding of Basis States |
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493 | (1) |
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18.6.3 Symmetrized Basis States |
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494 | (2) |
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496 | (1) |
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497 | (2) |
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18.6.6 Implementation Details and Performance Aspects |
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499 | (1) |
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500 | (3) |
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18.6.8 Dynamical Response Functions |
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503 | (1) |
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504 | (1) |
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18.6.10 Finite Temperatures |
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505 | (1) |
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18.7 Miscellaneous Further Methods |
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506 | (2) |
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18.7.1 Classical Spin Dynamics (Molecular Dynamics) |
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506 | (1) |
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18.7.2 Coupled-Cluster Method |
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506 | (1) |
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18.7.3 Dynamical Mean-Field Theory (DMFT) |
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507 | (1) |
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18.7.4 Contractor Renormalization (CORE) |
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507 | (1) |
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18.7.5 SR-RVB Calculations |
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|
507 | (1) |
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18.8 Source Code Availability |
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508 | (5) |
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509 | (4) |
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19 Exact Results in Frustrated Quantum Magnetism |
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513 | (24) |
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513 | (2) |
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514 | (1) |
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19.2 Exact Results in Spin-1/2 Heisenberg Models |
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515 | (11) |
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19.2.1 Exact Ground States in Coupled Triangular Cluster Models |
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516 | (6) |
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19.2.2 Exact Ground States in Coupled Tetrahedral Cluster Models |
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522 | (2) |
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19.2.3 Realization of Exact Ground States |
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524 | (2) |
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19.3 Exact Results in Frustrated Spin-1/2 Models with Four-Spin Interactions |
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526 | (8) |
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19.3.1 General Ladder Model with Four-Spin Interactions |
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526 | (5) |
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19.3.2 Two-Dimensional Model with Four-Spin Interactions |
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531 | (3) |
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534 | (3) |
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535 | (2) |
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20 Strong-Coupling Expansion and Effective Hamiltonians |
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537 | (26) |
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537 | (1) |
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20.2 Strong-Coupling Expansion |
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538 | (9) |
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20.2.1 Second-Order Perturbation Theory |
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539 | (1) |
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20.2.2 High-Order Perturbation Theory |
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539 | (1) |
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540 | (7) |
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20.3 Alternative Approaches Yielding Effective Hamiltonians |
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547 | (9) |
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20.3.1 Canonical Transformation |
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547 | (1) |
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20.3.2 Continuous Unitary Transformation |
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548 | (7) |
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20.3.3 Contractor Renormalization |
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555 | (1) |
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556 | (7) |
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558 | (5) |
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Part VI Frustration, Charge Carriers and Orbital Degeneracy |
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21 Mobile Holes in Frustrated Quantum Magnets and Itinerant Fermions on Frustrated Geometries |
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563 | |
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563 | (1) |
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21.2 Doping Holes in Frustrated Quantum Magnets |
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564 | (5) |
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21.2.1 The Holon-Spinon Deconfinement Scenario |
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564 | (1) |
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21.2.2 Single Hole Doped in Frustrated Mott Insulators |
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565 | (3) |
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21.2.3 Hole Pairing and Superconductivity |
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568 | (1) |
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21.3 Doped Quantum Dimer Model |
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|
569 | (6) |
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21.3.1 Origin of the Quantum Dimer Model |
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569 | (2) |
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21.3.2 Phase Diagrams at Zero Doping |
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571 | (1) |
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21.3.3 Connection to the XXZ Magnet on the Checkerboard Lattice |
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571 | (2) |
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21.3.4 Bosonic Doped Quantum Dimer Model |
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573 | (1) |
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21.3.5 Non-Frobenius Doped Quantum Dimer Model on the Square Lattice |
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574 | (1) |
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21.4 Mott Transition on the Triangular Lattice |
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575 | (4) |
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21.4.1 Frustration in Itinerant Electron Systems |
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575 | (1) |
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21.4.2 Mott Transition in Organic Compounds with Triangular Geometry |
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|
575 | (1) |
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21.4.3 Mott Transition in the Triangular-Lattice Hubbard Model |
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576 | (3) |
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21.5 Ordering Phenomena at Commensurate Fermion Densities on Frustrated Geometries |
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|
579 | (5) |
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21.5.1 Bond Order Waves from Nesting Properties of the Fermi surface |
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|
580 | (1) |
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21.5.2 Metal-Insulator Transitions and Frustrated Charge Order |
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|
581 | (2) |
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21.5.3 Away from Commensurability: Doping the Resonating-Singlet-Pair Crystal |
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|
583 | (1) |
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584 | |
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|
584 | |