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El. knyga: Molecular and Laser Spectroscopy: Advances and Applications: Volume 2

Edited by (University of Lucknow, India), Edited by (Professor Emeritus, School of Science and Technology, Kwansei Gakuin University, Sanda, Hyogo, Japan)
  • Formatas: PDF+DRM
  • Išleidimo metai: 10-Jul-2020
  • Leidėjas: Elsevier Science Publishing Co Inc
  • Kalba: eng
  • ISBN-13: 9780128188712
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Molecular and Laser Spectroscopy: Advances and Applications: Volume 2Didesnis paveikslėlis
  • Formatas: PDF+DRM
  • Išleidimo metai: 10-Jul-2020
  • Leidėjas: Elsevier Science Publishing Co Inc
  • Kalba: eng
  • ISBN-13: 9780128188712
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Molecular and Laser Spectroscopy, Advances and Applications: Volume 2 gives students and researchers an up-to-date understanding of the fast-developing area of molecular and laser spectroscopy. This book covers basic principles and advances in several conventional as well as new and upcoming areas of molecular and laser spectroscopy, such as a wide range of applications in medical science, material science, standoff detection, defence and security, chemicals and pharmaceuticals, and environmental science. It covers the latest advancements, both in terms of techniques and applications, and highlights future projections.

Editors V.P. Gupta and Yukihiro Ozaki have brought together eminent scientists in different areas of spectroscopy to develop specialized topics in conventional molecular spectroscopy (Cavity ringdown, Matrix Isolation, Intense THz, Far- and Deep- UV, Optogalvanic ), linear and nonlinear laser spectroscopy (Rayleigh & Raman Scattering), Ultrafast Time-resolved spectroscopy, and medical applications of molecular spectroscopy. and advanced material found in research articles. This new volume expands upon the topics covered in the first volume for scientists to learn the latest techniques and put them to practical use in their work.

  • Covers several areas of spectroscopy research and expands upon topics covered in the first volume
  • Includes exhaustive lists of research articles, reviews, and books at the end of each chapter to further learning objectives
  • Uses illustrative examples of the varied applications to provide a practical guide to those interested in using molecular and laser spectroscopy tools in their research
Contributors xix
Preface xxiii
1 Introduction and overview
1(40)
V.P. Gupta
1 Introduction
1(5)
1.1 Significance of spectroscopic studies
1(1)
1.2 Spectroscopic techniques
2(1)
1.2.1 Infrared spectroscopy
2(1)
1.2.2 Raman spectroscopy
3(2)
1.2.3 Electronic spectroscopy
5(1)
1.2.4 Other techniques
5(1)
2 Background information and overview
6(30)
2.1 Vibrational optical activity spectroscopy
6(2)
2.2 Cavity ring-down spectroscopy
8(2)
2.3 Terahertz time-domain spectroscopy (THz-TDS)
10(2)
2.4 Matrix isolation studies
12(2)
2.5 Optogalvanic spectroscopy
14(2)
2.6 Far- and deep-ultraviolet spectroscopy for inorganic semiconductor
16(1)
2.7 Hyper-Rayleigh scattering (HRS)
17(1)
2.8 Vibrational sum frequency generation (VSFG) spectroscopy
18(3)
2.9 Surface-enhanced Raman spectroscopy
21(3)
2.10 Shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS)
24(1)
2.11 Stimulated Raman scattering (SRS)
25(2)
