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El. knyga: Shape Memory Polymers for Biomedical Applications

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Edited by (École Polytechnique de Montréal, Canada)
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Shape memory polymers (SMPs) are an emerging class of smart polymers which give scientists the ability to process the material into a permanent state and predefine a second temporary state which can be triggered by different stimuli. The changing chemistries of SMPs allows scientists to tailor important properties such as strength, stiffness, elasticity and expansion rate. Consequently SMPs are being increasingly used and developed for minimally invasive applications where the material can expand and develop post insertion. This book will provide readers with a comprehensive review of shape memory polymer technologies. Part 1 will discuss the fundamentals and mechanical aspects of SMPs. Chapters in part 2 will look at the range of technologies and materials available for scientific manipulation whilst the final set of chapters will review applications.
  • Reviews the fundamentals of shape memory polymers with chapters focussing on the basic principles of the materials
  • Comprehensive coverage of design and mechanical aspects of SMPs
  • Expert analysis of the range of technologies and materials available for scientific manipulation

Daugiau informacijos

A comprehensive review of shape memory polymers with a focus on properties, behaviour, fabrication and characterisation
List of contributors
ix
Woodhead Publishing Series in Biomaterials xi
Part One Fundamentals of shape-memory polymers for biomedical applications
1(96)
1 Introduction to shape-memory polymers for biomedical applications
3(6)
L. Yahia
1.1 Introduction
3(6)
References
7(2)
2 Mechanical properties of shape-memory polymers for biomedical applications
9(26)
D.L. Safranski
J.C. Griffis
2.1 Introduction
9(6)
2.2 Mechanical properties of shape-memory polymers (SMPs)
15(6)
2.3 Mechanical properties of SMP biomedical devices
21(7)
2.4 Future of SMPs in biomedical applications
28(1)
2.5 Conclusions
29(6)
References
29(6)
3 Characterization of shape-memory polymers for biomedical applications
35(30)
K. Dyamenahalli
A. Famili
R. Shandas
3.1 Introduction
35(1)
3.2 Structural and chemical characterization
35(8)
3.3 Mechanical and thermo-mechanical characterization
43(5)
3.4 Surface characterization
48(3)
3.5 Imaging-based characterization
51(4)
3.6 Biological testing
55(2)
3.7 Example applications
57(3)
3.8 Future trends and conclusions
60(1)
3.9 Sources of further information
61(4)
References
61(4)
4 Mechanical testing of shape-memory polymers for biomedical applications
65(12)
H. Tobushi
R. Matsui
K. Takeda
S. Hayashi
4.1 Introduction
65(1)
4.2 Testing for basic mechanical properties
65(1)
4.3 Testing for tensile deformation
66(1)
4.4 Testing for creep and stress relaxation
67(1)
4.5 Testing for shape fixity and shape recovery
68(3)
4.6 Testing for shape fixity and shape recovery of foam
71(1)
4.7 Testing for recovery stress
71(1)
4.8 Testing for secondary shape forming
72(2)
4.9 Future trends
74(3)
References
74(1)
Appendix: abbreviations
75(2)
5 Biocompatibility of shape-memory polymers for biomedical applications
77(20)
D.A. Mbeh
R.O. do Nascimento
5.1 Introduction
77(1)
5.2 Biocompatibility of shape-memory polymers
78(2)
5.3 Biocompatibility assays
80(6)
5.4 Biocompatible coatings
86(3)
5.5 Conclusion
89(8)
References
90(7)
Part Two Technologies and materials for biomedical shape-memory polymers
97(150)
6 Chemo-responsive shape-memory polymers for biomedical applications
99(34)
H. Lu
W.M. Huang
6.1 Introduction
99(3)
6.2 Thermodynamic mechanism
102(2)
6.3 Working mechanisms
104(12)
6.4 Biomedical applications
116(11)
6.5 Conclusion
127(6)
Acknowledgments
128(1)
References
128(5)
7 Shape-memory polyurethane cellular solids for minimally invasive surgical procedures
133(24)
M.C. Tanzi
L. De Nardo
S. Bertoldi
S. Fare
7.1 Introduction
133(2)
7.2 Methods for obtaining cellular solids
135(2)
7.3 Morphological characterization
137(5)
7.4 Physico-mechanical characterization
142(3)
7.5 Biocompalibility studies
145(12)
Acknowledgments
154(1)
References
155(2)
8 Thiol-ene/acrylate systems for biomedical shape-memory polymers
157(10)
T. Javanbakht
W. Sokolowski
8.1 Introduction
157(1)
8.2 Properties of thiol-ene/acrylate photopolymers
158(2)
8.3 Techniques for activating the memory effect
160(1)
8.4 Medical applications of thiol-ene/acrylate photopolymers
161(2)
8.5 Conclusions
163(4)
References
164(3)
9 Polyurethane shape-memory polymers for biomedical applications
167(30)
Y.Q. Fu
W.M. Huang
J.K. Luo
H. Lu
9.1 Introduction
167(3)
9.2 Properties of shape-memory polyurethane (SMPU)
170(8)
9.3 Techniques for activating SME
178(5)
9.4 Medical applications of SMPU
183(6)
9.5 Summary and future trends
189(8)
References
190(7)
10 Polylactic acid (PLA)-based shape-memory materials for biomedical applications
197(22)
J. Xu
J. Song
10.1 Introduction
197(3)
10.2 Lactic acid-based shape-memory polymers (SMPs)
200(11)
10.3 New directions and future perspectives
211(1)
10.4 Further information
212(7)
References
212(7)
11 Biodegradable shape-memory polymers for biomedical applications
219(28)
S. Strandman
XX. Zhu
11.1 Introduction
219(1)
11.2 Biodegradable shape-memory polymers (SMPs)
220(7)
11.3 Activation and tailoring the shape-memory effect
227(5)
11.4 Biodegradation and biomedical applications
232(6)
11.5 Discussion and future perspectives
238(9)
References
239(8)
Part Three Biomedical applications of shape-memory polymers
247(54)
12 Shape-memory polymers for vascular and coronary devices
249(18)
R. Rath
M.K. Gupta
S.W. Crowder
H.-J. Sung
12.1 Introduction: Key principles
249(1)
12.2 Background
249(1)
12.3 Applications
250(6)
12.4 Tailoring the shape-memory properties
256(2)
12.5 Interface considerations
258(1)
12.6 Strengths and limitations
259(1)
12.7 Future trends
260(1)
12.8 Sources of further information
261(6)
References
261(6)
13 Shape-memory polymers for dental applications
267(14)
R.O. do Nascimento
N. Chirani
13.1 Introduction
267(1)
13.2 Dental materials
267(5)
13.3 Shape-memory polymers (SMPs) in dental materials
272(2)
13.4 Dental implant process
274(3)
13.5 Future trends
277(4)
References
277(4)
14 Shape-memory and self-reinforcing polymers as sutures
281(20)
H. Meng
G. Li
14.1 Introduction: Overview of chapter
281(1)
14.2 Various mechanisms of stimuli-active shape-memory polymers (SMPs)
281(3)
14.3 Shape-memory materials for medical and self-reinforcing suture applications
284(7)
14.4 Future trends
291(1)
14.5 Sources of further information and advice
292(9)
References
292(9)
Index 301
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