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Semiconducting Black Phosphorus: From 2D Nanomaterial to Emerging 3D Architecture [Kietas viršelis]

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  • Formatas: Hardback, 204 pages, aukštis x plotis: 234x156 mm, weight: 430 g, 3 Tables, black and white; 38 Line drawings, black and white; 46 Halftones, black and white; 84 Illustrations, black and white
  • Serija: Emerging Materials and Technologies
  • Išleidimo metai: 25-Oct-2021
  • Leidėjas: CRC Press
  • ISBN-10: 1032067632
  • ISBN-13: 9781032067636
Kitos knygos pagal šią temą:
Semiconducting Black Phosphorus: From 2D Nanomaterial to Emerging 3D ArchitectureDidesnis paveikslėlis
  • Formatas: Hardback, 204 pages, aukštis x plotis: 234x156 mm, weight: 430 g, 3 Tables, black and white; 38 Line drawings, black and white; 46 Halftones, black and white; 84 Illustrations, black and white
  • Serija: Emerging Materials and Technologies
  • Išleidimo metai: 25-Oct-2021
  • Leidėjas: CRC Press
  • ISBN-10: 1032067632
  • ISBN-13: 9781032067636
Kitos knygos pagal šią temą:
Pastovi nuoroda: https://www.kriso.lt/db/9781032067636.html
Raktažodžiai:
Black phosphorus-based two-dimensional nanomaterials are used in practical industrial applications in biomedicine, electronics, and photonics. This book provides an overview of the various synthetic strategies for 2D BP single layer nanomaterials, their scalable synthesis, properties, and assemblies into 3D architecture for increased performance.

Black phosphorus (BP)-based two-dimensional (2D) nanomaterials are used as components in practical industrial applications in biomedicine, electronics, and photonics. There is a need to controllably shape engineered scalable structures of 2D BP building blocks, and their assembly/organization is desired for the formation of three-dimensional (3D) forms such as macro and hybrid architectures, as it is expected that these architectures will deliver even better materials performance in applications. Semiconducting Black Phosphorus: From 2D Nanomaterial to Emerging 3D Architecture provides an overview of the various synthetic strategies for 2D BP single layer nanomaterials, their scalable synthesis, properties, and assemblies into 3D architecture.

  • Covers defect engineering and physical properties of black phosphorous

  • Describes different strategies for the development of 2D nanostructures of BP with other species such as polymers, organic molecules, and other inorganic materials

  • Offers a comparative study of 3D BP structures with other 3D architectures such as dichalcogenides (TMDs, graphene, and boron nitride)

  • Discusses in detail applications of 3D macrostructures of BP in various fields such as energy, biomedical, and catalysis

This is an essential reference for researchers and advanced students in materials science and chemical, optoelectronic, and electrical engineering.

