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Organophosphorus Chemistry: Volume 49 [Kietas viršelis]

Edited by (Sheffield Hallam University, UK), Edited by (Sheffield Hallam University, UK), Edited by (Newcastle University, UK), Edited by (University of Cambridge, UK)
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This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds, from phosphines and related P-C bonded compounds to phosphorus acids, phosphine chalcogenides and nucleotides. The Editors have added to the content with a timely chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect current interests in the area. This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds, from phosphines and related P-C bonded compounds to phosphorus acids, phosphine chalcogenides and nucleotides. The Editors have added to the content with a timely chapter on the recent developments in green synthetic approaches in organophosphorus chemistry to reflect current interests in the area. With an emphasis on interdisciplinary content, this book is aimed at the worldwide organic chemistry and engineering research communities.

This annual review of the literature presents a comprehensive and critical survey of the vast field of study involving organophosphorus compounds and includes a chapter on the recent developments in green synthetic approaches in this area to reflect current interests.
Preface v
David Allen
David Loakes
Lee Higham
John Tebby
Tertiary phosphines: preparation and reactivity
1(63)
E. I. Musina
A. V. Shamsieva
A. S. Balueva
A. A. Karasik
1 Introduction
1(1)
2 Preparation of phosphines
1(38)
3 Reactivity of phosphines
39(12)
References
51(13)
Phosphine chalcogenides
64(46)
G. Keglevich
References
105(5)
Tervalent phosphorus acid derivatives
110(38)
Mariette M. Pereira
Rui M. B. Carrilho
Sara M. A. Pinto
Mario J. F. Calvete
1 Introduction
110(1)
2 Tervalent phosphorus amides
110(13)
3 Tervalent phosphorus esters
123(20)
4 Mixed phosphorus(III) compounds
143(1)
References
143(5)
Phosphonium salts and P-ylides
148(50)
Maurizio Selva
Alvise Perosa
Giulia Fiorani
1 Introduction
148(1)
2 Phosphonium salts
148(12)
3 Phosphonium based ionic liquids (PILs)
160(23)
4 P-ylides (phosphoranes)
183(6)
References
189(9)
Quinquevalent phosphorus acids
198(134)
Piotr Balczewski
Joanna Wilk
1 Introduction
198(1)
2 Phosphoric acids and their derivatives
199(44)
3 Phosphonic acids and their derivatives
243(62)
4 Phosphinic acids and their derivatives
305(9)
5 Quinquevalent phosphorus acids and their derivatives as catalysts
314(3)
Acknowledgements
317(1)
References
317(15)
Pentacoordinated and hexacoordinated compounds
332(17)
Romana Pajkert
Gerd-Volker Roschenthaler
1 Introduction
332(1)
2 Pentacoordinated phosphorus compounds
332(9)
3 Hexacoordinated phosphorus compounds
341(7)
References
348(1)
Phosphazenes
349(28)
Vadapalli Chandrasekhar
Amit Chakraborty
1 Introduction
349(1)
2 Acyclic phosphazenes
349(9)
3 Cyclophosphazenes
358(8)
4 Polyphosphazenes and related polymers
366(6)
References
372(5)
Green synthetic approaches in organophosphorus chemistry: recent developments
377(9)
Goutam Brahmachari
1 Introduction
377(1)
2 Recent developments in green synthetic approaches in organophosphorus chemistry
378(7)
3 Conclusions
385(1)
Acknowledgements 386(1)
References 386
Professor David Allen is Emeritus professor of chemistry at the Sheffield Hallam University, UK. His main research interests are in phosphonium salts and related compounds. Current interests include the preparation of phosphonioalkyl derivatives of biologically active molecules, the phosphonioalkyl group facilitating the passage of the biologically active agent through cell membranes, and studies of the formation of biologically active surface-functionalised gold nanoparticles.