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Phase Rule and Its Applications [Kietas viršelis]

  • Formatas: Hardback, 152 pages, aukštis x plotis: 234x156 mm, weight: 380 g, 23 Tables, black and white; 87 Line drawings, black and white; 87 Illustrations, black and white
  • Išleidimo metai: 02-Jun-2022
  • Leidėjas: CRC Press
  • ISBN-10: 1032283068
  • ISBN-13: 9781032283067
Kitos knygos pagal šią temą:
  • Formatas: Hardback, 152 pages, aukštis x plotis: 234x156 mm, weight: 380 g, 23 Tables, black and white; 87 Line drawings, black and white; 87 Illustrations, black and white
  • Išleidimo metai: 02-Jun-2022
  • Leidėjas: CRC Press
  • ISBN-10: 1032283068
  • ISBN-13: 9781032283067
Kitos knygos pagal šią temą:

The book covers the fundamental concepts of phases, phase diagrams and their applications. Stress is on understanding and not on memorization. The book has descriptive passages and diagrams (cooling curves) that help students gain a solid foundation in subject. This text will help them learn phase rule faster. It also contains numerous phase diagrams.

Note: T& F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.



The book covers the fundamental concepts of phases, phase diagrams and their applications.  The book has descriptive passages and diagrams (cooling curves) that help students gain a solid foundation in subject.

Note: T& F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.

1 Phase Equilibria: The Phase Rule
12(16)
1.1 Introduction
1(1)
1.2 Terms used in Phase Rule
2(4)
1.2.1 Phase
2(1)
1.2.2 Components
3(2)
1.2.3 Degrees of Freedom or Variability of a System
5(1)
1.3 Advantages of Phase Rule
6(1)
1.4 Limitations of Phase Rule
6(1)
1.5 Derivation of Phase Rule
6(22)
1.5.1 Phase Rule for a Non-Reactive System
6(2)
1.5.2 Phase Rule for a Reactive System
8(1)
1.5.3 Phase Rule when One of the Component is Missing from One Phase [ One of the Component is present only in (P -- 1) Phases]
9(19)
2 One Component Systems
28(34)
2.1 Introduction
13(1)
2.2 Clapeyron Equation
14(1)
2.3 Applications of Clapeyron Equation
15(4)
2.4 Construction of Phase Diagram of one component systems
19(1)
2.5 Phase Diagram of one component systems
20(42)
2.5.1 Phase Diagram of Water
20(4)
2.5.2 Phase Diagram of Carbon dioxide System
24(1)
2.5.3 Phase Diagram of Sulphur
25(37)
3 Two Component Systems
62(17)
3.1 Introduction
29(1)
3.2 Types of Phase Diagrams in Two Component Systems
29(1)
3.3 Thermal Analysis
30(2)
3.3.1 Cooling Curve of a Pure Component
31(1)
3.3.2 Cooling Curve of a Mixture
31(1)
3.4 Construction of Phase Diagrams of Two Component Systems
32(2)
3.4.1 Lever Rule
33(1)
3.5 Phase Diagram of Two Component Systems: Type A
34(20)
3.5.1 Only the Pure Components Crystallise from the Solution-Simple Eutectic Diagram
34(4)
3.5.2 The Pure Components Crystallise from the Solution and One of the Solid Exists in more than One Crystalline Form
38(2)
3.5.3 A Solid Compound Stable upto its Melting Point is Formed by Two Constituents
40(4)
3.5.4 A Solid Compound Decomposes before it reaches its Melting Point is Formed by Two Constituents
44(3)
3.5.5 The Two Components are Completely Miscible in the Solid Phase and Form a Series of Solid Solutions
47(3)
3.5.6 In the Solid State, the Two Constituents are Partially Miscible and Form Stable Solid Solutions
50(2)
3.5.7 Solid Solutions Formed by Two Constituents and are Stable only upto a Transition Point
52(2)
3.6 Phase Diagram of Two component Systems: Type B
54(2)
3.6.1 The Two components are Partially Miscible in the Liquid Phase and Only Pure Components Crystallise from the Solution
54(2)
3.7 Phase Diagram of Two Component Systems: Type C
56(23)
3.7.1 Formation of Simple Eutectic or Cryohydrates
56(2)
3.7.2 Formation of Compounds (Hydrates) with Congruent Melting Points
58(1)
3.7.3 Formation of Compounds (Hydrates) with Incongruent Melting Points
59(20)
4 Solutions
79(8)
4.1 Introduction
63(2)
4.2 Systems with Lower Critical Solution Temperature (LCST)
65(1)
4.3 Systems having both Upper and Lower CST
66(1)
4.4 Effect of Pressure on CST
66(1)
4.5 Effect of Impurities on CST
67(1)
4.6 Vapour Pressure-Composition and Boiling Point-Composition Curves of Completely Miscible Binary Solutions
67(2)
4.7 Fractional Distillation of Binary Miscible Liquids
69(4)
4.8 Distillation of Immiscible Liquids
73(1)
4.9 Duhem-Margules Equation
74(4)
4.9.1 Ideal Solutions and the Duhem-Margules Equation
76(1)
4.9.2 Non-Ideal Solutions and the Duhem-Margules Equation
77(1)
4.10 Konovalov's Rule
78(9)
5 Three Component Systems (C = 3)
87(57)
5.1 Introduction
81(1)
5.2 Graphical Representation
81(3)
5.2.1 Method of Calculating the Composition of Each Component
82(1)
5.2.2 Location of the Point within the Triangle when Composition of Each Component is Known
83(1)
5.3 Systems Consisting of Three Liquid Components Exhibiting Partial Miscibility
84(60)
5.3.1 Formation of One Pair of Partially Miscible Liquids
84(2)
5.3.2 Formation of Two Pairs of Partially Miscible Liquids
86(1)
5.3.3 Formation of Three Pairs of Partially Miscible Liquids
87(57)
Solved Problems Based on Phase Rule 144(6)
Experiment on Phase Diagram 150(2)
Index 152
Suruchi, University of Delhi, Delhi, India

Sheza Zaidi, University of Delhi, Delhi, India