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El. knyga: Silver Nanoparticles: From Silver Halide Photography to Plasmonics

(Former President of the International Commitee on the Science of Photography)
  • Formatas: 240 pages
  • Išleidimo metai: 17-Sep-2015
  • Leidėjas: Oxford University Press
  • Kalba: eng
  • ISBN-13: 9780191023996
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Silver Nanoparticles: From Silver Halide Photography to PlasmonicsDidesnis paveikslėlis
  • Formatas: 240 pages
  • Išleidimo metai: 17-Sep-2015
  • Leidėjas: Oxford University Press
  • Kalba: eng
  • ISBN-13: 9780191023996
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Nanoscience and nanotechnology concern themselves with the research and application of extremely small things and can be used across all scientific fields such as physics, chemistry, biology, material science and engineering. Nanoparticles are of great scientific interest as they provide a bridge between bulk materials and atomic or molecular structures. Interesting and unexpected properties of nanoparticles are largely due to the large surface area of the material. Nanoparticles of noble metals including silver (Ag) attract the interest of many researchers owing to their high potential for plasmonic devices in future. On the other hand, nanoparticles of silver (Ag) and silver halides (AgX) have played central roles and have been extensively studied for many years in silver halide (AgX) photography.

Combining knowledge of nanoparticles of Ag and related materials in plasmonics and AgX photography, this book reinforces already existing knowledge, but also presents new ideas for metal nanoparticles in plasmonics. The first part examines the structure and formation of nanoparticles of Ag and related materials. Systematic descriptions of the structure and preparation of Ag, Au, and other noble metal nanoparticles for plasmonics are followed by and related to those of nanoparticles of Ag and AgX in AgX photography. The exploration of the structure and preparation of Ag and AgX nanoparticles in photography incorporates nanoparticles with widely varied sizes, shapes, and structures, and formation processes from nucleation to growth. The second part describes the properties and performances of nanoparticles of Ag and related materials, including chapters on light absorption and scattering, catalysis, photovoltaic effects, and stability. The accumulated knowledge of many years of research in AgX photography is analysed and explained to deepen the reader's knowledge on metal nanoparticles for plasmonics, catalysis, and photovoltaics with new ideas arising from the interaction between them.

Recenzijos

This book is important because it gives an overview of this field drawn from the history of photography and how it can be applied to emerging technologies such as catalysis, photovoltaics, and plasmonics. The author has worked in the photography industry for nearly 50 years and has a deep knowledge that is reflected in this book ... useful reference for researchers and graduate students * Thomas M. Cooper, MRS Bulletin * This book is unique in approaching the science and technology in plasmonics from the unprecedented viewpoint and should be recommended to those, who are anxious to promote the research on plasmonics with metal nanoparticles. (translated from Japanese) * Hiroaki Misawa, President of the Japanese Photochemistry Association * This book offers invaluable insights into understanding of the synthesis, properties and applications of silver nanoparticles. Great wealth of knowledge accumulated over several decades for silver halides is bridged to silver nanoparticles by the expert in both fields for the benefits of a wide range of researchers in nanoparticles and plasmonics. * Vladimir Kitaev, Wilfrid Laurier University * This book offers a comprehensive review of silver and silver halide nanomaterials, including their preparation, optical properties, and their unique applications in photography, plamonics, and catalysis. It is also interesting to see the connection between silver and silver halide in these aspects. It is a very useful reference book on these two types of functional nanomaterials. * Younan Xia, Georgia Institute of Technology *