Preface ix
Authors' Biographies xi
Chapter 1 General Overview of 2D Black Phosphorus
1(12)
1.1 Introduction
1(3)
1.2 Overview of
Chapters
4(2)
1.3 Summary
6(1)
1.4 Acknowledgments
6(7)
References
6(7)
Chapter 2 Chemistry of Phosphorus
13(10)
2.1 Introduction
13(1)
2.2 Allotropes of Phosphorus
14(3)
2.2.1 White Phosphorus
14(1)
2.2.1.1 Toxicity
15(1)
2.2.2 Red Phosphorus
16(1)
2.2.3 Black Phosphorus
16(1)
2.3 Stability Study of Various Allotropes of Phosphorus
17(2)
2.4 Summary
19(1)
2.5 Acknowledgments
20(3)
References
20(3)
Chapter 3 2D Form of Black Phosphorus
23(78)
3.1 Introduction
23(1)
3.2 Synthetic Strategies/Morphological Engineering and Characterizations of Black Phosphorus
23(47)
3.2.1 Non-Epitaxial Growth
24(1)
3.2.1.1 Mechanical Cleavage Approach
24(8)
3.2.1.2 Liquid Phase Exfoliation
32(18)
3.2.1.3 Electrochemical Exfoliation
50(5)
3.2.1.4 Laser Irradiation
55(1)
3.2.1.5 Thermal Annealing
56(2)
3.2.1.6 Scalable Synthesis of 2D Black Phosphorus
58(3)
3.2.2 Epitaxial Growth
61(1)
3.2.2.1 Chemical Vapor Deposition
61(5)
3.2.2.2 Pulsed Laser Deposition
66(2)
3.2.2.3 Molecular Beam Epitaxy
68(2)
3.3 Stability Property and Defect Engineering of Black Phosphorus
70(3)
3.4 Properties and Application of 2D BP
73(15)
3.4.1 Bandgap
73(1)
3.4.2 On-Off Ratio/Mobility
74(1)
3.4.3 In-Plane Anisotropy
75(1)
3.4.4 Thermal Properties of Back Phosphorus
76(2)
3.4.5 Mechanical Properties of Black Phosphorus
78(1)
3.4.6 The Optical Property of Black Phosphorus
79(1)
3.4.6.1 Linear Optical Properties
79(3)
3.4.6.2 Nonlinear Optical Properties
82(2)
3.4.7 Electrical Properties of Black Phosphorus
84(1)
3.4.8 Biodegradable Property of Black Phosphorus
85(3)
3.5 Summary
88(1)
3.6 Acknowledgments
88(13)
References
89(12)
Chapter 4 Composites and Heterostructures of Black Phosphorus
101(16)
4.1 Introduction
101(1)
4.2 Composites of Black Phosphorus with Polymers
102(2)
4.3 Heterostructures of Black Phosphorus with Graphene
104(2)
4.4 Heterostructures of Black Phosphorus with Transition Metal Dichalcogenides
106(7)
4.4.1 Heterostructures of Black Phosphorus withMOS2
107(2)
4.4.2 Heterostructures of Black Phosphorus withWS2
109(3)
4.4.3 Heterostructures of Black Phosphorus withWSe2
112(1)
4.5 Summary
113(1)
4.6 Acknowledgments
114(3)
References
114(3)
Chapter 5 3D Structures Based on 2D BP
117(38)
5.1 Why 3D Structures of BP Are Important
117(1)
5.2 Morphological Engineering of 3D Architecture of BP
117(12)
5.2.1 Honeycomb-Lantern-Inspired 3D Structures of 2D Black Phosphorus
117(2)
5.2.2 3D-Printed Scaffolds from 2D Black Phosphorus
119(2)
5.2.3 Black Phosphorus Sponges by the Modified Electrochemical Approach
121(2)
5.2.4 Graphene Oxide/Black Phosphorus 3D Nanoflakes Aerogel
123(1)
5.2.5 Cellulose/BP Nanosheets (BPNSs)-Based Hydrogel Possesses 3D Networks
123(3)
5.2.6 Palladium Nanoparticles and Black Phosphorus Hybrids 3D Structure
126(3)
5.3 Comparison of 3D Structures of BP with Other 3D Structures of 2D Layered Materials
129(15)
5.3.1 3D Structures of Graphene
129(2)
5.3.1.1 3D Graphene Network from GO-Derived Structures
131(4)
5.3.2 3D Structures of Transition Metal Dichalcogenides
135(1)
5.3.2.1 MoS2
135(2)
5.3.2.2 WS2
137(1)
5.3.3 3D Structures of Boron Nitride
138(2)
5.3.4 Comparison of 3D Structures of BP with Other 3D Structures of 2D Layered Materials
140(4)
5.4 Summary
144(1)
5.5 Acknowledgments
144(11)
References
144(11)
Chapter 6 Emerging Applications of 3D Structures of BP
155(44)
6.1 Introduction
155(1)
6.2 3D Architecture of BP in Optoelectronics
156(33)
6.2.1 Photo-Detectors
156(4)
6.2.2 Biomedical-Based Applications
160(1)
6.2.2.1 Photothermal Performance
161(7)
6.2.2.2 Tissue Engineering
168(5)
6.2.3 Energy Storage Devices
173(1)
6.2.3.1 Li-Ion Batteries
173(3)
6.2.4 Supercapacitors
176(7)
6.2.5 Catalysis
183(1)
6.2.5.1 Electrocatalysis
183(3)
6.2.5.2 Photocatalysis
186(3)
6.3 Conclusion
189(1)
6.4 Acknowledgments
189(10)
References
190(9)
Chapter 7 Brief Summary and Future Directions
199(4)
7.1 Brief Summary
199(1)
7.2 Future Directions
200(1)
7.3 Conclusions
201(1)
7.4 Acknowledgments
201(2)
References
201(2)
Index 203
Han Zhang received his B.S. degree from Wuhan University in 2006 and Ph.D. from Nanyang Technological University in 2010. His current research is on the ultrafast and nonlinear photonics of two-dimensional materials. He is currently the director of Shenzhen Key Laboratory of 2D Materials and Devices and Shenzhen Engineering Laboratory of Phosphorene and Optoelectronics, Shenzhen University. Google Scholar h-index 81, total citations 24,500, ESI highly cited papers (52) and hot papers (6).

Dr. Nasir Mahmood Abbasi received his Master's degree in Chemistry from the University of Karachi, Pakistan, and PhD in Chemical Engineering with focus on nanoscale materials from Zhejiang University, China. Currently, he is working as a postdoc fellow in the School of Physics and Optoelectronic Engineering at Shenzhen University. His research interests include heterostructures and the macro-assemblies of two-dimensional materials for their applications in energy, healthcare, and electronics.

Bing Wang received her PhD degree in Physics from Sun Yat-Sen University (SYSU) in 2007. Currently, she is Associate Professor in the College of Physics and Optoelectronic Engineering, Shenzhen University. Her scientific research concentrates on 2D semiconductor optoelectronic properties and applications.