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New Theories for Chemistry [Kietas viršelis]

(Department of Chemistry, University of Pretoria, Pretoria, South Africa)
  • Formatas: Hardback, 292 pages, aukštis x plotis: 240x165 mm, weight: 680 g
  • Išleidimo metai: 28-Apr-2005
  • Leidėjas: Elsevier Science Ltd
  • ISBN-10: 0444518673
  • ISBN-13: 9780444518675
Kitos knygos pagal šią temą:
New Theories for ChemistryDidesnis paveikslėlis
  • Formatas: Hardback, 292 pages, aukštis x plotis: 240x165 mm, weight: 680 g
  • Išleidimo metai: 28-Apr-2005
  • Leidėjas: Elsevier Science Ltd
  • ISBN-10: 0444518673
  • ISBN-13: 9780444518675
Kitos knygos pagal šią temą:
Pastovi nuoroda: https://www.kriso.lt/db/9780444518675.html
Raktažodžiai:
Many new developments, related to the interpretation and importance of symmetry relationships, quantum mechanics, general relativity, field theory and mathematics have occurred in the second half of the 20th century without having a visible impact on chemical thinking. By re-examining basic theories, The New Theories for Chemistry aims to introduce a new understanding of old concepts, such as electron spin, The Periodic Table and electronegativity. The book focuses on the new mathematical concepts that enable the exploration of interactions between particles, waves and fields within a chemical context, and is packed with examples to support its arguments. The author adopts a practical approach and topics are arranged sequentially, from the mathematical basis through to general concepts. An essential reference source, this book is suitable for physicists, theoretical and physical chemists, as well as students and researchers working in the field.

* Re-examines basic theories, such as electronegativity and electron spin, and introduces new theory
* Full of practical experiments and examples
* Is an excellent single reference source

Recenzijos

"The book is recommended for theoretical chemists, graduate level and up, and possibly for very advanced undergraduates." --Choice

