Atnaujinkite slapukų nuostatas

Principles of Colloid and Surface Chemistry, Revised and Expanded 3rd edition [Kietas viršelis]

Edited by (Emeritus -Cal State Polytechnic University, Pomona, CA), Edited by (Consultant, Singapore, The Republic of Singapore)
  • Formatas: Hardback, 672 pages, aukštis x plotis: 254x178 mm, weight: 1900 g
  • Išleidimo metai: 18-Mar-1997
  • Leidėjas: CRC Press Inc
  • ISBN-10: 0824793978
  • ISBN-13: 9780824793975
Kitos knygos pagal šią temą:
  • Formatas: Hardback, 672 pages, aukštis x plotis: 254x178 mm, weight: 1900 g
  • Išleidimo metai: 18-Mar-1997
  • Leidėjas: CRC Press Inc
  • ISBN-10: 0824793978
  • ISBN-13: 9780824793975
Kitos knygos pagal šią temą:
This work aims to familiarize students with the fundamentals of colloid and surface science, from various types of colloids and colloidal phenomena, and classical and modern characterization/measurement techniques to applications of colloids and surface science in engineering, technology, chemistry, physics and biological and medical sciences. The Journal of Textile Studies proclaims "High praise from peers . . .contains valuable information on many topics of interest to food rheologists and polymer scientists [ The book] should be in the libraries of academic and industrial food research organizations" and Chromatographia describes the book as "an excellent textbook, excellently organised, clearly written and well laid out."

Recenzijos

"High praise from peers . . .contains valuable information on many topics of interest to food rheologists and polymer scientists. . ..should be in the libraries of academic and industrial food research organizations. " ---Journal of Texture Studies ". . .the treatment is unique. The most striking, perhaps, is the introduction of short 'vignettes. . ..' which expand on the main point being made in the text. This is a fine revision of a fine book. Highly recommended. " ---Journal of Dispersion Science and Technology ". . .an excellent textbook, excellently organised, clearly written and well laid out. " ---Chromatographia "Controlled release scientists will find the book of major help in solving problems related with diffusion, sedimentation, osmosis, dispersion, colloidal suspensions, light scattering, surface tension, double-layer theory, electronkinetic phenomena and colloidal stability. . ..Recommended. " ---Journal of Controlled Release

