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Scanning Probe Microscopy For Energy Research [Kietas viršelis]

Edited by (Oak Ridge Nat'l Lab, Usa), Edited by (The Univ Of Pennsylvania, Usa)
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Several conferences have been held over the last few years on the convergence of scanning probe microscopy (SPM) and energy research. Here physicists, materials scientists, and engineers review approaches being used by leading researchers now. They cover scanning probes for energy harvesting systems, for fuel cells and local electrochemistry, and for energy storage materials and devices; and emerging scanning probe techniques. The topics include organic solar cell materials and devices characterized by conductive and photoconductive atomic force microscopy, imaging nanoscale photogenerated charge transport in organic photovoltaic materials, subvolumes of solid electrolytes analyzed by electrostatic force spectroscopy, the in situ analysis of interfacial phenomena in lithium-ion batteries, and the mechanisms of piezoelectric nanogenerators. Annotation ©2013 Book News, Inc., Portland, OR (booknews.com)

Efficiency and life time of solar cells, energy and power density of the batteries, and costs of the fuel cells alike cannot be improved unless the complex electronic, optoelectronic, and ionic mechanisms underpinning operation of these materials and devices are understood on the nanometer level of individual defects. Only by probing these phenomena locally can we hope to link materials structure and functionality, thus opening pathway for predictive modeling and synthesis. While structures of these materials are now accessible on length scales from macroscopic to atomic, their functionality has remained Terra Incognitae. In this volume, we provide a summary of recent advances in scanning probe microscopy studies of local functionality of energy materials and devices ranging from photovoltaics to batteries, fuel cells, and energy harvesting systems. Recently emergent SPM modes and combined SPM-electron microscopy approaches are also discussed. Contributions by internationally renowned leaders in the field describe the frontiers in this important field.
Preface v
List of Color Plates
xv
Introduction 1(2)
Chapter 1 Local Probes in the Next Decade of Energy Research: Bridging Macroscopic and Atomic Worlds
3(34)
D. A. Bonnell
S. V. Kalinin
1 The Energy Challenge
3(3)
2 The Need for Local Characterization
6(3)
3 Science and Technology of Renewable and Sustainable Options
9(9)
4 Frontiers of Scanning Probe Microscopy
18(19)
I Scanning Probes for Energy Harvesting Systems: Photovoltaics and Solar Cells
37(214)
Chapter 2 Electrical Scanning Probe Microscopy on Solar Cell Materials
3(70)
R. Giridharagopal
G. E. Rayermann
D. S. Ginger
1 Introduction
39(3)
2 Conducting Atomic Force Microscopy (cAFM)
42(2)
3 Photoconductive Atomic Force Microscopy (pcAFM)
44(5)
4 AC-Mode AFM
49(2)
5 Electrostatic Force Microscopy (EFM)
51(2)
6 Scanning Kelvin Probe Microscopy (SKPM)
53(2)
7 Time-Resolved Electrostatic Force Microscopy (trEFM)
55(7)
8 Conclusions and Future Outlook
62(11)
Chapter 3 Organic Solar Cell Materials and Devices Characterized by Conductive and Photoconductive Atomic Force Microscopy
73(42)
X.-D. Dang
M. Guide
T.-Q. Nguyen
1 Introduction
73(1)
2 Basic Operation of Organic Solar Cells
74(2)
3 Fundamental Principles of Conductive and Photoconductive AFM
76(5)
4 Applications of c-AFM and pc-AFM for Characterization of Organic Solar Cell Materials and Devices
81(27)
5 Summary and Outlook
108(7)
Chapter 4 Kelvin Probe Force Microscopy for Solar Cell Applications
115(48)
