Atnaujinkite slapukų nuostatas

Reaction Engineering, Catalyst Preparation, and Kinetics [Kietas viršelis]

  • Formatas: Hardback, 364 pages, aukštis x plotis: 234x156 mm, weight: 520 g, 28 Tables, black and white; 185 Line drawings, black and white; 3 Halftones, black and white; 188 Illustrations, black and white
  • Išleidimo metai: 23-Nov-2021
  • Leidėjas: CRC Press
  • ISBN-10: 1138605980
  • ISBN-13: 9781138605985
Kitos knygos pagal šią temą:
Reaction Engineering, Catalyst Preparation, and KineticsDidesnis paveikslėlis
  • Formatas: Hardback, 364 pages, aukštis x plotis: 234x156 mm, weight: 520 g, 28 Tables, black and white; 185 Line drawings, black and white; 3 Halftones, black and white; 188 Illustrations, black and white
  • Išleidimo metai: 23-Nov-2021
  • Leidėjas: CRC Press
  • ISBN-10: 1138605980
  • ISBN-13: 9781138605985
Kitos knygos pagal šią temą:
Pastovi nuoroda: https://www.kriso.lt/db/9781138605985.html
Raktažodžiai:

Reaction Engineering, Catalyst Preparation, and Kinetics serves as an introduction to the subject, giving readers the tools to solve real-world chemical reaction engineering problems. It features a section of fully solved examples as well as end of chapter problems. It includes coverage of catalyst characterization and its impact on kinetics and reactor modeling. Each chapter presents simple ideas and concepts which build towards more complex and realistic cases and situations.

  • Introduces an in-depth kinetics analysis

  • Features well developed sections on the major topics of catalysts, kinetics, reactor design, and modeling

  • Includes a chapter that showcases a fully worked out example, detailing a typical problem that is faced when performing laboratory work

  • Offers end of chapter problems and a solutions manual for adopting professors

Aimed at chemical engineering advanced undergraduates and graduate students taking chemical reaction engineering courses as well as chemical engineering professionals, this textbook provides the knowledge to tackle real problems within the industry.



This textbook covers reaction engineering, catalyst preparation, and kinetics. It features a section of fully solved examples as well as end of chapter problems. It includes coverage of catalyst characterization and its impact on kinetics and reactor modeling. It presents simpler cases as well as fully developed complicated scenarios.

