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1 Phase Equilibria: The Phase Rule |
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12 | (16) |
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1 | (1) |
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1.2 Terms used in Phase Rule |
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2 | (4) |
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2 | (1) |
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3 | (2) |
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1.2.3 Degrees of Freedom or Variability of a System |
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5 | (1) |
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1.3 Advantages of Phase Rule |
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6 | (1) |
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1.4 Limitations of Phase Rule |
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6 | (1) |
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1.5 Derivation of Phase Rule |
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6 | (22) |
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1.5.1 Phase Rule for a Non-Reactive System |
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6 | (2) |
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1.5.2 Phase Rule for a Reactive System |
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8 | (1) |
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1.5.3 Phase Rule when One of the Component is Missing from One Phase [ One of the Component is present only in (P -- 1) Phases] |
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9 | (19) |
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28 | (34) |
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13 | (1) |
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14 | (1) |
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2.3 Applications of Clapeyron Equation |
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15 | (4) |
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2.4 Construction of Phase Diagram of one component systems |
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19 | (1) |
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2.5 Phase Diagram of one component systems |
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20 | (42) |
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2.5.1 Phase Diagram of Water |
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20 | (4) |
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2.5.2 Phase Diagram of Carbon dioxide System |
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24 | (1) |
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2.5.3 Phase Diagram of Sulphur |
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25 | (37) |
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62 | (17) |
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29 | (1) |
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3.2 Types of Phase Diagrams in Two Component Systems |
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29 | (1) |
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30 | (2) |
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3.3.1 Cooling Curve of a Pure Component |
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31 | (1) |
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3.3.2 Cooling Curve of a Mixture |
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31 | (1) |
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3.4 Construction of Phase Diagrams of Two Component Systems |
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32 | (2) |
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33 | (1) |
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3.5 Phase Diagram of Two Component Systems: Type A |
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34 | (20) |
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3.5.1 Only the Pure Components Crystallise from the Solution-Simple Eutectic Diagram |
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34 | (4) |
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3.5.2 The Pure Components Crystallise from the Solution and One of the Solid Exists in more than One Crystalline Form |
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38 | (2) |
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3.5.3 A Solid Compound Stable upto its Melting Point is Formed by Two Constituents |
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40 | (4) |
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3.5.4 A Solid Compound Decomposes before it reaches its Melting Point is Formed by Two Constituents |
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44 | (3) |
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3.5.5 The Two Components are Completely Miscible in the Solid Phase and Form a Series of Solid Solutions |
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47 | (3) |
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3.5.6 In the Solid State, the Two Constituents are Partially Miscible and Form Stable Solid Solutions |
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50 | (2) |
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3.5.7 Solid Solutions Formed by Two Constituents and are Stable only upto a Transition Point |
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52 | (2) |
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3.6 Phase Diagram of Two component Systems: Type B |
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54 | (2) |
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3.6.1 The Two components are Partially Miscible in the Liquid Phase and Only Pure Components Crystallise from the Solution |
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54 | (2) |
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3.7 Phase Diagram of Two Component Systems: Type C |
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56 | (23) |
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3.7.1 Formation of Simple Eutectic or Cryohydrates |
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56 | (2) |
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3.7.2 Formation of Compounds (Hydrates) with Congruent Melting Points |
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58 | (1) |
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3.7.3 Formation of Compounds (Hydrates) with Incongruent Melting Points |
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59 | (20) |
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79 | (8) |
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63 | (2) |
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4.2 Systems with Lower Critical Solution Temperature (LCST) |
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65 | (1) |
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4.3 Systems having both Upper and Lower CST |
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66 | (1) |
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4.4 Effect of Pressure on CST |
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66 | (1) |
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4.5 Effect of Impurities on CST |
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67 | (1) |
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4.6 Vapour Pressure-Composition and Boiling Point-Composition Curves of Completely Miscible Binary Solutions |
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67 | (2) |
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4.7 Fractional Distillation of Binary Miscible Liquids |
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69 | (4) |
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4.8 Distillation of Immiscible Liquids |
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73 | (1) |
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4.9 Duhem-Margules Equation |
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74 | (4) |
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4.9.1 Ideal Solutions and the Duhem-Margules Equation |
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76 | (1) |
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4.9.2 Non-Ideal Solutions and the Duhem-Margules Equation |
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77 | (1) |
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78 | (9) |
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5 Three Component Systems (C = 3) |
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87 | (57) |
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81 | (1) |
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5.2 Graphical Representation |
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81 | (3) |
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5.2.1 Method of Calculating the Composition of Each Component |
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82 | (1) |
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5.2.2 Location of the Point within the Triangle when Composition of Each Component is Known |
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83 | (1) |
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5.3 Systems Consisting of Three Liquid Components Exhibiting Partial Miscibility |
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84 | (60) |
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5.3.1 Formation of One Pair of Partially Miscible Liquids |
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84 | (2) |
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5.3.2 Formation of Two Pairs of Partially Miscible Liquids |
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86 | (1) |
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5.3.3 Formation of Three Pairs of Partially Miscible Liquids |
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87 | (57) |
Solved Problems Based on Phase Rule |
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144 | (6) |
Experiment on Phase Diagram |
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150 | (2) |
Index |
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152 | |