T. Glatzel
1 Introduction
115(1)
2 Experimental Technique and Working Modes
116(12)
3 Application to Solar Cells
128(35)
Chapter 5 Reversible Rectification in Sub-Monolayer Molecular P-N Junctions: Towards Nanoscale Photovoltaic Studies
163(22)
J. A. Smerdon
N. C. Giebink
J. R. Guest
1 Introduction
163(2)
2 Transport in a D-A HJ at the Molecular Scale
165(3)
3 Ultrahigh Vacuum Scanning Tunneling Microscopy and Spectroscopy
168(3)
4 Promise and Challenges of Laser-Assisted STM
171(1)
5 UHV STM of Individual Molecules and Molecular Layers
172(4)
6 Previous STM Work on C60-Pn Heterojunctions
176(2)
7 UHV-STM of C60/Pn/Cu(111)
178(7)
Chapter 6 Study of Photoinduced Charges with Atomic Force Microscopy
185(22)
M. Dokukin
N. Guz
I. Sokolov
1 Introduction
185(1)
2 Materials and Methods
186(2)
3 Theory of the Frequency Control Electric Force Microscopy
188(1)
4 Results and Discussion
189(1)
5 Charge Measurements
190(1)
6 Control Experiments
191(2)
7 Measurement of the Sign of the Charge
193(1)
8 AFM-probe Accelerated Photoionization
194(1)
9 Understanding of the Obtained Results
195(4)
10 Possible Applications for Digital Memory
199(2)
11 Comparison with the AFM Methods Used Previously
201(1)
12 Conclusion
202(5)
Chapter 7 Imaging of Nanoscale Photogenerated Charge Transport in Organic Photovoltaic Materials
207(20)
B. Hamadani
P. M. Haney
N. B. Zhitenev
1 Introduction
207(2)
2 Local Photocurrent Measured with Nano-contacts of Different Size
209(4)
3 Surface and Bulk Characterization: Morphology and Photo-current
213(6)
4 Tip Work Function and PC-AFM of Normal and Inverted OPV Structures
219(4)
5 Conclusions
223(4)
Chapter 8 Photoassisted Kelvin Probe Force Microscopy for Characterization of Solar Cell Materials
227(24)
T. Takahashi
1 Introduction
227(1)
2 Principle of Photoassisted Kelvin Probe Force Microscopy (p-KPFM)
228(4)
3 Sample Structure
232(1)
4 Photovoltage Mapping
232(4)
5 Minority Carrier Diffusion Length
236(5)
6 Minority Carrier Lifetime
241(5)
7 Conclusions
246(5)
II Scanning Probes for Fuel Cells and Local Electrochemistry
251(102)
Chapter 9 Electrochemical Strain Microscopy of Oxygen-Ion Conductors: Fuel Cells and Oxide Electronics
253(46)
A. Kumar
S. Jesse
S. V. Kalinin
F. Ciucci
A. Morozovska
1 Introduction
253(4)
2 Dynamic Electrochemical Strain Microscopy of ORR/OER
257(17)
3 Mapping Electrochemistry Using ESM in Fuel Cell Materials
274(19)
4 Conclusions
293(6)
Chapter 10 Ion Dynamics in Nanoscopic Subvolumes of Solid Electrolytes Analysed by Electrostatic Force Spectroscopy
299(18)
A. Schirmeisen
B. Roling
1 Introduction
299(5)
2 Non-Contact Local Probing of Solid Electrolytes by Electrostatic Force Spectroscopy
304(10)
3 Conclusion and Outlook
314(3)
Chapter 11 Nanoscale Electrochemistry in Energy Related Systems using Atomic Force Microscopy
317(24)
W. Lee
M. H. Lee
R. P. O'Hayre
F. B. Prinz
1 Nanoscale Characterization of Complex Properties in Energy Materials and Devices
317(1)
2 Application Examples to Energy Related Materials and Devices
318(14)
3 Challenges and Future Possibilities
332(3)
4 Summary and Outlook
335(6)
Chapter 12 Scanning Probe Microscopy of Fuel Cell Materials Under Realistic Operating Conditions
341(12)
S. S. Nonnenmann
D. A. Bonnell
1 Introduction
341(1)
2 In-situ Methods for Fuel Cells: A Race for Resolution
342(1)
3 High Temperature Scanning Probe Microscopy: Implications for SOFCs
343(1)
4 Inherent Challenges of Scanning in Realistic Operating Regimes
344(1)
5 Miniature Environmental Sample Chamber (MESC)
345(1)
6 Energy-Related in-situ SPM: Exploring the Operating Regime
346(2)
7 Impact and Outlook
348(5)
III Scanning Probe Microscopy of Energy Storage Materials and Devices
