Preface to the Third Edition |
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iii | (4) |
Acknowledgments |
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vii | (2) |
Preface to the Second Edition |
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ix | (2) |
Preface to the First Edition |
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xi | |
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1. colloid and Surface Chemistry: Scope and Variables |
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1 | (61) |
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1 | (5) |
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1.2 The Importance of the Surface for Small Particles |
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6 | (4) |
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1.3 Classification of Colloids Based on Affinity to Carrier Fluid |
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10 | (4) |
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1.4 Concept of Stability of Colloidal Systems |
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14 | (5) |
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1.5 Some Physical Characteristics of Colloids |
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19 | (19) |
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1.6 Some Classical and Emerging Experimental Tools |
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38 | (18) |
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1.7 An Overview of the Book |
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56 | (1) |
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57 | (1) |
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57 | (2) |
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59 | (3) |
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2. Sedimentation and Diffusion and Their Equilibrium |
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62 | (43) |
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62 | (3) |
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2.2 Sedimentation: Some Basic Considerations |
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65 | (2) |
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2.3 Gravitational Sedimentation |
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67 | (7) |
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2.4 Centrifugal Sedimentation |
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74 | (4) |
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78 | (7) |
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2.6 Brownian Motion and Diffusion |
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85 | (9) |
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2.7 The Random Coil and Random Walk Statistics |
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94 | (4) |
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2.8 Equilibrium Between Sedimentation and Diffusion |
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98 | (3) |
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101 | (1) |
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101 | (1) |
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102 | (3) |
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3. Solution Thermodynamis: Osmotic and Donnan Equilibria |
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105 | (40) |
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105 | (3) |
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3.2 Osmotic Pressure: Thermodynamic Foundations |
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108 | (6) |
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3.3 Osmometry: Some Applications |
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114 | (6) |
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3.4 Statistical Foundations of Solution Thermodynamic |
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120 | (12) |
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3.5 Osmoticc Equilibrium in Charged Systems |
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132 | (7) |
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3.6 Some Applications of Osmotic Phenomena |
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139 | (1) |
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140 | (1) |
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141 | (1) |
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142 | (3) |
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4. The Rheology of Dispersions |
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145 | (48) |
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145 | (3) |
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4.2 Newton's Law of Viscosity |
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148 | (2) |
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4.3 Concentric-Cylinder and Cone-and Plate Viscometers |
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150 | (4) |
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4.4 The Poiseuille Equation and Capillary Viscometers |
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154 | (4) |
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4.5 The Equation of Motion: The Navier-Stokes Equation |
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158 | (3) |
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4.6 Einstein's Theory of Viscosity of Dispersions |
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161 | (7) |
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4.7 Deviations from the Einstein Model |
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168 | (6) |
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4.8 Non-Newtonian Behavior |
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174 | (7) |
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4.9 Viscosity of Polymer Solutions |
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181 | (7) |
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188 | (1) |
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188 | (1) |
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189 | (4) |
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5. Static and Dynamic Light Scattering and Other Radiation Scattering |
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193 | (55) |
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193 | (3) |
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5.2 Interaction of Radiation with Matter |
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196 | (6) |
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5.3 Scattering by Small Particles: Theory of Rayleigh Scattering |
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202 | (5) |
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5.4 Experimental Aspects of Light Scattering |
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207 | (6) |
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5.5 Extension to Larger Particles and to Intraparticle Interference Effects |
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213 | (10) |
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5.6 Interference Effects and Structure of Particles |
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223 | (6) |
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5.7 Scattering by Large, Absorbing Particles |
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229 | (7) |
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5.8 Dynamic Light Scattering |
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236 | (6) |
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242 | (1) |
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242 | (1) |
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244 | (4) |
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6. Surface Tension and Contact Angle: Application to pure Substances |
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248 | (49) |
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248 | (3) |
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6.2 Surface Tension and Contact Angle: A First Look |
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251 | (4) |
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6.3 Thermodynamics of Surfaces: Surface Tension as Surface Free Energy |
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255 | (2) |
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6.4 Surface Tension: Implications for Curved Interfaces and Capillarity |
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257 | (4) |
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6.5 Effects of Curved Interfaces on Phase Equilibria and Nucleation: The Kelvin Equation |
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261 | (4) |
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6.6 Surface Tension and Contact Angle: Their Relation to Wetting and Spreading Phenomena |
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265 | (7) |
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6.7 Contact Angles: Some Complications |
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272 | (4) |
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6.8 Measuring Surface Tension and Contact Angle: Round Two |
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272 | (4) |
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6.9 Contact of Liquids with Porous Solids and Powders |
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276 | (7) |
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6.10 Molecular Interpretation of Surface Tension |
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283 | (3) |
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286 | (5) |
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291 | (2) |
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293 | (4) |
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7. Adsorption from Solution and Monolayer Formation |
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297 | (58) |
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297 | (3) |
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7.2 Insoluble Monolayers: Spreading of Surfactants on Aqueous Surfaces |
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300 | (4) |
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7.3 Experimental Measurement of Film Pressure |
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304 | (4) |
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7.4 Results of Film Balance Studies |
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308 | (10) |
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7.5 Viscous Behavior of Two-Dimensional Phases |
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318 | (2) |
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7.6 Applications of Monolayers Concepts |
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320 | (3) |
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7.7 Adsorption from Solution: Thermodynamics |
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323 | (4) |
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7.8 The Gibbs Equation: Experimental Results |
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327 | (4) |
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7.9 Adsorption on Solid Surfaces |
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331 | (3) |
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7.10 Applications of Adsorption from Solution |
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338 | (5) |
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7.11 Adsorption in the Presence of an Applied Potential |