2.12 Synchrotron-based UV resonance Raman scattering (SR-UVRR)
27(1)
2.13 Stand-off Raman spectroscopy
28(3)
2.14 Ultrafast time-resolved molecular spectroscopy techniques
31(1)
2.14.1 Overview of time-resolved electronic spectroscopic studies
32(1)
2.14.2 Overview of ultrafast time-resolved molecular spectroscopy studies
33(1)
2.15 Infrared and Raman imaging and microscopy in medical applications
33(2)
2.15.1 Overview of infrared imaging and microscopy
35(1)
2.15.2 Overview of Raman imaging and microscopy
36(1)
References
36(5)
2 Vibrational optical activity spectroscopy
41(42)
Tomotsumi Fujisawa
Masashi Unno
1 Introduction
41(1)
2 Principles of vibrational optical activity spectroscopy
42(8)
2.1 Raman optical activity
42(2)
2.2 Nonresonance Raman optical activity
44(3)
2.3 Resonance effect in Raman optical activity
47(1)
2.4 Vibrational circular dichroism
47(3)
3 Instrumentation of vibrational optical activity spectroscopy
50(3)
3.1 Instrumentation of Raman optical activity
50(2)
3.2 Instrumentation of vibrational circular dichroism
52(1)
4 Spectral analysis in vibrational optical activity spectroscopy
53(3)
4.1 Quantum chemical calculations of vibrational optical activity spectra
53(1)
4.2 Effects of solvent and conformational averaging
54(1)
4.3 Applications to large systems
55(1)
5 Selected applications of Raman optical activity and vibrational circular dichroism spectroscopy
56(21)
5.1 Raman optical activity
56(1)
5.1.1 Absolute configuration of small molecules
56(1)
5.1.2 Peptides and proteins
56(6)
5.1.3 Carbohydrates
62(2)
5.1.4 Chromophoric proteins
64(2)
5.1.5 Resonance Raman optical activity
66(2)
5.2 Vibrational circular dichroism
68(1)
5.2.1 Determination of absolute configuration
68(1)
5.2.2 Determination of absolute configuration by vibrational circular dichroism exciton coupling
69(3)
5.2.3 Structural analysis of biopolymers
72(3)
5.2.4 Supramolecules
75(2)
6 Summary
77(1)
References
77(6)
3 Cavity ring-down spectroscopy: recent technological advances and applications
83(38)
Abhijit Maity
Sanchi Maithani
Manik Pradhan
1 Introduction
83(2)
2 Principle of CRDS operation
85(3)
2.1 Sensitivity of CRDS
87(1)
3 Mode Structure of an optical cavity
88(3)
4 Brief historical overview
91(1)
5 Continuous wave (cw) cavity ring-down spectroscopy
91(3)
6 Recent technological advances
94(8)
6.1 Rapidly swept cw-CRD spectroscopy
94(2)
6.2 Cavity-enhanced (CE) optical frequency comb (OFC) spectroscopy
96(1)
6.3 Optical feedback (OF) cavity-enhanced spectroscopy
97(1)
6.4 Pound-Drever-Hall (PDH) locking and frequency stabilized (FS) cavity ring-down spectroscopy
97(2)
6.5 Noise-immune cavity-enhanced optical heterodyne molecular spectroscopy (NICE-OHMS)
99(1)
6.6 Frequency-agile, rapid-scanning (FARS) cavity ring-down spectroscopy
100(1)
6.7 Quantum cascade laser (QCL) coupled cavity ring-down spectroscopy
101(1)
7 Applications of cavity ring-down spectroscopy
102(10)
7.1 High-resolution fundamental spectroscopy
102(2)
7.2 Environmental monitoring
104(4)
7.3 Dissolved trace gas monitoring
108(1)
7.4 Bio-medical diagnostics
108(2)
7.5 Plasma diagnostics
110(1)
7.6 Liquid-phase CRDS
111(1)
8 Conclusion and future perspectives
112(1)
References
113(8)
4 Terahertz time-domain spectroscopy: advanced techniques
121(46)
Jean-Louis Coutaz
Alexander P. Shkurinov
1 Introduction
122(1)
2 Basic concepts of THz time-domain spectroscopy
123(14)
