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El. knyga: Organic Coatings: Science and Technology

(Eastern Michigan University), , (Polychrome Corporation)
  • Formatas: PDF+DRM
  • Išleidimo metai: 30-Aug-2017
  • Leidėjas: John Wiley & Sons Inc
  • Kalba: eng
  • ISBN-13: 9781119337157
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Organic Coatings: Science and TechnologyDidesnis paveikslėlis
  • Formatas: PDF+DRM
  • Išleidimo metai: 30-Aug-2017
  • Leidėjas: John Wiley & Sons Inc
  • Kalba: eng
  • ISBN-13: 9781119337157
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The definitive guide to organic coatings, thoroughly revised and updated—now with coverage of a range of topics not covered in previous editions

Organic Coatings: Science and Technology, Fourth Edition offers unparalleled coverageof organic coatings technology and its many applications. Written by three leading industry experts (including a new, internationally-recognized coatings scientist) it presents a systematic survey of the field, revises and updates the material from the previous edition, and features new or additional treatment of such topics as superhydrophobic, ice-phobic, antimicrobial, and self-healing coatings; sustainability, artist paints, and exterior architectural primers. making it even more relevant and useful for scientists and engineers in the field, as well as for students in coatings courses.

The book incorporates up-to-date coverage of recent developments in the field with detailed discussions of the principles underlying the technology and their applications in the development, production, and uses of organic coatings. All chapters in this new edition have been updated to assure consistency and to enable extensive cross-referencing. The material presented is also applicable to the related areas of printing inks and adhesives, as well as areas within the plastics industry.

This new edition

  • Completely revises outdated chapters to ensure consistency and to enable extensive cross-referencing
  • Correlates the empirical technology of coatings with the underlying science throughout
  • Provides expert troubleshooting guidance for coatings scientists and technologists
  • Features hundreds of illustrative figures and extensive references to the literature
  • A new, internationally-recognized coatings scientist brings fresh perspective to the content.

Providing a broad overview for beginners in the field of organic coatings and a handy reference for seasoned professionals, Organic Coatings: Science and Technology, Fourth Edition, gives you the information and answers you need, when you need them.

