|
|
1 | (30) |
|
|
1 | (2) |
|
|
3 | (1) |
|
1.3 Regions of the Electromagnetic Spectrum |
|
|
4 | (2) |
|
1.4 Absorption Spectra of Proteins and Nucleic Acids |
|
|
6 | (2) |
|
1.5 Absorption Spectra of Mixtures |
|
|
8 | (1) |
|
1.6 The Photoelectric Effect |
|
|
9 | (1) |
|
1.7 Techniques for Measuring Absorbance |
|
|
10 | (4) |
|
1.8 Pump-probe and Photon-Echo Experiments |
|
|
14 | (1) |
|
1.9 Linear and Circular Dichroism |
|
|
15 | (2) |
|
1.10 Distortions of Absorption Spectra by Light Scattering or Nonuniform Distributions of the Absorbing Molecules |
|
|
17 | (2) |
|
|
19 | (5) |
|
1.12 IR and Raman Spectroscopy |
|
|
24 | (1) |
|
|
25 | (1) |
|
|
26 | (5) |
|
|
27 | (1) |
|
|
28 | (3) |
|
2 Basic Concepts of Quantum Mechanics |
|
|
31 | (50) |
|
2.1 Wavefunctions, Operators and Expectation Values |
|
|
31 | (7) |
|
|
31 | (1) |
|
2.1.2 Operators and Expectation Values |
|
|
32 | (6) |
|
2.2 The Time-Dependent and Time-Independent Schrodinger Equations |
|
|
38 | (7) |
|
2.2.1 Superposition States |
|
|
44 | (1) |
|
2.3 Spatial Wavefunctions |
|
|
45 | (17) |
|
|
45 | (1) |
|
2.3.2 A Particle in a Box |
|
|
46 | (3) |
|
2.3.3 The Harmonic Oscillator |
|
|
49 | (3) |
|
|
52 | (4) |
|
|
56 | (4) |
|
2.3.6 Wavefunctions for Large Systems |
|
|
60 | (2) |
|
2.4 Spin Wavefunctions and Singlet and Triplet States |
|
|
62 | (8) |
|
2.5 Transitions Between States: Time-Dependent Perturbation Theory |
|
|
70 | (3) |
|
2.6 Lifetimes of States and the Uncertainty Principle |
|
|
73 | (8) |
|
|
76 | (1) |
|
|
77 | (4) |
|
|
81 | (42) |
|
3.1 Electromagnetic Fields |
|
|
81 | (25) |
|
3.1.1 Electrostatic Forces and Fields |
|
|
81 | (1) |
|
3.1.2 Electrostatic Potentials |
|
|
82 | (3) |
|
3.1.3 Electromagnetic Radiation |
|
|
85 | (7) |
|
3.1.4 Energy Density and Irradiance |
|
|
92 | (7) |
|
3.1.5 The Complex Electric Susceptibility and Refractive Index |
|
|
99 | (5) |
|
3.1.6 Local-Field Correction Factors |
|
|
104 | (2) |
|
3.2 The Black-Body Radiation Law |
|
|
106 | (2) |
|
3.3 Linear and Circular Polarization |
|
|
108 | (2) |
|
3.4 Quantum Theory of Electromagnetic Radiation |
|
|
110 | (4) |
|
3.5 Superposition States and Interference Effects in Quantum Optics |
|
|
114 | (4) |
|
3.6 Distribution of Frequencies in Short Pulses of Light |
|
|
118 | (5) |
|
|
120 | (1) |
|
|
121 | (2) |
|
|
123 | (102) |
|
4.1 Interactions of Electrons with Oscillating Electric Fields |
|
|
123 | (5) |
|
4.2 The Rates of Absorption and Stimulated Emission |
|
|
128 | (4) |
|
4.3 Transition Dipoles and Dipole Strengths |
|
|
132 | (9) |
|
4.4 Calculating Transition Dipoles for π Molecular Orbitals |
|
|
141 | (2) |
|
4.5 Molecular Symmetry and Forbidden and Allowed Transitions |
|
|
143 | (17) |
|
|
160 | (4) |
|
4.7 Configuration Interactions |
|
|
164 | (4) |
|
4.8 Calculating Electric Transition Dipoles with the Gradient Operator |
|
|
168 | (9) |
|
4.9 Transition Dipoles for Excitations to Singlet and Triplet States |
|
|
177 | (2) |
|
4.10 The Born-Oppenheimer Approximation, Franck-Condon Factors, and the Shapes of Electronic Absorption Bands |
|
|
179 | (9) |
|
4.11 Spectroscopic Hole Burning |
|
|
188 | (3) |
|
4.12 Effects of the Surroundings on Molecular Transition Energies |
|
|
191 | (8) |
|
4.13 The Electronic Stark Effect |
|
|
199 | (6) |
|
4.14 Metal-Ligand and Ligand-Metal Charge-Transfer Transitions and Rydberg Transitions |
|
|
205 | (3) |
|
4.15 Thermodynamics of Photoexcitation |
|
|
208 | (17) |
|
|
214 | (2) |
|
|
216 | (9) |
|
|
225 | (72) |
|
5.1 The Einstein Coefficients |
|
|
225 | (3) |
|
|
228 | (2) |
|
|
230 | (3) |
|
5.4 The Strickler-Berg Equation and Other Relationships Between Absorption and Fluorescence |
|
|
233 | (6) |
|
5.5 Quantum Theory of Absorption and Emission |
|
|
239 | (6) |
|
5.6 Fluorescence Yields and Lifetimes |
|
|
245 | (11) |
|
5.7 Fluorescent Probes and Tags |
|
|
256 | (4) |
|
|
260 | (1) |
|
5.9 Fluorescence Anisotropy |
|
|
261 | (6) |
|