Daugiau informacijos

An exciting look at the new theories of chemistry
Preface v
1 The Symmetry Laws of Nature 1(38)
1.1 Introduction
1(1)
1.2 Group Theory and Symmetry
2(5)
1.2.1 Continuous Space-Time Symmetries
4(1)
1.2.2 Discrete Space-Time Symmetries
5(1)
1.2.3 Permutation Symmetry
6(1)
1.2.4 Gauge Invariance and Internal Symmetry
6(1)
1.3 Symmetry and the Laws of Nature
7(5)
1.3.1 Conservation Laws
9(2)
1.3.2 Reversal Invariances
11(1)
1.4 Quantum Theory and Symmetry
12(5)
1.4.1 Symmetry of the Hamiltonian
15(1)
1.4.2 Quantum Invariances
15(2)
1.5 Field Symmetries
17(8)
1.5.1 Noether's Theorem
19(3)
1.5.2 Symmetry Breaking
22(3)
1.6 Symmetry in Theories
25(14)
1.6.1 Continuous Translational Symmetry
26(2)
1.6.2 Continuous Rotational Symmetry
28(1)
1.6.3 Discrete Rotational Symmetry
29(1)
1.6.4 Lattice Translations
29(4)
1.6.5 Crystallographic Symmetry
33(3)
1.6.6 The 230 Space Groups
36(1)
1.6.7 Internal Symmetry
37(1)
1.6.8 Broken Symmetry
38(1)
2 Mathematical Structures in Chemistry 39(20)
2.1 Introduction
39(2)
2.2 Number Theory
41(2)
2.2.1 Number Spiral and Periodicity
42(1)
2.3 Periodic Laws
43(3)
2.4 Atomic and Nuclear Structure
46(10)
2.4.1 Physical Interpretation
47(2)
2.4.2 The Number Pattern
49(1)
2.4.3 The Farey Sequence
50(3)
2.4.4 A Golden Parabola
53(1)
2.4.5 Periodic Symmetry
54(2)
2.5 Space-Time Structure
56(3)
3 Bohmian Mechanics 59(30)
3.1 Historical Introduction
59(3)
3.2 The Quantum Limit
62(3)
3.3 The Ontological Interpretation
65(4)
3.3.1 Hydrodynamic Analogy
67(1)
3.3.2 Theory of Measurement
68(1)
3.4 Nonlocality
69(8)
3.4.1 The EPR Effect
70(3)
3.4.2 Bell's Inequality
73(2)
3.4.3 Entanglement
75(2)
3.5 Stationary States
77(2)
3.6 Angular Momentum
79(7)
3.6.1 Bohmian Interpretation
81(5)
3.7 Chemical Significance
86(3)
4 Structure of the Electron 89(40)
4.1 Introduction
89(1)
4.2 Historical Development
90(2)
4.3 The Quantum View
92(4)
4.3.1 Hole theory
93(1)
4.3.2 Zitterbewegung
94(2)
4.4 Distortion of Space
96(3)
4.5 Wave Model of the Electron
99(5)
4.6 Electronic Charge
104(4)
4.6.1 Kaluza-Klein Theory
105(3)
4.7 Geometrical Model of the Electron
108(10)
4.7.1 Electron Spin
113(5)
4.8 The Real Electron
118(5)
4.9 Electronic Interactions
123(5)
4.10 Chemical Aspects
128(1)
5 Chemical Concepts 129(48)
5.1 Introduction
129(1)
5.2 The Chemical Problem
130(1)
5.3 Compressed Atoms
130(4)
5.3.1 Particle on a Sphere
131(1)
5.3.2 Ionization Radii
132(2)
5.4 Molecular Cohesion
134(1)
5.5 The Valence State
135(2)
5.6 Electronegativity
137(5)
5.6.1 Ontological Interpretation
140(1)
5.6.2 Absolute Electronegativities
140(2)
5.7 Chemical Equilibrium
142(7)
5.7.1 Entropy
145(4)
5.8 Chemical Reaction
149(2)
5.8.1 The Chemistry of Atoms
151(1)
5.9 Chemical Bonding
151(13)
5.9.1 Electrostatic Model
152(2)
5.9.2 The Heitler-London Method
154(5)
5.9.3 Multiple Bonding
159(5)
5.10 The Chemical Vacuum
164(13)
5.10.1 Crystal Nucleation and Growth
166(6)
5.10.2 Entropy and the Arrow of Time
172(2)
5.10.3 Chirality
174(3)
6 Molecular Structure 177(52)
6.1 Introduction
177(1)
6.2 Conventional Theory
178(9)
6.2.1 The Chemical Bond
178(6)
6.2.2 The Valence Shell
184(3)
6.3 Experimental Study of Molecular Structure
187(13)
6.3.1 Diffraction Methods
187(4)
6.3.2 Spectroscopy
191(1)
6.3.3 Theoretical Analysis
192(1)
6.3.4 Charge Density
193(1)
6.3.5 Atoms in Molecules
194(3)
6.3.6 Chiral Structures and States
197(3)
6.4 Molecular Conformation
200(16)
6.4.1 Barriers to Rotation
201(3)
6.4.2 Molecular Shape
204(1)
6.4.3 The Shape of Simple Molecules
204(7)
6.4.4 The Role of Screening
211(2)
6.4.5 Molecular Geometry
213(1)
6.4.6 Nature of the Chemical Bond
214(1)
6.4.7 Optical Activity
215(1)
6.5 Conformational Analysis
216(13)
6.5.1 The Conformation of Cyclic Fragments
219(5)
6.5.2 Molecular Shape Descriptors
224(5)
7 The Chemical World 229(28)
7.1 Introduction
229(1)
7.2 Five-dimensional Space-time
230(7)
7.2.1 The Thierrin Model
233(4)
7.3 Topology of World Space
237(8)
7.3.1 Space-time Geometry
238(3)
7.3.2 Topology
241(2)
7.3.3 World Space
243(2)
7.4 The Geometry of Quantum Events
245(5)
7.4.1 The Quantum Potential
247(1)
7.4.2 Antimatter
248(1)
7.4.3 Quantum Effects
248(2)
7.5 Chemical Effects
250(7)
7.5.1 Interfacial Equilibrium
251(2)
7.5.2 Non-local Interaction
253(4)
Bibliography 257(9)
Index 266