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343 | (5) |
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348 | (1) |
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348 | (1) |
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349 | (6) |
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8. Colloidal Structures in Surfactant Solutions: Association Colloids |
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355 | (50) |
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355 | (2) |
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8.2 Surfactants in Solution: Experimental Observations and Models |
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357 | (5) |
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8.3 Structure of Micelles |
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362 | (5) |
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8.4 Molecular Architecture of Surfactants, Packing Considertions, and Shapes of Micelles |
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367 | (3) |
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8.5 Critical Micelle Concentration and the Thermodynamics of Micellization |
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370 | (5) |
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375 | (5) |
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8.7 Catalysis by Micelles |
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380 | (6) |
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386 | (3) |
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8.9 Emulsions and Microemulsions |
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389 | (3) |
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8.10 Some Applications of Microemulsions |
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392 | (3) |
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8.11 Biological Membranes |
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395 | (3) |
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398 | (1) |
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399 | (1) |
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399 | (6) |
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9. Adsorption at Gas-Solid Interfaces |
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405 | (57) |
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405 | (4) |
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9.2 Experimental and Theoretical Treatments of Adsorption: An Overview |
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409 | (4) |
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9.3 Thermodynamics of Adsorption: Phenomenological Perspective |
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413 | (6) |
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9.4 Thermodynamics of Adsorption: A Statistical Perspective |
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419 | (6) |
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9.5 Multilayer Adsorption: The Brunauer-Emmett-Teller Equation |
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425 | (8) |
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9.6 Energetics of Adsorption |
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433 | (3) |
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9.7 Adsorption in Porous Solids |
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436 | (3) |
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9.8 Adsorption on Crystal Surfaces |
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439 | (12) |
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9.9 Metal Surfaces and Heterogeneous Catalysis |
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451 | (4) |
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455 | (1) |
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456 | (1) |
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456 | (6) |
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462 | (37) |
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462 | (2) |
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10.2 van der Waals Forces and Their Importance in Colloid and Surface Chemistry |
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464 | (3) |
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10.3 Molecular Interactions and Power Laws |
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467 | (4) |
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10.4 Molecular Origians and the Macroscopic Implication of van der Waals Forces |
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471 | (8) |
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10.5 van der Waals Forces Between Large Particles and Over Large Distances |
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479 | (4) |
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10.6 Calculating van der Waals Forces Between Macroscopic Bodies |
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483 | (3) |
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10.7 Theories of van der Waals Forces Based on Bulk Properties |
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486 | (4) |
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10.8 Effect of the Medium on the van der Waals Attraction |
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490 | (5) |
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495 | (1) |
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495 | (1) |
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496 | (3) |
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11. The Electrical Double Layer and Double-Layer Interactions |
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499 | (35) |
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499 | (3) |
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11.2 Surface Charges and Electrical Double Layer: Background |
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502 | (2) |
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11.3 The Capacitor Model of the Double Layer |
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504 | (4) |
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11.4 The Diffuse Double Layer: The Debye-Huckel Approximation |
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508 | (4) |
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11.5 The Debye-Huckel Approximation: Results |
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512 | (4) |
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11.6 The Electrical Double Layer: Gouy-Chapman Theory |
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516 | (4) |
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11.7 Overlapping Double Layers and Interparticle Repulsion |
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520 | (7) |
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11.8 "Not-Quite-Indifferent" Electrolytes: Stern Adsorption |
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527 | (3) |
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530 | (1) |
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530 | (1) |
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531 | (3) |
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12. Electrophoresis and Other Electrokinetic Phenomena |
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534 | (41) |
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534 | (2) |
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12.2 Mobilities of Small Ions and Macroions Electric Fields: A Comparison |
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536 | (2) |
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12.3 Zeta Potential: Thick Electrical Double Layers |
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538 | (6) |
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Zeta Potential: Thin Electrical Double Layers |
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544 | (2) |
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12.5 Zeta Potential General Theory for Spherical Particles |
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546 | (4) |
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550 | (3) |
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553 | (2) |
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12.8 The Surface of Shear and Viscoelectric Effect |
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555 | (4) |
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12.9 Experimental Aspects of Electrophoresis |
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559 | (6) |
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12.10 Determining the Surface Change from Electrokinetic Measurments |
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565 | (2) |
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12.11 Applications of Electrokinetic Phenomena |
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567 | (3) |
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570 | (1) |
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570 | (1) |
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571 | (4) |
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13. Electrostatic and Polymer-Induced Colloid Stability |
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575 | (50) |
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575 | (3) |
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13.2 Interparticle Forces and the Structure and Stability of Dispersions |
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578 | (7) |
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13.3 The Derjaguin-Landau-Verwey-Overbeek Theory of Colloid Stability |
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585 | (7) |
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13.4 Theory of Coagulation in Dilute Dispersions |
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592 | (12) |
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13.5 Polymer-Colloid Mixtures: A Phenomenological Perspective |
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604 | (6) |
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13.6 Polymer-Induced Forces |
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610 | (4) |
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13.7 Steric Stabilization: A Model for the Initial Encounter |
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614 | (5) |
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619 | (1) |
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620 | (1) |
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621 | (4) |
Appendix A: Examples of Expansions Encountered in This Book |
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625 | (1) |
Reference |
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625 | (1) |
Appendix B: Units: CSS-SI Interconversions |
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626 | (1) |
Reference |
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626 | (6) |
Appendix C: Statistics of Discrete and Continuous Distributions of Data |
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631 | (7) |
C.1 Introduction |
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631 | (1) |
C.2 Discrete Distributions |
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631 | (3) |
C.3 Theoretical Distributions Functions |
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634 | (1) |
References |
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637 | (1) |
Appendix D: List Worked-Out Examples |
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638 | (3) |
Index |
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641 | |