Preface xi
Acknowledgements xiii
Author xv
Chapter 1 Catalysis Preparation and Characterization
1(42)
1.1 Introduction: Basic Concept and Origin of Catalysis
1(1)
1.2 Cataloging Catalytic Material
2(7)
1.2.1 Homogeneous Catalysis
2(1)
1.2.2 Heterogeneous Catalysis
2(2)
1.2.2.1 Nanoscale Catalytic Materials
4(1)
1.2.2.2 Porous Materials
4(1)
1.2.2.3 Supported Catalysts
5(1)
1.2.3 Biocatalysis
6(2)
1.2.4 Photocatalysis
8(1)
1.3 Catalyst Preparation Techniques
9(10)
1.3.1 Precipitation
10(1)
1.3.2 Coprecipitation
10(2)
1.3.2.1 Theory of Nucleation
12(1)
1.3.3 Impregnation
12(1)
1.3.4 Sol Gel Method
13(1)
1.3.5 Chemical Vapor Deposition
14(1)
1.3.6 Ion Exchange
15(1)
1.3.7 Immobilization of Catalysts
16(1)
1.3.7.1 Covalent Bonding
17(1)
1.3.7.2 Entrapment
17(1)
1.3.7.3 Adsorption
18(1)
1.3.7.4 Ionic Bonding
18(1)
1.3.8 Other Alternatives
18(1)
1.4 Catalyst Characterization Techniques
19(14)
1.4.1 X-ray Diffraction (XRD)
19(2)
1.4.2 Porosity Measurements
21(2)
1.4.3 Scanning Electron Microscopy (SEM)
23(1)
1.4.4 Transmission Electron Microscopy (TEM)
24(1)
1.4.5 Infrared Spectroscopy (IR)
25(1)
1.4.6 Thermal Analysis
26(3)
1.4.7 Raman Spectroscopy
29(1)
1.4.8 X-ray Photoelectron Spectroscopy (XPS)
30(3)
1.5 Industrial Catalytic Processes
33(10)
1.5.1 Synthesis Gas
34(1)
1.5.2 Ammonia Synthesis
35(1)
1.5.3 Selective Oxidation
36(1)
1.5.4 Fischer-Tropsch Process
36(1)
1.5.5 Biodiesel Production
37(1)
References
38(5)
Chapter 2 Reactor Design: Mole and Energy Balance
43(142)
2.1 Introduction
43(1)
2.2 Types of Reactors
43(30)
2.2.1 Batch Reactor
45(4)
2.2.2 Semi-Batch Reactor
49(2)
2.2.2.1 Balance for Reactant A
51(1)
2.2.2.2 Balance for Reactant B
52(5)
2.2.3 Continuous Reactors
57(1)
2.2.3.1 Continuous Stirred Tank Reactor (CSTR)
58(4)
2.2.3.2 Plug Flow Reactor (PFR)
62(8)
2.2.3.3 Pack Bed Reactor (PBR)
70(1)
2.2.3.4 Membrane Reactor (MR)
71(2)
2.3 Conversion
73(6)
2.4 Reactors in Series
79(2)
2.5 Reactors in Parallel
81(1)
2.6 Moles Balance Calculations
82(4)
2.7 Reaction in Gas Phase
86(8)
2.8 Pressure Drop
94(6)
2.9 Multiple Reactions
100(13)
2.9.1 Series Reactions
101(3)
2.9.2 Parallel Reactions
104(1)
2.9.2.1 Scenario 1
105(1)
2.9.2.2 Scenario 2
106(4)
2.9.3 Combined Reactions
110(3)
2.10 Equilibrium Reactions
113(4)
2.11 Non-Isothermal Reactors
117(35)
2.11.1 Adiabatic
122(8)
2.11.1.1 Adiabatic Process for a Reaction at Equilibrium
130(4)
2.11.2 Plug Flow with Heat Added/Removed at a Constant Outside Temperature
134(7)
2.11.3 Co-Current Heating/Cooling Fluid System
141(1)
2.11.4 Counter Current Heating/Cooling Fluid System
142(5)
2.11.5 CSTR with Heat Transfer
147(5)
2.12 Non-Isothermal, Non-Steady State Reactors
152(7)
2.12.1 Batch Reactor
153(1)
2.12.2 Semi-Batch Reactor
154(5)
2.13 Multiple Reaction System in a Plug Flow Reactor
159(7)
2.14 Multiple Reactions in a Batch or Semi-Batch Reactor
166(19)
Notes
171(1)
References
172(1)
Problems
172(13)
Chapter 3 Reaction Kinetics
185(74)
3.1 Introduction
185(1)
3.2 Elementary Reactions
185(1)
3.3 Non-Elementary Reactions
186(2)
3.4 Multiple Reactions
188(1)
3.5 Evaluation of Experimental Data
188(6)
3.5.1 Integration Method
189(1)
3.5.2 Differential Method
190(4)
3.5.3 Generic Method
194(1)
3.6 Kinetics Modeling for Simple Reactions
194(15)
3.6.1 1-Phase Irreversible Reaction
195(1)
3.6.2 1-Phase Reversible Reaction
196(1)
3.6.2.1 Equilibrium Method
196(3)
3.6.2.2 PSSH Method
199(1)
3.6.3 2-Phase Irreversible Reaction
200(1)
3.6.3.1 PSSH Method
200(2)
3.6.4 2-Phase Reversible Reaction
202(1)
3.6.4.1 Equilibrium Method
202(5)
3.6.4.2 PSSH Method
207(2)
3.7 Kinetic Modeling of Complex Systems
209(16)
3.7.1 Homogeneous Systems
210(9)
3.7.2 Heterogeneous Systems
219(6)
3.8 Catalyst Deactivation
225(3)
3.9 Mass Transfer Limitations
228(31)
3.9.1 Internal Mass Transfer Limitations
231(2)
3.9.1.1 Cylindrical Pore
233(2)
3.9.1.2 Spherical Pore
235(3)
3.9.2 Overall Mass Transfer Limitations
238(11)
Note
249(1)
References
249(1)
Problems
250(9)
Chapter 4 Completely Solved Example
259(101)
4.1 Introduction
259(1)
4.2 Description of the Problem
260(1)
4.3 Laboratory Equipment Employed
260(1)
4.4 Experimental Procedure
261(1)
4.5 Sample Analysis and Errors
262(1)
4.6 Data Evaluation
263(6)
4.7 Mathematical Model 1
269(5)
4.8 Comparison of Data and Model 1
274(7)
4.9 Mathematical Model 2
281(10)
4.10 Comparison of Data and Model 2
291(12)
4.11 Final Expression for Kinetics
303(1)
4.12 Simulation of an Isothermal Plug Flow Reactor Using Kinetics from 4.11
304(3)
4.13 Simulation of an Adiabatic Plug Flow Reactor with the Kinetics from 4.11
307(3)
4.14 Simulation of a Constant Heat Transfer Plug Flow Reactor with Kinetics from 4.11
310(4)
4.15 Simulation of a Co-Current Heat Transfer Flow in a Plug Flow Reactor with Kinetics from 4.11
314(4)
4.16 Simulation of a Counter-Current Heat Transfer Flow in a Plug Flow Reactor with Kinetics from 4.11
318(5)
4.17 Comparison For A Gas Phase System with Pressure Drop
323(37)
4.17.1 Isothermal
323(6)
4.17.2 Adiabatic
329(7)
4.17.3 Constant External Temperature
336(7)
4.17.4 Co-Current External Flow
343(6)
4.17.5 Counter-Current External Flow
349(7)
4.17.6 Comparison of Previous Cases
356(4)
References 360(1)
Index 361
Dr. Jorge Marchetti was awarded his 5-year Bachelor in 2003 from Universidad Nacional del Sur in Chemical Engineering. In 2008 he was awarded his Ph.D. in Chemical Engineering in Biodiesel Production and in 2009 he was awarded his Ph.D. in Physics in the area of Hydrogen Storage, both Ph.D. were given by Universidad Nacional del Sur in Argentina. From 2008 to 2010 Dr. Marchetti was a postdoctoral fellow at Norwegian University of Science and Technology (NTNU) working on Natural Gas Refining at the Chemical Engineering Department. After that, he was appointed Assistant Professor at Chalmers Technological University in Sweden, at the Forrest Products and Chemical Engineering Division from the Chemical Engineering Department. Since 2011, Dr. Marchetti has been an Associate Professor at the Norwegian University of Life Sciences, NMBU until July 2017 where he was promoted to Full Professor in Chemical Engineering.

Dr. Marchetti is the leader of the Reaction Engineering and Catalysis Group and the group is work on the area of waste based biorefinery, biochemical productions from different biomasses, biofuels production from 2nd and 3rd generation raw materials as well as mathematical modeling, kinetics modeling and techno economy assessment of upscaling technologies. Dr Marchetti is also working on hydrogen storage for fuel cell as well as basic physics modeling of the interaction of chemicals and catalyst in order to have a better understanding of their behavior.