2.1 Generation and detection of picosecond electromagnetic bursts
123(1)
2.1.1 Photo-conducting antennas
124(1)
2.1.2 Electrooptic (EO) antennas
125(1)
2.2 THz-TDS systems and THz-TDS signals
126(1)
2.2.7 THz-TDS setups
126(1)
2.2.2 THz-TDS signals
127(1)
2.2.3 Noise and errors
128(1)
2.3 Extraction of the THz parameters of samples
129(1)
2.3.1 THz-TDS in transmission
130(2)
2.3.2 THz-TDS in reflection
132(1)
2.3.3 Precision of the extraction
133(1)
2.4 Comparison with other far-infrared characterization techniques
134(1)
2.4.1 CW optoelectronic systems
134(2)
2.4.2 CWVNA systems
136(1)
2.4.3 Comparison with FTIR
136(1)
3 Dedicated measurements
137(6)
3.1 Characterization of thin films
137(2)
3.2 Characterization of liquids
139(1)
3.3 Ellipsometry
140(1)
3.4 Characterization of anisotropic materials and magnetic materials
140(1)
3.5 Characterization of scattering materials
141(1)
3.6 Determination of the sample thickness
142(1)
4 THz-IDs time-resolved studies: from pump-and-probe to THz spectro-chronography techniques
143(4)
4.1 Pump-and-probe THz-TDS
143(1)
4.2 THz spectro-chronography: the windowed Fourier transform procedure
144(3)
5 Generation of THz waves in gases
147(11)
5.1 Generalities and historical overview
147(2)
5.2 Photo-induced ionization of a gas
149(1)
5.2.1 Ponderomotive force
149(2)
5.3 Laser wakefield-accelerated electron bunch transition radiation
151(1)
5.4 Generation in the presence of an electrical bias
151(1)
5.5 THz generation in gases excited by the fundamental and second harmonic frequencies of the laser beam
152(1)
5.5.7 THz generation by four-wave mixing rectification
152(1)
5.5.2 Optical and photocurrent asymmetry at the plasma
153(1)
5.6 Estimation of the THz pulse electric field using air-based photonics
154(4)
5.7 THz-TDS with air-plasma sources
158(1)
6 Conclusion
158(1)
References
159(8)
5 Spectroscopy of molecules confined in solid para-hydrogen
167(50)
Masashi Tsuge
Yuan-Pern Lee
1 Introduction
168(1)
2 Properties of H2
169(3)
2.1 Ortho and para species
169(1)
2.2 Properties of solid p-H2
170(1)
2.3 Quantum solid
171(1)
3 Instrumentation: preparation of p-H2 and matrix-isolation spectroscopy
172(9)
3.1 Ortho-to-para converter
172(1)
3.2 Matrix-isolation spectrometry
173(2)
3.3 Ortho-H2 mixing ratio in solid para-H2
175(2)
3.4 Estimation of mixing ratio from IR spectra
177(3)
3.5 Estimation of sample temperature
180(1)
4 Spectroscopy of stable molecules
181(7)
4.1 High-resolution infrared spectroscopy
181(1)
4.1.1 Methane
181(1)
4.1.2 Propene
182(2)
4.2 Large amplitude motion: methyl internal rotation
184(2)
4.3 Interaction between guest molecules and o-H2 impurity
186(1)
4.4 Electronic spectroscopy
187(1)
5 Spectroscopy of free radicals and ions
188(19)
5.1 Diminished cage effect and spectroscopy of radicals
188(1)
5.7.7 Photolysis in situ
188(2)
5.7.2 Bimolecular reactions: reaction of CI atom with unsaturated hydrocarbon molecules
190(2)
5.2 Protonated species
192(1)
5.2.1 Infrared spectroscopy of protonated species
192(2)
5.2.2 Electron bombardment during p-H2 matrix deposition
194(2)
5.2.3 Application to polycyclic aromatic hydrocarbons (PAH)
196(3)
5.2.4 Application to small molecules
199(2)
5.2.5 Identification of proton-bound dimers
201(2)
5.3 Hydrogen atoms and hydrogen reaction in solid p-H2
203(1)
5.3.1 Generation of hydrogen atoms in solid p-H2
203(2)
