Preface |
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xv | |
Introduction |
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1 | (2) |
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Chapter 1 Local Probes in the Next Decade of Energy Research: Bridging Macroscopic and Atomic Worlds |
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3 | (34) |
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3 | (3) |
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2 The Need for Local Characterization |
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6 | (3) |
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3 Science and Technology of Renewable and Sustainable Options |
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9 | (9) |
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4 Frontiers of Scanning Probe Microscopy |
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18 | (19) |
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I Scanning Probes for Energy Harvesting Systems: Photovoltaics and Solar Cells |
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37 | (214) |
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Chapter 2 Electrical Scanning Probe Microscopy on Solar Cell Materials |
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3 | (70) |
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39 | (3) |
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2 Conducting Atomic Force Microscopy (cAFM) |
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42 | (2) |
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3 Photoconductive Atomic Force Microscopy (pcAFM) |
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44 | (5) |
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49 | (2) |
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5 Electrostatic Force Microscopy (EFM) |
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51 | (2) |
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6 Scanning Kelvin Probe Microscopy (SKPM) |
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53 | (2) |
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7 Time-Resolved Electrostatic Force Microscopy (trEFM) |
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55 | (7) |
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8 Conclusions and Future Outlook |
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62 | (11) |
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Chapter 3 Organic Solar Cell Materials and Devices Characterized by Conductive and Photoconductive Atomic Force Microscopy |
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73 | (42) |
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73 | (1) |
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2 Basic Operation of Organic Solar Cells |
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74 | (2) |
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3 Fundamental Principles of Conductive and Photoconductive AFM |
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76 | (5) |
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4 Applications of c-AFM and pc-AFM for Characterization of Organic Solar Cell Materials and Devices |
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81 | (27) |
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108 | (7) |
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Chapter 4 Kelvin Probe Force Microscopy for Solar Cell Applications |
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115 | (48) |
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115 | (1) |
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2 Experimental Technique and Working Modes |
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116 | (12) |
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3 Application to Solar Cells |
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128 | (35) |
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Chapter 5 Reversible Rectification in Sub-Monolayer Molecular P-N Junctions: Towards Nanoscale Photovoltaic Studies |
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163 | (22) |
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163 | (2) |
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2 Transport in a D-A HJ at the Molecular Scale |
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165 | (3) |
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3 Ultrahigh Vacuum Scanning Tunneling Microscopy and Spectroscopy |
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168 | (3) |
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4 Promise and Challenges of Laser-Assisted STM |
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171 | (1) |
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5 UHV STM of Individual Molecules and Molecular Layers |
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172 | (4) |
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6 Previous STM Work on C60-Pn Heterojunctions |
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176 | (2) |
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7 UHV-STM of C60/Pn/Cu(111) |
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178 | (7) |
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Chapter 6 Study of Photoinduced Charges with Atomic Force Microscopy |
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185 | (22) |
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185 | (1) |
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186 | (2) |
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3 Theory of the Frequency Control Electric Force Microscopy |
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188 | (1) |
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189 | (1) |
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190 | (1) |
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191 | (2) |
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7 Measurement of the Sign of the Charge |
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193 | (1) |
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8 AFM-probe Accelerated Photoionization |
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194 | (1) |
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9 Understanding of the Obtained Results |
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195 | (4) |
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10 Possible Applications for Digital Memory |
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199 | (2) |
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11 Comparison with the AFM Methods Used Previously |
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201 | (1) |
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202 | (5) |
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Chapter 7 Imaging of Nanoscale Photogenerated Charge Transport in Organic Photovoltaic Materials |
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207 | (20) |
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207 | (2) |
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2 Local Photocurrent Measured with Nano-contacts of Different Size |
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209 | (4) |
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3 Surface and Bulk Characterization: Morphology and Photo-current |
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213 | (6) |
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4 Tip Work Function and PC-AFM of Normal and Inverted OPV Structures |
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219 | (4) |
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223 | (4) |
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Chapter 8 Photoassisted Kelvin Probe Force Microscopy for Characterization of Solar Cell Materials |
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227 | (24) |
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227 | (1) |
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2 Principle of Photoassisted Kelvin Probe Force Microscopy (p-KPFM) |
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228 | (4) |
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232 | (1) |
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232 | (4) |
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5 Minority Carrier Diffusion Length |
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236 | (5) |
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6 Minority Carrier Lifetime |
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241 | (5) |
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246 | (5) |
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II Scanning Probes for Fuel Cells and Local Electrochemistry |
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251 | (102) |
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Chapter 9 Electrochemical Strain Microscopy of Oxygen-Ion Conductors: Fuel Cells and Oxide Electronics |
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253 | (46) |
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253 | (4) |
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2 Dynamic Electrochemical Strain Microscopy of ORR/OER |
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257 | (17) |
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3 Mapping Electrochemistry Using ESM in Fuel Cell Materials |
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274 | (19) |
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293 | (6) |
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Chapter 10 Ion Dynamics in Nanoscopic Subvolumes of Solid Electrolytes Analysed by Electrostatic Force Spectroscopy |
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299 | (18) |
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299 | (5) |
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2 Non-Contact Local Probing of Solid Electrolytes by Electrostatic Force Spectroscopy |
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304 | (10) |
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314 | (3) |
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Chapter 11 Nanoscale Electrochemistry in Energy Related Systems using Atomic Force Microscopy |
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317 | (24) |
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1 Nanoscale Characterization of Complex Properties in Energy Materials and Devices |
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317 | (1) |
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2 Application Examples to Energy Related Materials and Devices |
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318 | (14) |
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3 Challenges and Future Possibilities |
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332 | (3) |
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335 | (6) |
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Chapter 12 Scanning Probe Microscopy of Fuel Cell Materials Under Realistic Operating Conditions |
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341 | (12) |