5.10 Single-Molecule Fluorescence and High-Resolution Fluorescence Microscopy |
|
|
267 | (5) |
|
5.11 Fluorescence Correlation Spectroscopy |
|
|
272 | (7) |
|
5.12 Intersystem Crossing, Phosphorescence, and Delayed Fluorescence |
|
|
279 | (18) |
|
|
282 | (1) |
|
|
283 | (14) |
|
|
297 | (28) |
|
6.1 Vibrational Normal Modes and Wavefunctions |
|
|
297 | (8) |
|
6.2 Vibrational Excitation |
|
|
305 | (7) |
|
6.3 Infrared Spectroscopy of Proteins |
|
|
312 | (3) |
|
6.4 Vibrational Stark Effects |
|
|
315 | (10) |
|
|
317 | (1) |
|
|
318 | (7) |
|
7 Resonance Energy Transfer |
|
|
325 | (28) |
|
|
325 | (2) |
|
|
327 | (15) |
|
7.3 Using Energy Transfer to Study Fast Processes in Single Protein Molecules |
|
|
342 | (2) |
|
|
344 | (2) |
|
7.5 Energy Transfer to and from Carotenoids in Photosynthesis |
|
|
346 | (7) |
|
|
348 | (2) |
|
|
350 | (3) |
|
|
353 | (30) |
|
8.1 Stationary States of Systems with Interacting Molecules |
|
|
353 | (8) |
|
8.2 Effects of Exciton Interactions on the Absorption Spectra of Oligomers |
|
|
361 | (6) |
|
8.3 Transition-Monopole Treatments of Interaction Matrix Elements and Mixing with Charge-Transfer Transitions |
|
|
367 | (3) |
|
8.4 Exciton Absorption Band Shapes and Dynamic Localization of Excitations |
|
|
370 | (3) |
|
8.5 Exciton States in Photosynthetic Antenna Complexes |
|
|
373 | (3) |
|
8.6 Excimers and Exciplexes |
|
|
376 | (7) |
|
|
377 | (2) |
|
|
379 | (4) |
|
|
383 | (34) |
|
9.1 Magnetic Transition Dipoles and n-π* Transitions |
|
|
383 | (11) |
|
9.2 The Origin of Circular Dichroism |
|
|
394 | (6) |
|
9.3 Circular Dichroism of Dimers and Higher Oligomers |
|
|
400 | (5) |
|
9.4 Circular Dichroism of Proteins and Nucleic Acids |
|
|
405 | (4) |
|
9.5 Magnetic Circular Dichroism |
|
|
409 | (8) |
|
|
412 | (2) |
|
|
414 | (3) |
|
10 Coherence and Dephasing |
|
|
417 | (46) |
|
10.1 Oscillations Between Quantum States of an Isolated System |
|
|
417 | (4) |
|
|
421 | (6) |
|
10.3 The Stochastic Liouville Equation |
|
|
427 | (2) |
|
10.4 Effects of Stochastic Relaxations on the Dynamics of Quantum Transitions |
|
|
429 | (6) |
|
10.5 A Density-Matrix Treatment of Absorption of Weak, Continuous Light |
|
|
435 | (3) |
|
10.6 The Relaxation Matrix |
|
|
438 | (10) |
|
10.7 More General Relaxation Functions and Spectral Lineshapes |
|
|
448 | (6) |
|
10.8 Anomalous Fluorescence Anisotropy |
|
|
454 | (9) |
|
|
460 | (1) |
|
|
461 | (2) |
|
11 Pump-Probe Spectroscopy, Photon Echoes and Vibrational Wavepackets |
|
|
463 | (50) |
|
11.1 First-Order Optical Polarization |
|
|
463 | (9) |
|
11.2 Third-Order Optical Polarization and Non-linear Response Functions |
|
|
472 | (5) |
|
11.3 Pump-Probe Spectroscopy |
|
|
477 | (3) |
|
|
480 | (7) |
|
11.5 Two-Dimensional Electronic and Vibrational Spectroscopy |
|
|
487 | (3) |
|
|
490 | (3) |
|
11.7 Vibrational Wavepackets |
|
|
493 | (9) |
|
11.8 Wavepacket Pictures of Spectroscopic Transitions |
|
|
502 | (11) |
|
|
504 | (2) |
|
|
506 | (7) |
|
12 Raman Scattering and Other Multi-photon Processes |
|
|
513 | (36) |
|
12.1 Types of Light Scattering |
|
|
513 | (4) |
|
12.2 The Kramers-Heisenberg-Dirac Theory |
|
|
517 | (9) |
|
12.3 The Wavepacket Picture of Resonance Raman Scattering |
|
|
526 | (2) |
|
12.4 Selection Rules for Raman Scattering |
|
|
528 | (3) |
|
12.5 Surface-Enhanced Raman Scattering |
|
|
531 | (1) |
|
12.6 Biophysical Applications of Raman Spectroscopy |
|
|
531 | (1) |
|
12.7 Coherent (Stimulated) Raman Scattering |
|
|
532 | (2) |
|
12.8 Multi-photon Absorption |
|
|
534 | (3) |
|
12.9 Quasielastic (Dynamic) Light Scattering (Photon Correlation Spectroscopy) |
|
|
537 | (12) |
|
|
541 | (1) |
|
|
542 | (7) |
|
|
549 | (12) |
|
|
549 | (2) |
|
|
551 | (2) |
|
|
553 | (4) |
|
A.4 Phase Shift and Modulation Amplitude in Frequency-Domain Spectroscopy |
|
|
557 | (3) |
|
A.5 CGS and SI Units and Abbreviations |
|
|
560 | (1) |
References |
|
561 | (2) |
Index |
|
563 | |