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El. knyga: Physico-Chemical Principles for Processing of Oligomeric Blends

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Supplies engineers and technologists with quantitative approaches to preparing liquid oligomeric compositions and choosing proper operating conditions for processing them into materials or articles. Synthesizing recent theoretical and experimental studies, Mezhikovskii (chemical physics, Russian Academy of Sciences, Moscow) makes recommendations on the practical use of existing physico-chemical patterns, and concludes by looking at the physico-chemical aspects of processing, including analyzing the effect of composition ingredients on the final properties of materials. No index. Annotation c. by Book News, Inc., Portland, Or.
Introduction to the Series xi
Preface xiii
Introduction xvii
Oligomers and Characteristic of Oligomer Blends
1(20)
Oligomers: Terminology and Classification
1(10)
Oligomer Blends
11(3)
Structural Hierarchy
14(7)
Thermodynamics of Oligomer Systems
21(62)
Compatibility and Phase Equilibria in Oligomer Systems
21(7)
Phase Diagrams of Oligomer of Blends
28(4)
Influence of the Molecular Parameters of Components on Compatibility in Oligomer Blends
32(8)
Analysis of Thermodynamic Parameters
40(5)
Invariance of Phase Diagrams of Oligomer Blends
45(3)
Structural Inhomogeneity of Single-Phase Oligomer Blends
48(4)
Equilibrium in Single-Phase Oligomer Blends
52(2)
Equilibria and Morphology Control in Two-Phase Oligomer Blends
54(4)
Relationship Between the Structure and Technological Properties of Oligomer Blends
58(25)
Translational Diffusion
59(4)
Rotational Diffusion
63(4)
Adsorption on Solid Surfaces
67(2)
Viscosity
69(14)
Kinetics of Polymerization Reactions and Mechanisms of Structure Formation During the Cure of Oligomer Blends
83(60)
Curing Kinetics
83(4)
Curing of Reactive Oligomers
87(6)
Nucleation and Spinodal Mechanisms of Phase Separation
93(2)
Relationship Between the Curing Kinetics and the Multistage Character of Thermodynamic Equilibrium in Uncured Oligomer Blends
95(3)
Relationship Between the Curing Kinetics and the Phase Organization of Uncured Oligomer Blends
98(2)
Relationship Between the Curing Kinetics and the Supermolecular Organization of Uncured Oligomer Blends
100(4)
Curing Kinetics and Phase Transformations in Oligomer Blends
104(9)
Structure Formation During the Cure of Polymer-Oligomer Blends
113(10)
Curing of Single-Phase Blends
113(6)
Curing of Two-Phase Blends
119(4)
The Structure of Cured Oligomer Blends
123(20)
Physico-Chemical Aspects of Materials Science of Oligomer Blend Composites
143(54)
Principles of the Morphology Control
143(7)
Relationship Between the Morphology of Solid Composites and Their Mechanical Properties
150(8)
Control of Mechanical Properties
158(10)
Control of the Shear Viscosity and Other Technological Properties
168(2)
Influence of Additives on the Properties of Oligomer-Based Materials
170(27)
Fillers
170(8)
Activators and Inhibitors
178(8)
Nonreactive Plasticizers
186(11)
Conclusion 197
Semjon M Mezhikouski
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