Preface xi
1 Introduction to Coatings
1(5)
1.1 Definitions and Scope
1(2)
1.2 Types of Coatings
3(1)
1.3 Composition of Coatings
3(1)
1.4 Coating History
4(1)
1.5 Commercial Considerations
5(1)
References
5(1)
2 Polymerization and Film Formation
6(23)
2.1 Polymers
6(7)
2.2 Polymerization
13(6)
2.3 Film Formation
19(10)
References
27(2)
3 Flow
29(17)
3.1 Shear Flow
29(1)
3.2 Types of Shear Flow
30(2)
3.3 Determination of Shear Viscosity
32(4)
3.4 Shear Viscosity of Resin Solutions
36(4)
3.5 Viscosity of liquids With Dispersed Phases
40(2)
3.6 Other Modes of Flow
42(4)
References
44(2)
4 Mechanical Properties
46(21)
4.1 Introduction
46(1)
4.2 Basic Mechanical Properties
46(11)
4.3 Fracture Mechanics
57(1)
4.4 Abrasion, Scratch, and Mar Resistance
58(3)
4.5 Measurement of Mechanical Properties
61(1)
4.6 Tests of Coatings on Substrates
62(5)
References
66(1)
5 Exterior Durability
67(19)
5.1 Photoinitiated Oxidative Degradation
67(3)
5.2 Photostabilization
70(5)
5.3 Degradation of Chlorinated Resins
75(1)
5.4 Hydrolytic Degradation
75(2)
5.5 Other Modes of Failure on Exterior Exposure
77(1)
5.6 Testing for Exterior Durability
78(6)
5.7 Service Life Prediction
84(2)
References
84(2)
6 Adhesion
86(13)
6.1 Mechanisms of Adhesion
86(3)
6.2 Mechanical Stresses and Adhesion
89(1)
6.3 Adhesion to Metal Surfaces
90(2)
6.4 Characterization of Surfaces
92(1)
6.5 Organic Chemical Treatment of Substrates to Enhance Adhesion
93(1)
6.6 Covalent Bonding to Glass and Metal Substrates
94(1)
6.7 Adhesion to Plastics and to Coatings
95(1)
6.8 Testing for Adhesion
96(3)
References
98(1)
7 Corrosion Protection by Coatings
99(16)
7.1 Corrosion Basics
99(1)
7.2 Corrosion of Uncoated Steel
100(1)
7.3 Corrosion Protection of Metals
101(2)
7.4 Corrosion Protection by Intact Coatings
103(4)
7.5 Corrosion Protection by Nonintact Films
107(4)
7.6 Evaluation and Testing
111(4)
References
113(2)
8 Acrylic Resins
115(10)
8.1 Thermoplastic Acrylic Resins
115(1)
8.2 Thermosetting Acrylic Resins
116(5)
8.3 Water-Reducible Thermosetting Acrylic Resins
121(4)
References
124(1)
9 Latexes
125(16)
9.1 Emulsion Polymerization
125(8)
9.2 Acrylic Latexes
133(2)
9.3 Vinyl Ester Latexes
135(2)
9.4 Thermosetting Latexes
137(4)
References
139(2)
10 Polyester Resins
141(10)
10.1 Hydroxy-Terminated Polyester Resins for Conventional Solids Coatings
142(4)
10.2 Polyester Resins for High Solids Coatings
146(1)
10.3 Carboxylic Acid-Terminated Polyester Resins
147(1)
10.4 Carbamate-Functional Polyester Resins
148(1)
10.5 Water-Reducible Polyester Resins
148(1)
10.6 Polyester Resins for Powder Coatings
149(2)
References
150(1)
11 Amino Resins
151(12)
11.1 Synthesis of Melamine--Formaldehyde Resins
151(3)
11.2 Types of MF Resins
154(1)
11.3 MF-Polyol Reactions in Coatings
155(6)
11.4 Other Amino Resins
161(2)
References
162(1)
12 Polyurethanes and Polyisocyanates
163(25)
12.1 Reactions of Isocyanates
164(1)
12.2 Kinetics of Reactions of Isocyanates with Alcohols
165(5)
12.3 Isocyanates Used in Coatings
170(3)
12.4 Two-Package (2K) Solventborne Urethane Coatings
173(3)
12.5 Blocked Isocyanates
176(5)
12.6 Moisture-Curable Urethane Coatings
181(1)
12.7 Waterborne Polyurethane Coatings
182(3)
12.8 Hydroxy-Terminated Polyurethanes
185(3)
References
186(2)
13 Epoxy and Phenolic Resins
188(17)
13.1 Epoxy Resins
188(5)
13.2 Amine Cross-Linked Epoxy Resins
193(6)
13.3 Other Cross-Linking Agents for Epoxy Resins
199(2)
13.4 Water-Reducible Epoxy/Aery lie Graft Copolymers: Epoxy/Acrylic Hybrids
201(1)
13.5 Epoxy Resin Phosphate Esters
202(1)
13.6 Phenolic Resins
202(3)
References
204(1)
14 Drying Oils
205(8)
14.1 Compositions of Natural Oils
205(1)
14.2 Autoxidation and Cross-Linking
206(3)
14.3 Synthetic and Modified Drying Oils
209(4)
References
211(2)
15 Alkyd Resins
213(15)
15.1 Oxidizing Alkyds
214(3)
15.2 High Solids Oxidizing Alkyds
217(1)
15.3 Waterborne Oxidizing Alkyds
218(2)
15.4 Nonoxidizing Alkyds
220(1)
15.5 Synthetic Procedures for Alkyd Resins
220(3)
15.6 Modified Alkyds
223(1)
15.7 Uralkyds and Other Autoxidizable Urethanes
224(1)
15.8 Epoxy Esters
225(3)
References
226(2)
16 Silicon Derivatives
228(7)
16.1 Silicones
228(4)
16.2 Reactive Silanes
232(1)
16.3 Orthosilicates
233(2)
References
234(1)
17 Other Resins and Cross-Linkers
235(11)
17.1 Halogenated Polymers
235(2)
17.2 Cellulose Derivatives
237(1)
17.3 Unsaturated Polyester Resins
238(2)
17.4 (Meth)Acrylated Oligomers
240(1)
17.5 2-Hydroxyalkylamide Cross-Linkers
240(1)
17.6 Acetoacetate Cross-Linking Systems
241(1)
17.7 Polyaziridine Cross-Linkers
242(1)
17.8 Polycarbodiimide Cross-Linkers
242(1)
17.9 Polycarbonates
243(1)
17.10 Non-Isocyanate Two-Package Binders
243(1)
17.11 Dihydrazides
244(2)
References
244(2)
18 Solvents
246(21)
18.1 Solvent Composition
246(1)
18.2 Solubility
247(4)
18.3 Solvent Evaporation Rates
251(6)
18.4 Viscosity Effects
257(1)
18.5 Flammability
258(1)
18.6 Other Physical Properties
259(1)
18.7 Toxic Hazards