5.3.2 Spectroscopy of hydrogenated species
205(1)
5.3.3 Hydrogen abstraction reaction
206(1)
6 Future perspective
207(1)
References
208(9)
6 Optogalvanic spectroscopy and its applications
217(28)
Surya N. Thakur
1 Introduction
217(3)
2 Physics of optogalvanic spectroscopy
220(3)
3 Experimental systems
223(5)
3.1 Laser optogalvanic spectroscopy of dc discharge
223(2)
3.2 Laser optogalvanic spectroscopy with hollow cathode discharge
225(1)
3.3 Laser optogalvanic spectroscopy of radio frequency and microwave discharges
226(1)
3.4 Laser optogalvanic spectroscopy in flames
227(1)
4 Applications of optogalvanic spectroscopy
228(13)
4.1 Optogalvanic spectroscopy of rare gases
229(1)
4.2 Optogalvanic spectroscopy of molecules
230(3)
4.3 Mobility measurements of ions and small particles in flames
233(2)
4.4 Electron-photodetachment studies by optogalvanic spectroscopy
235(1)
4.4.1 Photodetachment threshold
236(2)
4.5 Intracavity optogalvanic spectroscopy
238(1)
4.6 Wavelength calibration
238(1)
4.7 Laser frequency and power stabilization
239(1)
4.8 Rydberg states of atoms
239(1)
4.9 Understanding the physics of OGS
240(1)
5 Conclusion
241(1)
References
241(4)
7 Far- and deep-ultraviolet spectroscopy for inorganic semiconductor materials
245(30)
Ichiro Tanabe
1 Introduction
245(1)
2 Study of optical properties of Ti02 using radiation spectroscopy and theoretical simulation
246(2)
3 ATR spectroscopy for semiconductor materials
248(12)
3.1 ATR-FUV instrument
248(6)
3.2 ATR-FUV measurements of semiconductor powders
254(3)
3.3 Photon-induced spectral changes of Ti02
257(3)
4 DUV Rayleigh scattering spectroscopy for individual Ti02 nanocrystals
260(3)
5 Applications of UV Raman spectroscopy for semiconductor nanocrystals
263(5)
5.1 Study of Ti02 phase transformation using UV Raman spectroscopy
263(3)
5.2 UV Raman spectroscopy of zirconia nanocrystals
266(2)
6 Summary and future outlook
268(1)
References
269(6)
8 First-order hyperpolarizability of organic molecules: hyper-Rayleigh scattering and applications
275(40)
Marcelo G. Vivas
Daniel L. da Silva
Cleber R. Mendonca
Leonardo De Boni
1 Introduction
275(4)
2 Microscopic description of the nonlinear optical response: Electronic first-order hyperpolarizability
279(3)
3 Hyper-Rayleigh scattering technique
282(2)
4 Theoretical calculation
284(7)
4.1 Importance of symmetry on the second-order NLO responses
284(1)
4.1.1 Intrinsic symmetry of permutation
285(1)
4.1.2 Kleinman's symmetry
285(1)
4.1.3 Molecular symmetry
286(1)
4.2 Molecular first-order hyperpolarizability by hyper-Rayleigh scattering experiment
286(2)
4.3 Schemes for the determination of the molecular hyperpolarizabilities
288(3)
5 First-order hyperpolarizability in push-pull octupolar molecules
291(9)
5.1 Enhancing the electronic first-order hyperpolarizability
291(4)
5.2 Comparison between experimental and theoretical data for dynamic first-order hyperpolarizability
295(1)
5.3 Molecular branching effect on the dynamic first-order hyperpolarizability
296(2)
5.4 Quantifying molecular interaction via HRS signal
298(2)
6 Discussing HRS results based on quantum chemical results
300(9)
7 Final Remarks
309(2)
References
311(4)
9 Heterodyne-detected chiral vibrational sum frequency generation spectroscopy of bulk and interfacial samples
315(34)
Taka-aki lshibashi
Masanari Okuno
1 Introduction
315(2)
2 Principles of chiral VSFG spectroscopy
317(9)