1 Introduction
1(7)
1.1 Introduction to Metal Nanoparticles and Plasmonics
1(3)
1.2 Introduction to AgX Photography
4(1)
1.3 Nanoparticles in AgX Photography and Plasmonics
5(3)
2 Shape and Structure of Nanoparticles of Ag and Related Materials
8(42)
2.1 Shape and Structure of Metal Nanoparticles for Plasmonics
8(10)
2.1.1 Nuclei and Seeds for Metal Nanoparticles
8(2)
2.1.2 Single-Crystalline Metal Nanoparticles
10(1)
2.1.3 Metal Nanoparticles as Modified by Crystal Defects
10(7)
2.1.4 Composite Metal Nanoparticles
17(1)
2.2 Shape and Structure of Ag and AgX Nanoparticles in Photography
18(16)
2.2.1 Nuclei of Ag Nanoparticles
18(3)
2.2.2 Single-Crystalline AgX Nanoparticles
21(1)
2.2.3 Nanoparticles as Modified by Crystal Defects
22(7)
2.2.4 Composite AgX Nanoparticles: Uniform, Core/Shell, and Epitaxial
29(5)
2.3 Evaluation of Crystal Structure of Nanoparticles
34(16)
2.3.1 Lattice Constant
34(2)
2.3.2 Size of Nanoparticles and Crystallites
36(2)
2.3.3 Bulk Crystal Defects
38(1)
2.3.4 Surface Structure and Defects
39(3)
2.3.5 Crystal Habit
42(8)
3 Preparation of Nanoparticles of Ag and Related Materials
50(59)
3.1 Preparation of Metal Nanoparticles for Plasmonics
50(13)
3.1.1 Fundamentals of Preparation of Metal Nanoparticles for Plasmonics
50(3)
3.1.2 Small Metal Nanoparticles as Nuclei and Seeds
53(1)
3.1.3 Preparation of Single-Crystalline Metal Nanoparticles
54(1)
3.1.4 Light-Induced Size Reduction of Metal Nanoparticles
55(1)
3.1.5 Metal Nanoparticles with Defect-Induced Shapes: Nanorods and Nanoplates
56(4)
3.1.6 Rate-Determining Growth Step and Shape of Metal Nanoparticles
60(2)
3.1.7 Composite Metal Nanoparticles
62(1)
3.1.8 Arrangement of Metal Nanoparticles
62(1)
3.2 Preparation of Ag Nanoparticles in AgX Photography
63(13)
3.2.1 Nucleation of Ag Nanoparticles as Latent Image Formation
63(4)
3.2.2 Growth of Ag Nanoparticles as per Photographic Development
67(9)
3.3 Preparation of AgX Nanoparticles in Photography
76(20)
3.3.1 Protective Colloids for AgX Nanoparticles in Photography
76(3)
3.3.2 Apparatus for Preparation of AgX Nanoparticles
79(1)
3.3.3 Preparation of Single-Crystalline AgX Nanoparticles
80(3)
3.3.4 Preparation of Tabular AgX Nanoparticles
83(5)
3.3.5 Preparation of Composite AgX Nanoparticles: Uniform, Core/Shell, and Epitaxial
88(4)
3.3.6 Control of Size Distribution and Anisotropy in AgX Nanoparticle Shape
92(4)
3.4 Arrangement of AgX and Ag Nanoparticles
96(13)
4 Light Absorption and Scattering of Ag and Metal Nanoparticles
109(32)
4.1 Plasmonics
109(18)
4.1.1 Introduction
109(3)
4.1.2 Isotropic Metal Nanoparticles
112(5)
4.1.3 Anisotropic Metal Nanoparticles
117(2)
4.1.4 Light Absorption of Arranged Metal Nanoparticles, Nanorods, and Nanoplates
119(7)
4.1.5 Effects of Surface Plasmon Resonance of Metal Nanoparticles
126(1)
4.2 Light Absorption of Ag and Related Materials in AgX Photography
127(14)
4.2.1 Light Absorption of Ag Nanoparticles in AgX Photography
127(3)
4.2.2 Light Absorption of Ag Nanoplates as Arranged by Coating Technology
130(3)
4.2.3 Light Absorption of Aggregated Chromophores in AgX Photography
133(8)
5 Catalysis by Ag and Metal Nanoparticles
141(25)
5.1 Catalysis by Metal Nanoparticles in Plasmonics
141(5)
5.1.1 Introduction to Catalysis by Metal Nanoparticles
141(1)
5.1.2 Reactions Enhanced by Homogeneous Catalysts of Metal Nanoparticles
142(1)
5.1.3 Reactions Enhanced by Heterogeneous Catalysis of Metal Nanoparticles
143(1)
5.1.4 Promotors for Catalysis of Nanoparticles
144(2)
5.2 Catalysis by Ag Nanoparticles as for AgX Photographic Systems
146(20)
5.2.1 Promotion of Ag Nanoparticles for Water Splitting by Photocatalytic AgX Systems
146(1)
5.2.2 Catalysis of Ag Clusters for Formation of Latent Image Centres and Ag Nanoparticles
147(1)
5.2.3 Ag Nanoparticles as Catalysts for Photographic Development: Size, Shape, and Site Dependences
148(18)
6 Photovoltaic Effect of Ag and Metal Nanoparticles
166(18)
6.1 Light-Induced Charge Separation and Roles of Metal Nanoparticles
166(2)
6.2 Enhancement of Light-Induced Charge Separation in Inorganic and Organic Semiconductors by Metal Nanoparticles
168(1)
6.3 Photovoltaic Effect of Metal Nanoparticles on Inorganic Semiconductor Nanoparticles
169(4)
6.3.1 Generation of Hot Electrons in Metal Nanoparticles by Light Absorption
169(1)
6.3.2 Generation of Hot Electrons on Metal Nanoparticles by Exothermic Chemical Processes
169(1)
6.3.3 Photovoltaic Effect of Metal Nanoparticles on Inorganic Semiconductors
170(3)
6.4 Light-Induced Charge Separation in Ag/AgX Nanoparticle Systems in Relation to Photography
173(11)
6.4.1 Light-Induced Charge Separation in AgX Nanoparticles to Form Ag Nanoparticles
173(1)
6.4.2 Photovoltaic Effect of Ag Nanoparticles in AgX Photography
174(2)
6.4.3 Mechanism of Photovoltaic Effects of Noble-Metal Nanoparticles on Semiconductors
176(8)
7 Stability of Ag and Metal Nanoparticles
184(17)
7.1 Introduction
184(1)
7.2 Stability of Ag Nanoparticles in Plasmonic Devices
184(1)
7.3 Stability of Ag Nanoparticles in AgX Photography
185(6)
7.3.1 Evaluation of Ag Nanoparticle Stability in AgX Photography
185(1)
7.3.2 Mechanism of Degradation of Ag Nanoparticles in AgX Photography
185(3)
7.3.3 Stabilization of Ag Clusters in Photographic Materials
188(1)
7.3.4 Stability of Ag Nanoparticles in Photographic Materials
188(3)
7.4 Electrochemical Examination of Ag Nanoparticles: Effect of Gelatin
191(1)
7.5 Electronic Structure of Ag Nanoparticles in Gelatin Layers in Ambient Atmosphere
192(4)
7.6 Stabilization of Ag and Metal Nanoparticles in Photographic Materials and Plasmonic Devices
196(5)
Index 201
Tadaaki Tani received his doctorate in Engineering from the University of Tokyo in 1968, and went on to prestigious careers in the photoraphic industry and in academia. He worked on silver halide photography in the laboratories of the Fujifilm Corporation (1968-2010), and as Lecturer and Guest Professor at the Tokyo Institute of Technology (1994-2008). He was also President of the International Committee for imaging Science (1997-2006), and President of the Society of Photograph and Imaging of Japan (2002-2006). He has won many awards for his work, including the Berg Prize of the International Committee for Imaging Science (2010).
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