259(1)
18.8 Atmospheric Photochemical Effects
260(2)
18.9 Regulation of Solvent Emissions from Coatings
262(5)
References
265(2)
19 Color and Appearance
267(26)
19.1 Light
267(1)
19.2 Light-Object Interactions
268(6)
19.3 Hiding
274(1)
19.4 Metallic and Interference Colors
275(1)
19.5 The Observer
276(1)
19.6 Interactions of Light Source, Object, and Observer
277(1)
19.7 Color Systems
277(4)
19.8 Color Mixing
281(1)
19.9 Color Matching
281(5)
19.10 Gloss
286(7)
References
292(1)
20 Pigments
293(14)
20.1 White Pigments
293(3)
20.2 Color Pigments
296(6)
20.3 Inert Pigments
302(1)
20.4 Functional Pigments
303(1)
20.5 Nano-Pigments
304(3)
References
305(2)
21 Pigment Dispersion
307(16)
21.1 Dispersion in Organic Media
307(4)
21.2 Formulation of Nonaqueous Mill Bases
311(2)
21.3 Dispersion in Aqueous Media
313(2)
21.4 Dispersion Equipment and Processes
315(5)
21.5 Evaluation of Dispersions
320(3)
References
322(1)
22 Effect of Pigments on Coating Properties
323(8)
22.1 PVC and CPVC
323(3)
22.2 Relationships Between Film Properties and PVC
326(5)
References
330(1)
23 Application Methods
331(11)
23.1 Brushes, Pads, and Hand Rollers
331(1)
23.2 Spray Application
332(6)
23.3 Dip and How Coating
338(1)
23.4 Roll Coating
339(1)
23.5 Curtain Coating
340(2)
References
341(1)
24 Film Defects
342(15)
24.1 Surface Tension
342(2)
24.2 Leveling
344(2)
24.3 Sagging and Drip Marks
346(2)
24.4 Crawling, Cratering, and Related Defects
348(3)
24.5 Floating and Flooding: Hammer Finishes
351(1)
24.6 Wrinkling: Wrinkle Finishes
352(1)
24.7 Bubbling and Popping
353(1)
24.8 Foaming
354(1)
24.9 Dirt
355(2)
References
355(2)
25 Solventborne and High Solids Coatings
357(9)
25.1 Primers
358(2)
25.2 Top Coats
360(6)
References
365(1)
26 Waterborne Coatings
366(8)
26.1 Water-Reducible Coatings
367(2)
26.2 Latex-based Coatings
369(2)
26.3 Emulsion Coatings
371(3)
References
372(2)
27 Electrodeposition Coatings
374(11)
27.1 Anionic Electrodeposition Coatings
375(1)
27.2 Cationic Electrodeposition Coatings
376(2)
27.3 Effect of Variables on Electrodeposition
378(2)
27.4 Application of Electrodeposition Coatings
380(1)
27.5 Advantages and Disadvantages of Electrodeposition
381(2)
27.6 Autodeposition Coatings
383(2)
References
383(2)
28 Powder Coatings
385(18)
28.1 Binders for Thermosetting Powder Coatings
385(5)
28.2 Binders for Thermoplastic Powder Coatings
390(1)
28.3 Formulation of Thermosetting Powder Coatings
391(3)
28.4 Manufacture of Powder Coatings
394(2)
28.5 Application Methods
396(4)
28.6 Advantages and Limitations
400(3)
References
401(2)
29 Radiation Cure Coatings
403(16)
29.1 UV Curing
404(2)
29.2 Free Radical-Initiated UV Cure
406(6)
29.3 Cationic UV Cure
412(1)
29.4 Hybrid Free Radical/Cationic Polymerization
413(1)
29.5 Effects of Pigmentation
414(1)
29.6 Electron Beam Cure Coatings
415(1)
29.7 Dual UV/Thermal Cure
415(1)
29.8 Selected Applications
416(1)
29.9 Advantages, Disadvantages, and Selected Advances
416(3)
References
418(1)
30 Product Coatings for Metal Substrates
419(19)
30.1 OEM Automotive Coatings
419(8)
30.2 Appliance Coatings
427(1)
30.3 Container Coatings
427(4)
30.4 Coil Coating
431(4)
30.5 Coatings for Aircraft
435(3)
References
436(2)
31 Product Coatings for Nonmetallic Substrates
438(11)
31.1 Coatings for Wood
438(6)
31.2 Coating of Plastics
444(5)
References
448(1)
32 Architectural Coatings
449(15)
32.1 Exterior House Paints and Primers
450(5)
32.2 Flat and Semigloss Interior Paints
455(4)
32.3 Gloss Enamels
459(5)
References
463(1)
33 Special Purpose Coatings
464(16)
33.1 Maintenance Paints
464(7)
33.2 Marine Coatings
471(3)
33.3 Automobile Refinish Paints
474(3)
33.4 Traffic Striping Paints
477(3)
References
478(2)
34 Functional Coatings
480(8)
34.1 Superhydrophobic and Superhydrophilic Coatings
480(3)
34.2 Ice-Phobic Coatings
483(1)
34.3 Self-Healing Coatings
484(1)
34.4 Environmentally Sensing Coatings
485(1)
34.5 Antimicrobial Coatings
486(2)
References
486(2)
Index 488
FRANK N. JONES is a consultant and an Emeritus Professor at Eastern Michigan University, where he was Director, of the National Science Foundation Industry/University Cooperative Research Center in Coatings. Previously he was Professor and Chair of the Department of Polymers and Coatings at North Dakota State University.

MARK E. NICHOLS is currently Technical Leader, Paint and Corrosion Research at the Ford Motor Company and the Editor-in-Chief of the Journal of Coatings Technology and Research. He is the recipient of the Industry Excellence Award from the ACA as well as a Roon Award.

SOCRATES PETER PAPPAS is a consultant. Previously he was Corporate Scientist at Kodak Polychrome Graphics, Director of Chemical Imaging at Polychrome Corporation, Scientific Fellow at Loctite Corporation, and Professor at North Dakota State University in the Departments of Chemistry, as well as Polymers and Coatings.
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