2.1 What is VSFG spectroscopy?
317(1)
2.2 VSFG susceptibility and its symmetric properties
318(1)
2.3 VSFG susceptibility and molecular hyperpolarizability
319(2)
2.4 Relation between chiral VSFG susceptibility and the symmetry of Raman tensor
321(1)
2.5 Polarization combinations for chiral and achiral SFG measurements
322(2)
2.6 Modes of SFG signal measurement
324(1)
2.6.1 Narrowband IR scheme and multiplex scheme of SFG spectral measurement
324(1)
2.6.2 Intensity measurement and phase-sensitive measurement of SFG signals
324(2)
3 Experimental setup and the analysis of observed data in HD chiral VSFG
326(4)
3.1 Multiplex HD VSFG spectrometer
326(2)
3.2 Method for analyzing raw data to calculate the susceptibility of a sample
328(2)
4 Applications of HD chiral VSFG spectroscopy
330(13)
4.1 Neat liquid limonene
330(2)
4.2 Vibrationally-electronically doubly-resonant chiral SFG of chiral solutions
332(3)
4.3 Vibrationally-electronically doubly-resonant chiral SFG of chiral monolayers - electronic excitation profiles of complex chiral susceptibilities
335(3)
4.4 Polymer thin films - bulk-or-interface assignment by polarization dependence
338(3)
4.5 Air/protein solution interfaces
341(2)
5 Concluding remarks
343(1)
References
344(3)
Appendix A Fresnel factors
347(2)
10 Surface-enhanced Raman scattering (SERS) and applications
349(38)
Xiaoxia Han
Bing Zhao
1 SERS and its mechanisms: a brief introduction
350(1)
2 SERS-active substrates
351(6)
2.1 Noble metals
352(1)
2.2 Transition metals
353(1)
2.3 Semiconductors
353(1)
2.3.1 Metal oxides
353(4)
2.4 Semiconductor-metal heterostructures
357(1)
3 Mechanism of SERS on semiconductor nanomaterials
357(4)
3.1 Plasmon resonance
358(1)
3.2 Mie resonance
358(1)
3.3 CT resonance
359(1)
3.4 Exciton resonance
360(1)
3.5 Key points of SERS on pure semiconductor nanomaterials
361(1)
4 Applications
361(15)
4.1 Probing CT in dye-sensitized solar cells
361(1)
4.1.1 ZnO-TiO2/N3/Ag
362(1)
4.1.2 Au@Ag/N3ffiO2
362(1)
4.2 Chemical and biological sensing
363(1)
4.2.1 Small ions and toxic molecules
363(4)
4.2.2 Protein biomarkers
367(1)
4.2.3 Cell viability and apoptosis assays
368(3)
4.3 Probing intermolecular interactions
371(1)
4.3.1 The effect of hydrogen bonds on CT
371(2)
4.3.2 Enantioselective discrimination by hydrogen binding
373(2)
4.3.3 ET between redox proteins
375(1)
5 Conclusions and outlook
376(1)
References
376(11)
11 Shell-isolated nanoparticle-enhanced Raman spectroscopy: a review
387(28)
Jan Krajczewski
Andrzej Kudelski
1 Introduction
387(1)
2 Interaction of light with the plasmonic nanoparticles
388(3)
3 Synthesis of plasmonic cores for SHINERS nanoresonators
391(3)
4 Formation of the protecting layer
394(1)
5 Example applications of SHINERS spectroscopy
395(14)
6 Summary
409(1)
References
409(6)
12 Novel application of stimulated Raman scattering for high-resolution spectroscopic imaging utilizing its phase information
415(32)
Motohiro Banno
Hiroharu Yui
1 The brief history and the principle of stimulated Raman scattering microscopy
416(7)
1.1 Principles of spontaneous and coherent Raman scattering
416(3)
1.2 Application of coherent Raman scattering to microscopic imaging
419(2)
1.3 Difficulties in conventional stimulated Raman scattering microscopy and possible solutions
421(2)
2 Interferometric approach for obtaining the phase information from the stimulated Raman scattering signal
423(7)
2.1 Principle of stimulated Raman scattering interferometry
423(3)