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341 | (1) |
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2 In-situ Methods for Fuel Cells: A Race for Resolution |
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342 | (1) |
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3 High Temperature Scanning Probe Microscopy: Implications for SOFCs |
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343 | (1) |
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4 Inherent Challenges of Scanning in Realistic Operating Regimes |
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344 | (1) |
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5 Miniature Environmental Sample Chamber (MESC) |
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345 | (1) |
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6 Energy-Related in-situ SPM: Exploring the Operating Regime |
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346 | (2) |
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348 | (5) |
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III Scanning Probe Microscopy of Energy Storage Materials and Devices |
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353 | (102) |
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Chapter 13 In situ SPM Analysis of Interfacial Phenomena in Lithium-Ion Batteries |
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355 | (16) |
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355 | (1) |
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356 | (2) |
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3 Negative Electrode Materials |
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358 | (5) |
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4 Positive Electrode Materials |
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363 | (4) |
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367 | (4) |
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Chapter 14 Conducting-Probe Atomic Force Microscopy of Electrochemical Interfaces |
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371 | (22) |
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371 | (1) |
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2 Conducting-Probe Atomic Force Microscopy |
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372 | (3) |
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3 Surface Structure, Chemistry and Modification of Optically Transparent Electrodes |
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375 | (7) |
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4 Studies of the Local Structure and Li+ Insertion Kinetics of Metal Oxides |
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382 | (5) |
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5 Conclusions and Outlook |
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387 | (6) |
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Chapter 15 Electrochemical Strain Microscopy of Li-ion and Li-air Battery Materials |
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393 | (62) |
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393 | (4) |
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2 Li-ion and Li-air Batteries |
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397 | (2) |
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3 SPMs for Battery Characterization |
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399 | (2) |
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401 | (1) |
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5 ESM of Li-ion Batteries |
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402 | (34) |
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436 | (4) |
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440 | (4) |
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444 | (11) |
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IV Emerging Scanning Probe Techniques |
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455 | (136) |
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Chapter 16 High Sensitivity Scanning Impedance Microscopy and Spectroscopy |
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457 | (24) |
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457 | (1) |
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2 Relation of Impedance to Materials Properties |
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458 | (3) |
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3 Scanning Impedance Microscopy: Interfaces and Nanotubes |
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461 | (5) |
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4 Nanoimpedance Microscopy/Spectroscopy |
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466 | (5) |
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5 High Sensitivity Impedance: Polarization of Single Molecular Layers |
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471 | (5) |
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476 | (5) |
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Chapter 17 Scanning Microwave Microscopy: Advances in Quantitative Capacitance and Carrier Density Measurements at the Nanometer Scale |
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481 | (32) |
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481 | (2) |
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2 Working Principles of NSMM |
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483 | (7) |
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3 Microwave Detection with a Vector Network Analyzer |
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490 | (7) |
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4 Implementation of SMM with AFM and VNA |
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497 | (1) |
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5 Capacitance Calibration Workflow |
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498 | (3) |
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501 | (1) |
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7 Dopant Profiling Calibration Workflow |
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501 | (4) |
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8 Dopant Profiling Imaging Optimization |
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505 | (3) |
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9 Conclusions and Outlooks |
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508 | (5) |
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Chapter 18 Mapping Electrochemistry at the Micro and Nanoscales with Scanning Ion Conductance Microscopy |
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513 | (16) |
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1 Introduction: The Application of SICM to Energy and Materials Systems |
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513 | (1) |
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2 Principles and Operating Modes |
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514 | (2) |
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3 Instrumentation and Electrochemical Probes |
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516 | (3) |
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4 Material Interfaces: Local Reactivity and Corrosion |
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519 | (2) |
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5 Soft Materials: Ion Exchange and Materials Transport |
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521 | (1) |
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6 Energy Materials: Polymer Membranes, Fuel Cell Catalysts |
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522 | (2) |
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7 The Convergence of SPM Techniques |
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524 | (1) |
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8 Conclusions and Outlook |
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525 | (4) |
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Chapter 19 Force Microscopy, Nanochemistry and Nanofabrication |
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529 | (28) |
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529 | (2) |
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2 Field-induced Chemistry |
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531 | (1) |
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3 Carbon Dioxide Dissociation |
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532 | (3) |
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535 | (4) |
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5 AFM Oxidation and Constructive Nanolithography |
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539 | (1) |
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6 Chemistry Beyond Water Bridges |
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540 | (2) |
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7 Deposition of Semiconductors |
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542 | (1) |
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8 Thermal-Induced Nanoscale Chemistry |
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543 | (3) |
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9 Nanomachining and Mechanochemical Patterning |
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546 | (1) |
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10 Dip-pen Nanolithography |
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547 | (1) |
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11 Scanning Tunneling Microscopy and Nanochemistry |
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547 | (1) |
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548 | (1) |
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13 Conclusions and Outlook |
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549 | (8) |
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Chapter 20 Studying the Mechanism of Piezoelectric Nanogenerators |
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557 | (34) |
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557 | (1) |
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2 Discovery of Nanogenerator |
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558 | (6) |
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3 Theoretical Calculation on Power Output of NW |
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564 | (2) |
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4 p-Type Nanowires vs. n-Type Nanowires |
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566 | (4) |
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5 Harvesting Energy Using Other Nanomaterials |
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570 | (12) |
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6 Optimizing Power Output of Nanogenerator |
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582 | (5) |
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587 | (4) |
Index |
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