Preface to the Third Edition iii(4)
Acknowledgments vii(2)
Preface to the Second Edition ix(2)
Preface to the First Edition xi
1. colloid and Surface Chemistry: Scope and Variables
1(61)
1.1 Introduction
1(5)
1.2 The Importance of the Surface for Small Particles
6(4)
1.3 Classification of Colloids Based on Affinity to Carrier Fluid
10(4)
1.4 Concept of Stability of Colloidal Systems
14(5)
1.5 Some Physical Characteristics of Colloids
19(19)
1.6 Some Classical and Emerging Experimental Tools
38(18)
1.7 An Overview of the Book
56(1)
Review Questions
57(1)
References
57(2)
Problems
59(3)
2. Sedimentation and Diffusion and Their Equilibrium
62(43)
2.1 Introduction
62(3)
2.2 Sedimentation: Some Basic Considerations
65(2)
2.3 Gravitational Sedimentation
67(7)
2.4 Centrifugal Sedimentation
74(4)
2.5 Diffusion
78(7)
2.6 Brownian Motion and Diffusion
85(9)
2.7 The Random Coil and Random Walk Statistics
94(4)
2.8 Equilibrium Between Sedimentation and Diffusion
98(3)
Review Questions
101(1)
References
101(1)
Problems
102(3)
3. Solution Thermodynamis: Osmotic and Donnan Equilibria
105(40)
3.1 Introduction
105(3)
3.2 Osmotic Pressure: Thermodynamic Foundations
108(6)
3.3 Osmometry: Some Applications
114(6)
3.4 Statistical Foundations of Solution Thermodynamic
120(12)
3.5 Osmoticc Equilibrium in Charged Systems
132(7)
3.6 Some Applications of Osmotic Phenomena
139(1)
Review Questions
140(1)
References
141(1)
Problems
142(3)
4. The Rheology of Dispersions
145(48)
4.1 Introduction
145(3)
4.2 Newton's Law of Viscosity
148(2)
4.3 Concentric-Cylinder and Cone-and Plate Viscometers
150(4)
4.4 The Poiseuille Equation and Capillary Viscometers
154(4)
4.5 The Equation of Motion: The Navier-Stokes Equation
158(3)
4.6 Einstein's Theory of Viscosity of Dispersions
161(7)
4.7 Deviations from the Einstein Model
168(6)
4.8 Non-Newtonian Behavior
174(7)
4.9 Viscosity of Polymer Solutions
181(7)
Review Questions
188(1)
References
188(1)
Problems
189(4)
5. Static and Dynamic Light Scattering and Other Radiation Scattering
193(55)
5.1 Introduction
193(3)
5.2 Interaction of Radiation with Matter
196(6)
5.3 Scattering by Small Particles: Theory of Rayleigh Scattering
202(5)
5.4 Experimental Aspects of Light Scattering
207(6)
5.5 Extension to Larger Particles and to Intraparticle Interference Effects
213(10)
5.6 Interference Effects and Structure of Particles
223(6)
5.7 Scattering by Large, Absorbing Particles
229(7)
5.8 Dynamic Light Scattering
236(6)
Review Questions
242(1)
References
242(1)
Problems
244(4)
6. Surface Tension and Contact Angle: Application to pure Substances
248(49)
6.1 Introduction
248(3)
6.2 Surface Tension and Contact Angle: A First Look
251(4)
6.3 Thermodynamics of Surfaces: Surface Tension as Surface Free Energy
255(2)
6.4 Surface Tension: Implications for Curved Interfaces and Capillarity
257(4)
6.5 Effects of Curved Interfaces on Phase Equilibria and Nucleation: The Kelvin Equation
261(4)
6.6 Surface Tension and Contact Angle: Their Relation to Wetting and Spreading Phenomena
265(7)
6.7 Contact Angles: Some Complications
272(4)
6.8 Measuring Surface Tension and Contact Angle: Round Two
272(4)
6.9 Contact of Liquids with Porous Solids and Powders
276(7)
6.10 Molecular Interpretation of Surface Tension
283(3)
Review Questions
286(5)
References
291(2)
Problems
293(4)
7. Adsorption from Solution and Monolayer Formation
297(58)
7.1 Introduction
297(3)
7.2 Insoluble Monolayers: Spreading of Surfactants on Aqueous Surfaces
300(4)
7.3 Experimental Measurement of Film Pressure
304(4)
7.4 Results of Film Balance Studies
308(10)
7.5 Viscous Behavior of Two-Dimensional Phases
318(2)
7.6 Applications of Monolayers Concepts
320(3)
7.7 Adsorption from Solution: Thermodynamics
323(4)
7.8 The Gibbs Equation: Experimental Results
327(4)
7.9 Adsorption on Solid Surfaces
331(3)
7.10 Applications of Adsorption from Solution
338(5)
7.11 Adsorption in the Presence of an Applied Potential
343(5)
Review Questions
348(1)
Rerferences
348(1)
Problems
349(6)
8. Colloidal Structures in Surfactant Solutions: Association Colloids