2.2 Instrumental setup
426(1)
2.3 Results and discussion
427(3)
3 Differential interference contrast stimulated Raman scattering microscopy
430(4)
3.1 Principle of differential interference contrast-stimulated Raman scattering microscopy
430(2)
3.2 Instrumental setup
432(1)
3.3 Results and discussion
433(1)
4 Near-infrared stimulated Raman scattering photoacoustic spectroscopy
434(5)
4.1 Principle of near-infrared stimulated Raman scattering photoacoustic spectroscopy
434(2)
4.2 Instrumental setup
436(1)
4.3 Results and discussion
437(2)
5 Future plans: introduction of wave-front modulation technique
439(3)
5.1 Improvement of the lateral resolution by spot shaping based on Fourier optics
439(1)
5.2 Acceleration of imaging by multi-focus stimulated Raman scattering microscopy
440(2)
5.3 Image correction by the technique based on adaptive optics
442(1)
6 Conclusion
442(1)
References
443(4)
13 Synchrotron-based ultraviolet resonance Raman scattering for material science
447(36)
Barbara Rossi
Cettina Bottari
Sara Catalini
Francesco D'Amico
Alessandro Gessini
Claudio Masciovecchio
1 Introduction to resonance Raman spectroscopy
447(6)
1.1 Light scattering and Raman effect
447(4)
1.2 Resonance Raman scattering
451(1)
1.3 Advantages and limitations of resonance Raman spectroscopy
452(1)
2 Synchrotron-based ultraviolet resonance Raman setup at Elettra
453(3)
3 Ultraviolet resonance Raman for investigation of structure and dynamics of peptides and proteins
456(10)
3.1 Aqueous solvation of peptides
456(3)
3.2 Isotope-labeling for monitoring structural conformations in peptides
459(3)
3.3 Selectivity of synchrotron radiation-based ultraviolet resonance Raman for proteins
462(4)
4 Ultraviolet resonance Raman study of deoxyribonucleic acid and their assemblies
466(11)
4.1 Selectivity of ultraviolet resonance Raman on nucleobases
468(3)
4.2 Conformational stability of deoxyribonucleic acid in aqueous solution
471(2)
4.3 Thermal stability of deoxyribonucleic acid G-quadruplexes complexed with anticancer drug
473(3)
4.4 Complementarity of ultraviolet resonance Raman and infrared spectroscopies for investigation of deoxyribonucleic acid
476(1)
5 Final remarks and perspectives
477(1)
References
478(5)
14 Concept and applications of standoff Raman spectroscopy techniques
483(38)
Yashashchandra Dwivedi
1 Concept of standoff spectroscopy
483(2)
2 Standoff spectroscopic techniques
485(17)
2.1 Standoff Raman spectroscopy
485(1)
2.1.1 Experimental methods
486(4)
2.2 Time-resolved standoff Raman spectroscopy
490(3)
2.3 Standoff resonance Raman spectroscopy
493(1)
2.4 Standoff spatially offset Raman spectroscopy
494(1)
2.5 Raman-laser-induced breakdown spectroscopy
495(3)
2.6 Raman-light detection and ranging spectroscopy
498(4)
3 Applications
502(10)
3.1 Chemical and mineral detection
502(2)
3.2 Explosives detection
504(3)
3.3 Atmospheric applications
507(4)
3.4 Art and archeology
511(1)
4 Future scope
512(1)
References
513(8)
15 The role of excited states in deciphering molecules and materials: time-resolved electronic spectroscopic studies
521(42)
E. Siva Subramaniam Iyer
1 Introduction
521(1)
2 Probing microheterogeneity of a medium by monitoring the spectral properties
522(4)
2.1 Effect of solvent polarity
523(1)
2.2 Photoisomerization
524(1)
2.3 Excited-state proton transfer
525(1)
3 Experimental techniques for monitoring excited-state properties
526(6)
3.1 Time-correlated single-photon counting
526(2)