353(102)
Chapter 13 In situ SPM Analysis of Interfacial Phenomena in Lithium-Ion Batteries
355(16)
M. Inaba
S.-K. Jeong
Z. Ogumi
1 Introduction
355(1)
2 Experimental Setup
356(2)
3 Negative Electrode Materials
358(5)
4 Positive Electrode Materials
363(4)
5 Concluding Remarks
367(4)
Chapter 14 Conducting-Probe Atomic Force Microscopy of Electrochemical Interfaces
371(22)
P. A. Veneman
K. J. Stevenson
1 Introduction
371(1)
2 Conducting-Probe Atomic Force Microscopy
372(3)
3 Surface Structure, Chemistry and Modification of Optically Transparent Electrodes
375(7)
4 Studies of the Local Structure and Li+ Insertion Kinetics of Metal Oxides
382(5)
5 Conclusions and Outlook
387(6)
Chapter 15 Electrochemical Strain Microscopy of Li-ion and Li-air Battery Materials
393(62)
T. M. Arruda
N. Balke
S. Jesse
S. V. Kalinin
1 Introduction
393(4)
2 Li-ion and Li-air Batteries
397(2)
3 SPMs for Battery Characterization
399(2)
4 Principles of ESM
401(1)
5 ESM of Li-ion Batteries
402(34)
6 Irreversible Processes
436(4)
7 Future Perspectives
440(4)
8 Outlook
444(11)
IV Emerging Scanning Probe Techniques
455(136)
Chapter 16 High Sensitivity Scanning Impedance Microscopy and Spectroscopy
457(24)
S. S. Nonnenmann
X. Chen
D. A. Bonnell
1 Introduction
457(1)
2 Relation of Impedance to Materials Properties
458(3)
3 Scanning Impedance Microscopy: Interfaces and Nanotubes
461(5)
4 Nanoimpedance Microscopy/Spectroscopy
466(5)
5 High Sensitivity Impedance: Polarization of Single Molecular Layers
471(5)
6 Summary of Impact
476(5)
Chapter 17 Scanning Microwave Microscopy: Advances in Quantitative Capacitance and Carrier Density Measurements at the Nanometer Scale
481(32)
S. Wu
F. Kienberger
H. Tanbakuchi
1 Introduction
481(2)
2 Working Principles of NSMM
483(7)
3 Microwave Detection with a Vector Network Analyzer
490(7)
4 Implementation of SMM with AFM and VNA
497(1)
5 Capacitance Calibration Workflow
498(3)
6 C-V Spectroscopy
501(1)
7 Dopant Profiling Calibration Workflow
501(4)
8 Dopant Profiling Imaging Optimization
505(3)
9 Conclusions and Outlooks
508(5)
Chapter 18 Mapping Electrochemistry at the Micro and Nanoscales with Scanning Ion Conductance Microscopy
513(16)
C. Laslau
D. E. Williams
J. Travas-Sejdic
1 Introduction: The Application of SICM to Energy and Materials Systems
513(1)
2 Principles and Operating Modes
514(2)
3 Instrumentation and Electrochemical Probes
516(3)
4 Material Interfaces: Local Reactivity and Corrosion
519(2)
5 Soft Materials: Ion Exchange and Materials Transport
521(1)
6 Energy Materials: Polymer Membranes, Fuel Cell Catalysts
522(2)
7 The Convergence of SPM Techniques
524(1)
8 Conclusions and Outlook
525(4)
Chapter 19 Force Microscopy, Nanochemistry and Nanofabrication
529(28)
R. Garcia
M. Chiesa
Y. K. Ryu
1 Introduction
529(2)
2 Field-induced Chemistry
531(1)
3 Carbon Dioxide Dissociation
532(3)
4 AFM Oxidation
535(4)
5 AFM Oxidation and Constructive Nanolithography
539(1)
6 Chemistry Beyond Water Bridges
540(2)
7 Deposition of Semiconductors
542(1)
8 Thermal-Induced Nanoscale Chemistry
543(3)
9 Nanomachining and Mechanochemical Patterning
546(1)
10 Dip-pen Nanolithography
547(1)
11 Scanning Tunneling Microscopy and Nanochemistry
547(1)
12 Patterning Throughput
548(1)
13 Conclusions and Outlook
549(8)
Chapter 20 Studying the Mechanism of Piezoelectric Nanogenerators
557(34)
J. Song
Z. L. Wang
1 Introduction
557(1)
2 Discovery of Nanogenerator
558(6)
3 Theoretical Calculation on Power Output of NW
564(2)
4 p-Type Nanowires vs. n-Type Nanowires
566(4)
5 Harvesting Energy Using Other Nanomaterials
570(12)
6 Optimizing Power Output of Nanogenerator
582(5)
7
Chapter Summary
587(4)
Index 591