355(50)
8.1 Introduction
355(2)
8.2 Surfactants in Solution: Experimental Observations and Models
357(5)
8.3 Structure of Micelles
362(5)
8.4 Molecular Architecture of Surfactants, Packing Considertions, and Shapes of Micelles
367(3)
8.5 Critical Micelle Concentration and the Thermodynamics of Micellization
370(5)
8.6 Solubilization
375(5)
8.7 Catalysis by Micelles
380(6)
8.8 Reverse Micelles
386(3)
8.9 Emulsions and Microemulsions
389(3)
8.10 Some Applications of Microemulsions
392(3)
8.11 Biological Membranes
395(3)
Review Questions
398(1)
References
399(1)
Problems
399(6)
9. Adsorption at Gas-Solid Interfaces
405(57)
9.1 Introduction
405(4)
9.2 Experimental and Theoretical Treatments of Adsorption: An Overview
409(4)
9.3 Thermodynamics of Adsorption: Phenomenological Perspective
413(6)
9.4 Thermodynamics of Adsorption: A Statistical Perspective
419(6)
9.5 Multilayer Adsorption: The Brunauer-Emmett-Teller Equation
425(8)
9.6 Energetics of Adsorption
433(3)
9.7 Adsorption in Porous Solids
436(3)
9.8 Adsorption on Crystal Surfaces
439(12)
9.9 Metal Surfaces and Heterogeneous Catalysis
451(4)
Review Questions
455(1)
References
456(1)
Problems
456(6)
10. van der Waals Forces
462(37)
10.1 Introduction
462(2)
10.2 van der Waals Forces and Their Importance in Colloid and Surface Chemistry
464(3)
10.3 Molecular Interactions and Power Laws
467(4)
10.4 Molecular Origians and the Macroscopic Implication of van der Waals Forces
471(8)
10.5 van der Waals Forces Between Large Particles and Over Large Distances
479(4)
10.6 Calculating van der Waals Forces Between Macroscopic Bodies
483(3)
10.7 Theories of van der Waals Forces Based on Bulk Properties
486(4)
10.8 Effect of the Medium on the van der Waals Attraction
490(5)
Review Questions
495(1)
References
495(1)
Problems
496(3)
11. The Electrical Double Layer and Double-Layer Interactions
499(35)
11.1 Introduction
499(3)
11.2 Surface Charges and Electrical Double Layer: Background
502(2)
11.3 The Capacitor Model of the Double Layer
504(4)
11.4 The Diffuse Double Layer: The Debye-Huckel Approximation
508(4)
11.5 The Debye-Huckel Approximation: Results
512(4)
11.6 The Electrical Double Layer: Gouy-Chapman Theory
516(4)
11.7 Overlapping Double Layers and Interparticle Repulsion
520(7)
11.8 "Not-Quite-Indifferent" Electrolytes: Stern Adsorption
527(3)
Review Questions
530(1)
References
530(1)
Problems
531(3)
12. Electrophoresis and Other Electrokinetic Phenomena
534(41)
12.1 Introduction
534(2)
12.2 Mobilities of Small Ions and Macroions Electric Fields: A Comparison
536(2)
12.3 Zeta Potential: Thick Electrical Double Layers
538(6)
Zeta Potential: Thin Electrical Double Layers
544(2)
12.5 Zeta Potential General Theory for Spherical Particles
546(4)
12.6 Electroosmosis
550(3)
12.7 Streaming Potential
553(2)
12.8 The Surface of Shear and Viscoelectric Effect
555(4)
12.9 Experimental Aspects of Electrophoresis
559(6)
12.10 Determining the Surface Change from Electrokinetic Measurments
565(2)
12.11 Applications of Electrokinetic Phenomena
567(3)
Review Questions
570(1)
References
570(1)
Problems
571(4)
13. Electrostatic and Polymer-Induced Colloid Stability
575(50)
13.1 Introduction
575(3)
13.2 Interparticle Forces and the Structure and Stability of Dispersions
578(7)
13.3 The Derjaguin-Landau-Verwey-Overbeek Theory of Colloid Stability
585(7)
13.4 Theory of Coagulation in Dilute Dispersions
592(12)
13.5 Polymer-Colloid Mixtures: A Phenomenological Perspective
604(6)
13.6 Polymer-Induced Forces
610(4)
13.7 Steric Stabilization: A Model for the Initial Encounter
614(5)
Review Questions
619(1)
References
620(1)
Problems
621(4)
Appendix A: Examples of Expansions Encountered in This Book 625(1)
Reference 625(1)
Appendix B: Units: CSS-SI Interconversions 626(1)
Reference 626(6)
Appendix C: Statistics of Discrete and Continuous Distributions of Data 631(7)
C.1 Introduction 631(1)
C.2 Discrete Distributions 631(3)
C.3 Theoretical Distributions Functions 634(1)
References 637(1)
Appendix D: List Worked-Out Examples 638(3)
Index 641
Paul C. Hiemenz, Raj Rajagopalan