3.1.1 Time-resolved area normalized emission spectroscopic analysis
528(2)
3.2 Transient absorption spectroscopy
530(1)
3.2.1 Global analysis of transient absorption spectroscopy data
531(1)
3.2.2 A note on time-resolved emission spectra and decay-associated spectra
532(1)
4 Applications
532(19)
4.1 The microenvironment in Nation probed by ultrafast fluorescence spectroscopy
532(5)
4.2 The effect of protein binding on the dynamics of DNA probed by fluorescence spectroscopy
537(3)
4.3 Early intramolecular events probed by transient absorption spectroscopy
540(1)
4.4 Understanding microenvironment inside thermophilic rhodopsin using transient absorption spectroscopy
541(6)
4.5 Investigating intermolecular charge separation in light-harvesting units using transient absorption spectroscopy
547(4)
5 Conclusion
551(1)
References
551(12)
16 Ultrafast time-resolved molecular spectroscopy
563(32)
Vikas Kumar
Sebastian Schliicker
Eckart Hasselbrink
1 Introduction
563(1)
2 Transient absorption spectroscopy (flash photolysis)
564(3)
3 Time-resolved fluorescence spectroscopy
567(5)
3.1 Fluorescence lifetime imaging microscopy
570(1)
3.2 Time-resolved fluorescence resonance energy transfer
571(1)
4 Time-resolved linear vibrational spectroscopy
572(7)
4.1 Time-resolved infrared spectroscopy
572(3)
4.2 Time-resolved resonance Raman spectroscopy
575(4)
5 Time-resolved nonlinear vibrational spectroscopy
579(13)
5.1 Time-resolved sum-frequency generation vibrational spectroscopy
579(1)
5.1.1 Steady-state sum-frequency generation vibrational spectroscopy
580(1)
5.1.2 Time-resolved infrared-visible sum-frequency generation vibrational spectroscopy
581(1)
5.1.3 Time-resolved pump/sum-frequency generation-probe spectroscopy
581(1)
5.2 Time-resolved coherent anti-Stokes Raman scattering spectroscopy
582(5)
5.3 Time-resolved femtosecond stimulated Raman spectroscopy
587(3)
5.4 Time-resolved femtosecond Raman-induced Kerr-effect spectroscopy
590(2)
6 Conclusion
592(1)
References
592(3)
17 Infrared spectroscopic imaging: a case study for digital molecular histopathology
595(28)
Anirudh Mittal
Shachi Mittal
Kevin Yeh
Anna Higham
Rohit Bhargava
1 Introduction
596(1)
2 Fundamentals of infrared imaging and considerations for use
597(10)
2.1 Michelson interferometer
597(2)
2.2 Interferogram
599(1)
2.3 Resolution
600(1)
2.3.1 Spectral resolution
600(1)
2.3.2 Spatial resolution
601(2)
2.4 Computational processing
603(1)
2.4.1 Apodization
604(1)
2.4.2 Baseline correction
605(1)
2.4.3 Noise reduction
605(2)
3 Infrared microscope design and influence of optics and sample properties on the data recorded
607(2)
3.1 Imaging setups
607(1)
3.2 Scattering effects
608(1)
4 Applications: a case study of breast cancer
609(4)
4.1 Overview of medical diagnosis
609(2)
4.2 Tumor detection and associated microenvironment
611(1)
4.3 Molecular content in infrared imaging
611(2)
5 Prospects and outlook
613(2)
References
615(8)
18 Emerging trends in biomedical imaging and disease diagnosis using Raman spectroscopy
623(30)
Santosh Kumar Paidi
Rishikesh Pandey
Ishan Barman
1 Introduction: biomedical Raman spectroscopy
623(2)
2 Biomedical Raman instrumentation: state-of-the-art
625(4)
2.1 Excitation sources
625(1)
2.2 Collection optics and detection system
626(1)
2.3 Integration with microscopes
627(1)
2.4 Fiber optic Raman probes for delivery and collection of light
627(2)
3 Clinical applications of Raman spectroscopy
629(7)
3.1 Ex vivo analysis for disease detection and bioanalyte monitoring
630(1)
3.1.1 Biofluids
630(1)
3.1.2 Bone and mineralized tissues
630(2)
3.1.3 Solid tumors
632(2)
3.2 In vivo tissue analysis for disease detection
634(1)
3.2.1 Intraoperative margin assessment
634(1)
3.2.2 Endoscopic applications
635(1)
4 Preclinical applications beyond disease diagnosis
636(2)
4.1 Insights into metastatic progression of cancer
636(2)
4.2 Personalized cancer therapy and response monitoring
638(1)
5 Cellular analysis using linear and nonlinear Raman imaging
638(6)
6 Surface enhanced Raman spectroscopy
644(2)
7 Concluding remarks
646(1)
References
646(7)
Index 653
Professor V.P. Gupta, born in December 30, 1942, obtained Ph.D. degree from Moscow, USSR, in 1967. He has been Professor Emeritus and also the Principal Investigator of DST Book-Writing Project under USERS (Utilization of Scientific Expertise of Retired Scientists) scheme at the University of Lucknow, Lucknow. Professor Gupta has 45 years of experience in teaching and research at several universities. He has been Professor and Chairman of the Department of Physics at the University of Jammu, Jammu-Tawi, India, a Visiting Professor of Chemistry at the Université de Provence, Marseilles, France and Professor of Physics at the University of Calabar, Nigeria. He has the distinction of being Professor Emeritus, University Grants Commission (UGC), India, and Emeritus scientist of the Council of Scientific & Industrial Research (CSIR), India, and the All India Council of Technical Education (AICTE), New Delhi, India. He was a visiting scientist/fellow at the University of Helsinki, Helsinki, Finland, and at International Centre for Theoretical Physics, Trieste, Italy; and a member of several national and international academic bodies. Over the past four decades, he has successfully executed several major and minor scientific research projects granted by the national funding agencies such as Department of Science & Technology (DST), Government of India, New Delhi; UGC, New Delhi; CSIR, New Delhi; AICTE, New Delhi; and Indian Space Research Organization (ISRO), Bangalore. His major areas of research are molecular spectroscopy and molecular structure, quantum chemistry, matrix isolation infrared studies, astrochemistry, and laser spectroscopy. He has to his credit 99 research publications and 3 books, including the book published by Elsevier Inc. (Waltham, United States - Academic Press), in October 2015. Dr. Ozaki received his B.Sc. in Chemistry in 1973 and PhD in Physical and Inorganic Chemistry in 1978, both from Osaka University. After over two years at the National Research Council of Canada as a research associate, he joined Jikei University School of Medicine in Tokyo. In 1989, he became associate professor and later full professor in the Chemistry Department at Kwansei Gakuin University until March 2018. He was a Vice President of Kwansei Gakuin University from April 2013 to March 2018. Currently Professor Ozaki is a professor emeritus of Kwansei Gakuin University. Ozaki has received many awards, including the 1998 Tomas Hirschfeld Award, 2001 EAS Award for Achievements in Near Infrared Spectroscopy, 2002 Spectroscopical Society of Japan Award, 2005 Science and Technology Award of Japanese Government, 2008 Japan Society for Analytical Chemistry Award, 2014 Bomem-Michelson Award, 2017 Chemical Society of Japan Award, and the 2018 Medal with Purple Ribbon.
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